Magnetic Order Peter de Chtel Institute of Nuclear Research - - PowerPoint PPT Presentation

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Magnetic Order Peter de Chtel Institute of Nuclear Research - - PowerPoint PPT Presentation

Magnetic Order Peter de Chtel Institute of Nuclear Research Hungarian Academy of Sciences Debrecen, Hungary Simple ferromagnetic, antiferromagnetic and ferrimagnetic order


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SLIDE 1

Magnetic Order

Peter de Châtel Institute of Nuclear Research Hungarian Academy of Sciences Debrecen, Hungary

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SLIDE 2

Simple ferromagnetic, antiferromagnetic and ferrimagnetic

  • rder

↑↑↑↑↑↑ ↑↑↑↑↑↑ ↑↑↑↑↑↑ ↑↑↑↑↑↑ ↑↓↑↓↑↓ ↓↑↓↑↓↑ ↑↓↑↓↑↓ ↓↑↓↑↓↑

↑↓↑↓↑↓

↓↑↓↑↓↑

↑↓↑↓↑↓

↓↑↓↑↓↑ ferro antiferro ferri

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SLIDE 3

Two sublattices

↑↓↑↓↑↓ ↓↑↓↑↓↑ ↑↓↑↓↑↓ ↓↑↓↑↓↑ A B A B A B B A B A B A A B A B A B B A B A B A

Binary alloy antiferromagnet

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SLIDE 4

Magnetite Fe3O4

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SLIDE 5

Two ways of partial compensation

↑↓↑↓↑↓

↓↑↓↑↓↑

↑↓↑↓↑↓

↓↑↓↑↓↑

Unbalanced antiferromagnet Cohabitation of ferro- and antiferromagnet

↑↑↓↑↑↓

↑↓↑↑↓↑ ↓↑↑↓↑↑

↑↑↓↑↑↓

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SLIDE 6

Three sublattices

↑↑↓↑↑↓

↑↓↑↑↓↑ ↓↑↑↓↑↑

↑↑↓↑↑↓

C A B C A B A B C A B C B C A B C A C A B C A B

A tetrahedral, occupied by Fe3+ B and C octahedral, B occupied by Fe3+, C occupied by Fe2+

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SLIDE 7

MnO, a ”simple” antiferromagnet

1949, Shull & Smart: AF order exists 1951, Shull, Strauser & Wollan: FM order in (111) planes, noncollinear structure not excluded 1988, Shaked, Faber & Hitterman: collinear, spins

  • riented in (111) plane

2006, Goodwin & al.: oriented in <11-2> direction, slight out-of-plane component

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SLIDE 8

Magnetic structure of MnO

C.G. Shull, W.A. Strauser & E.O. Wollan, Phys.Rev. 83 (1951) 333 nn: 6 ↑↑, 6 ↑↓ nnn: 6 ↑↑

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SLIDE 9

MnO, a ”simple” antiferromagnet

1949, Shull & Smart: AF order exists 1951, Shull, Strauser & Wollan: FM order in (111) planes, noncollinear structure not excluded 1988, Shaked, Faber & Hitterman: collinear, spins

  • riented in (111) plane

2006, Goodwin & al.: oriented in <11-2> direction, slight out-of-plane component

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SLIDE 10

Possible collinear magnetic structures

  • n the simple cubic lattice

E.O. Wollan and W.C. Koehler, Phys.Rev. 100 (1955) 345

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SLIDE 11

Magnetic structures of the rare earths

а ferromagnet б spiral в conical ferromagnet г conical antiferromagnet

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SLIDE 12

The ordered state of chromium amagn = 2π/δ

  • E. Fawcett, Rev.Mod.Phys. 60 (1988) 209
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SLIDE 13

The ordered state of chromium incommensurate

  • E. Fawcett, Rev.Mod.Phys. 60 (1988) 209
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SLIDE 14

Frustration

  • P. Schiffer, Nature 420 (2002) 35
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SLIDE 15

Noncollinear, coplanar structure in CsNiCl3

Zaliznyak & al. Pisma ZhETF 47 (1988) 172

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SLIDE 16

Water ice and spin ice

Dy2Ti2O7 , Pyrochlore structure

S.T. Bramwell and M.J.P. Gingras, Science 294 (2001) 1495

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SLIDE 17

Heat capacity and entropy

Remanent entropy in water ice: (R/2)ln(3/2) Pauling 1935

S.T. Bramwell and M.J.P. Gingras, Science 294 (2001)

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SLIDE 18

Predicted ground state

S.T. Bramwell and M.J.P. Gingras, Science 294 (2001) 1495

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SLIDE 19

The spinel structure