SLIDE 4 4
BOLTZMANN BOLTZMANN Distribution Distribution
Emission Basics Emission Basics
ph =
= ΔW = |W W = |Wu
u - W
Wl
l|
PHOTON PHOTON ENERGY ENERGY
- The population density of atoms, N
The population density of atoms, Nu, in , in an excited state, W an excited state, Wu, in relation to , in relation to those, those, N Nl
l, in a lower energy state
, in a lower energy state W Wl
l is
is given by the Boltzmann relationship, given by the Boltzmann relationship, as as
Energy exp(- ∆W/kT) Δ W4 Δ W3 Δ W2 Thermal equilibrium
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as, as, Nu/N Nl
l = exp[
= exp[-
(Wu-W Wl
l)/
)/kT kT] ] = = exp exp[ [-
W/kT kT] ]
- Equilibrium between Absorption
Equilibrium between Absorption vs vs spontaneous emission spontaneous emission
Nu/Nl at a given temperature T Δ W2 Δ W1
Principles of Laser Principles of Laser
Thermal equilibrium
Thermal equilibrium balance balance
W2 Incident photon W = hf Stimulated photon W = hf
q
- f Absorption
- f Absorption vs
vs spontaneous spontaneous emission emission
A third mechanism also exists:
A third mechanism also exists: crucial to the formation of crucial to the formation of LASER action this process is LASER action this process is known as known as STIMULATED STIMULATED
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W1
Stimulated emission
EMISSION EMISSION
Not a dominant process in
Not a dominant process in thermal systems at room thermal systems at room temperatures. temperatures.