Victor Ivanovich Petrik Full Member, Academician of Russian - - PDF document

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Victor Ivanovich Petrik Full Member, Academician of Russian - - PDF document

Victor Ivanovich Petrik Full Member, Academician of Russian Academy of natural sciences, Russian technological academy, Petrovskaya academy of sciences and arts, International academy of sciences, ecology and nature, Honoured member of European


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Victor Ivanovich

Petrik

Full Member, Academician of Russian Academy of natural sciences, Russian technological academy, Petrovskaya academy of sciences and arts, International academy of sciences, ecology and nature, Honoured member of European university. The author of four scientific discoveries: “Phenomenon of magnetic-ordered state of osmium-187 isotope in the ferromagnetic matrix”, Diploma No.180. “Phenomenon of generation of nanostructured carbon complexes”, Diploma No.163. “Phenomenon of nuclear spin selectivity in reversible chemical reactions with graphenes”, Diploma No.312. “Regularity of generation of the geometric spatial multidimensional structure using the mathematical golden section algorithm”, Diploma No.168.

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V.I. Petrik has established the following research centres in Russia:

  • 1. In 1991 he established a private research laboratory being the first

private research laboratory in new Russia.

  • 2. In 1997 the Research institute of physics of fullerenes and new

materials has been established being a limited liability company (LLC) and the first Russian private research institute, which founders are Russian Academy of natural sciences, Nauchpribor CJSC and V.I. Petrik, a natural person.

  • 3. In 2007 the second private research institute has been established in

Russia, Research institute

  • f

supramolecular systems and nanotechnologies LLC, which founders are Dubna International institute of nuclear research, State international university of nature, society and man and V.I. Petrik, a natural person. V.I. Petrik was elected the scientific leader of the institute.

  • 4. In 2008 Research institute of supremolecular systems and information

technologies LLC has been established. The institute has been founded by V.I. Petrik's company, Golden Formula Holding LLC, and M.A. Boch-Bruyevich state university of telecommunications. V.I. Petrik is the author of two scientific monographs: Optical armoured ceramics. Spinel. Published by Regional printing house No.1, Irkutsk, 2011. Anti-Stokes compounds and technologies based thereon. Published by Regional printing house No.1, Irkutsk, 2012.

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The basic elements of HRCM project as the subject for public presentation and commercialization objects are the following items created by Academician V.I.Petrik:

  • A unique substance – high reactivity carbon mixture (HRCM);
  • Unique HRCM production technology;
  • Technologies for HRCM application;
  • Special products created on the basis of HRCM (filters fir

drinking water, filtration booms and other various filters, heat- protective and moisture-retaining materials, catalysis and process additives, medicinal means and preparations, etc);

  • service and works related to HRCM production and

application. The high reactivity carbon mixture and technology for its production have been developed as a result of the scientific discovery made by Academician V.I.Petrik: “Phenomenon of generation of nanostructured carbon complexes” certified by the International association of the authors of scientific discoveries in 2001, Diploma No.163. Methods for commercial production and application of graphenes (HRCM) are protected by the following patents: RU2163883 30.09. 1999 Method for industrial production of a high reactivity carbon mixture by cold destruction and a device for its implementation”, 2 US 7,842,271 B2 30/11/2010 “Mass production

  • f

carbon nanostructures”, US 2003/ 0024884A1 06/02/2003 “Method for removing oil, petroleum products and/or chemical, pollutants from liquid and/or gas and/or surface”, European patent No.EP1247856, Eurasian patent No.002579 as well as patents of a number of Asian countries. HRCM is a new substance of a certain class having no analogues in the world by physical, chemical, functional and economic characteristics as well as by ecological purity, versatility and variety of spheres of application.

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The high reactivity carbon mixture (HRCM) is a homogeneous carbon mass consisting of graphenes being flat elements of graphite structure bonded by van der Waals’ forces as well as products of their chaotic coupling. The technology of HRCM production is also unique. HRCM is produced by the method of cold destruction of carbon laminated compounds into carbon clusters, graphenes. To this effect, chemical compounds being capable to explosive decomposition under external action (photochemical, mechanical, chemical, etc.) are placed into the interlayer spaces of the laminated carbon compounds, with subsequent initiation of the autocatalytic process of decomposition of the compound. The gaseous products of decomposition of the chemical compound being generated in the interlayer spaces destroy the carbon matrix with generation of individual two-dimensional carbon crystals (graphenes), which structure is complimentary to the structure of graphite’s basal plane.

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In the photo: cold method for grapheme production. An exceptional peculiarity is that HRCM can be produced in commercial quantities in field conditions and requires no special hardware support. The delegation of Spanish scientists are acquainting themselves with the industrial method of graphene production, 2001.

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The typical feature of divergent chemical reactions is the availability of limit phenomena consisting of the fact that in case of insignificant variation of a parameter (pressure, temperature, composition) a sharp change of the chemical reaction rate occurs. The use of special impurities initiating the autocatalytic acceleration of the chemical reaction or inhibiting the chemical reaction allows to regulate the rate of HRCM running production. Depending upon the rate of chemical reaction the degree of HRCM destruction varies as well as the changes occur in the content of graphenes, Graphite packets and various carbon aggregates being the result of their chaotic coupling. The use of special impurities initiating the autocatalytic acceleration of chemical reaction leads to the exponential growth of the rate of chemical reaction. Gaseous products of decomposition of chemical compounds actively emit HRCM from the reaction zone. A typical "plasma-like" glow is generated in the reaction zone.

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The reaction is initiated by Nitin Gadkari the President of the Indian party

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The industrial production of the main elements in the process line for the manufacture of HRCM, Cl2O7 high reactivity chemical compound, has been created, which synthesis is performed from NaCl in specially developed platinum electrolysers. Special compounds have been developed allowing to maintain the process of decomposition of the chemical compound contained in the interlayer spaces

  • f graphite in the mode of self-accelerating branched chain reaction.

Spanish scientists at the Cl2O7 production site. The high reactivity chemical compound is supplied from the electrolysis shop to special mixers for the treatment of graphite. Then graphite initiated is treated with stabilizing chemical compounds, after which it can be stored in the form of a concentrate for a long period of time in polyethylene containers at warehouses, at places with increased hazard of emergency spills of liquid hydrocarbons or any other hazardous chemical compounds,

  • n marine vessels, etc.
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The Golden Formula Holding LLC’s production site allows manufacturing HRCM in the amount of 300 tons per year. Properties of the high reactivity carbon mixture (HRCM) HRCM has unique physical and chemical characteristics, which causes the variety of their spheres of application. Unsurpassed sorption characteristics of HRCM have been virtually confirmed by the results of multiple full-scale tests (in various countries worldwide) as well as numerous expert examination studies conducted by competent national and international organisations. So, for example, comparative tests of HRCM sorption characteristics conducted in Excelchem Environmental Labs (USA) have shown that HRCM is superior by this characteristic than activated coconut charcoal GAC being the best on the American market by 50…200 times depending upon the liquid substance being under investigation. In particular, the HRCM sorption characteristics as to crude oil surpass GAC by 134,4 times, i.e. on gram of HRCM binds 67,2 grams of oil. It is notable that oil can be separated from HRCM, which allows using HRCM as a sorbent repeatedly.

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In 2012 in the Nova Biotec research centre (Germany), on the initiative of Rospotrebnadzor, the comparative testing of five leading filter manufacturers has been performed. The tests were conducted with respect to 22 analytical

  • parameters. The HRCM-based filters manufactured by Golden Formula

Holding LLC have been ranked first with respect to 22 parameters.

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THE FEDERAL SERVICE FOR SUPERVISION OVER PROTECTION OF CONSUMER RIGHTS AND HUMAN WELFARE Press release dated 07.07.2011 Re: Golden Formula Water Treatment Systems. Hereby the Federal Service for Supervision over Protection of Consumer Rights and Human Welfare informs that a Federal State Institution of Science «F.F.Erisman Federal Scientific Center of Hygiene» of the Federal Service for Supervision over Protection of Consumer Rights and Human Welfare has undertaken a comparative study to evaluate the water treatment efficiency of household jug-type filters under five brands that are most widespread in the Russian Federation, i.e. «Aquafor», «Barrier», «Brita», «Geyser», «Golden Formula» (ZF-5) . As per a data of the study undertaken concerning 18 basic safety indicators, including phenol, arsenic, zinc, cadmium, nitrites, and lead, the highest efficiency has been recorded with a filter under «Golden Formula» (ZF-5) brand. Therefore, a «Golden Formula» filter has ensured the highest number of indicators under which the hygienic treatment efficiency has been recorded. THE FEDERAL SERVICE FOR SUPERVISION OVER PROTECTION OF CONSUMER RIGHTS AND HUMAN WELFARE Press Centre 19.06.12 On investigation of water purification systems The Federal service for supervision in the sphere of protection of consumer rights and human welfare continues conducting monitoring of the effectiveness of water purification systems of domestic manufacture. In March 2012 NovaBiotec Dr.Fechter GmbH, a German company, conducted the assessment of effectiveness of water purification systems produced by five Russian and foreign manufacturers. The conclusion states the following:

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“The effectiveness of water purification was evaluated by 27 indicators, which comprised organoleptic characteristics (taste, colour, odour, turbidity), physical and chemical parameters (water oxidability, oxygen demand, acidity), content of organic chemical substances (benzene, chloroform, formaldehyde, carbon tetrachloride, etc.) as well as the content of heavy metals (lead, arsenic, cadmium, copper, zinc). The investigations have shown that ZF-5 filters have ranked first out of 27 by 22

  • indicators. So ZF-5 filters under the Gold Formula trademark have demonstrated the

absolute advantage by the absorption. At the present time ion-exchanging resins are used in filters for removing metals from

  • water. Nevertheless, in doing so the ion-exchanging resins demonstrate an undesirable

side effect, namely, they extract useful salts from water, for example, calcium, magnesium and potassium. In the given case we see a new phenomenon in water purification, namely, ZF-5 filters show the highest absorption activity with respect to heavy metals with the inertness to hardness salts being preserved. We believe that this phenomenon shall be considered as positive". Nova Biotec Dr.Fechter GmbH’s test laboratory has given a high rating to the filtration properties of the ZF-5 filter under the Gold Formula trademark.

Abnormal sorption properties of HRCM can be explained by the fact that carbon atoms at the graphene periphery are not saturated, have increased chemical activity and can be bound to many chemical compounds in order to compensate free valence.

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HRCM and materials obtained on its basis have been studied in the following American research and development institutions and laboratories:

  • 1. University of California Irvine Wen-An Chiou, Ph.D.
  • 2. CARBON NANOTECHNOLOGY LABORATORY Howard Khan

Schmidt, Ph.D.

  • 3. University of California Davis Department of Chemical Engineering

& Material Science

  • 4. University of California Irvine Jian-Guo Zheng, PhD
  • 5. Brunswick Laboratories
  • 6. Brighton Analytical LLC
  • 7. Nautilus Environmental
  • 8. Sierra Analytical
  • 9. Del Mar Analytical
  • 10. University of Nevada – Reno Nevada Stable Isotope Laboratory
  • 11. University of Waterloo Canada
  • 12. United States Department of Interior, U.S. Geological Survey ,431

National Centre

  • 13. Excelchem Environmental Labs

So the outstanding sorption properties of HRCM allows to use it as a special material for solving various technological problems:

  • neutralisation of toxic waste and destruction of chemical warfare

agents;

  • high quality additional cleaning of drinking water;
  • localization and extinguishing of fires of toxic and combustive fluids on

land and on water surface;

  • liquidation of emergency spills of oil and oil products on land and on

water surface including recultivation of soils and final water treatment;

  • cleaning of blood plasma;
  • creation of medicinal preparations;
  • removal of polyaromatic hydrocarbons from tobacco smoke;
  • moisture retention in sandy and alkaline soils;
  • waste water treatment, recovery of precious metals.
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A high effectiveness of HRCM use in case of spills of fuel and lubricant materials (FLM) and oil products into soil. At present this material is used by many enterprises and organisations for liquidation of ecological consequences of various accidents. In particular, in 1997-1998 Transneft’, a joint-stock company, purchased 25 tons of HRCM from Golden Formula Holding LLC for liquidation of oil spills in case of its unauthorised extraction from pipelines. HRCM is also used as a sorbent in a number of foreign countries for ecological purposes.

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Liquidation of an emergency spill of fuel and lubricant material by means

  • f HRCM, town of Siauliai, Lithuania. All fire fighting vehicles are

equipped with special pillows filled with HRCM. Boom containments based on HRCM have successfully used in marine conditions in case of large oil spills.

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HRCM in water treatment systems In Russia the systematic investigations of HRCM have been performed since 1998 in the following research institutions:

  • Institute of criminology, Federal Security Service of the Russian

Federation;

  • Institute of spectroscopy, Russian Academy of Sciences;
  • Moscow state institute of electronic engineering;
  • M.V. Lomonosov Moscow state university;
  • Research Institute, Ministry of Defence of the Russian Federation;
  • V.G. Khlopin Radium Institute Science & Production Association, a

federal state unitary enterprise (FSUE);

  • F.F. Erisman Federal science and production centre, a federal state

science institution (FSSI);

  • Centre of extreme medicine FSUE;
  • I.I. Janelidze Ambulance Research Institute;
  • Institute of toxicology FSSI.

These investigations have shown that the use of HRCM as a sorbent opens new unique possibilities relating to water treatment technologies. In doing so, the investigations performed in Institute of toxicology FSSI (Russia), in Brunswick Laboratories (USA) and in National Toxicology Centre (India) have convincingly demonstrated that water, which has passed through HRCM, has biological activity, antioxidant properties and enhances the adaptation capabilities of organism. This phenomenon opens a new era in water treatment technologies, a new understanding of the water value in biological processes, a new radical approach to solving health assurance problems. Taking into account the above, the United Russia party announced in 2007 about a national project called ‘Pure water’. According to this project all schools, children’s institutions. Medical institutions shall be equipped with filters based on HRCM.

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The Chairman of the State Duma B. Gryzlov hands over the diploma to

  • V. Petrik, the winner of the all-

Russian competition for the best water-treatment system. In 2009 all social institutions in Velikiy Novgorod and Novgorod Region have been equipped with such filters. It follows from the report prepared in the town of Novgorod that for the period of 2008-2009 the sickness rate related to viral hepatitis has virtually decreased by three times and the average children’s sickness rate related to dysentery has been reduced by 64.5% as compared to the average Russian

  • level. The monitoring of the quality of water treated on Golden Formula

Holding LLC’s systems installed in social institutions in the town of Novgorod and Novgorod Region is performed according to the agreement with the Novgorod Government by the efforts of Rospotrebnadzor. During the period from 2007 until 2010 over 1400 positive opinions have been

  • btained.
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In his speech at the Pure Water - 2010 International Forum, V.V. Putin determined the Pure water national project as a top priority project. Presidium of the Pure Water - 2010 International Forum

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In 2008 V.I. Petrik delivered a report on potable water problems at the 12th International Economic Forum held in St. Petersburg.

  • V. Petrik at the International economic forum.

A flask with water contaminated with oil products can be seen in the

  • foreground. The Vice Chairman of the Government of the Russian

Federation A.D. Zhukov and the Chairman of the State Duma of the Federal Assembly of the Russian Federation B.V. Gryzlov have drunk water that has passed through V.I. Petrik’s filter.

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On the photo: Minister of regional development of the Russian Federation D.N. Kozak and RANS (Russian Academy of Natural Sciences) Academician V.I. Petrik. Basing on HRCM V.I. Petrik has successfully solved a number of ecological problems. In 1990 the President of USA G. Bush signed the program called ‘Clean air for American cities’. According to the program adopted, they began adding methyl tret-butyl ether (MTBE) to petrol. Already five years afterwards, all seven water wells, from which the town of Santa Monica is supplied, were poisoned with MTBE. The ecological catastrophe was declared in the USA. At present the use of MTBE is prohibited in 25 US states. American scientists applied to V. Petrik with a proposal to develop a water treatment

  • technology. The technology developed by V. Petrik, Configuration and

methods for water purification BE - US 7,128,881 B2 31/10/2006, allows cleaning water with the МТВЕ content exceeding the standard rate by 8,000 times!

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According to G. Bush’s direction, the photo report on his meetings with

  • V. Petrik has been placed in the United States National Museum for

eternal storage. In bogged areas, one of the most important water treatment problems is the contamination of water with humic acids. This problem is equally expressed both in Leningradskaya oblast and in Miami. Before the dawning of the age of HRCM, there have existed no technologies in the world, which could be capable to clean water from humic acids.

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The Governor of Florida Jeb Bush has personally got convinced in the effectiveness of HRCM for cleaning water from humic acids. According to the Fort Lauderdale city council’s decision, V.I. Petrik has become an honored citizen of the city.

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Many well-known US politicians endeavour to get acquainted with

  • utstanding achievements of the Russian scientist V. Petrik.
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For many decades the residents of Kuwait have been forced to accept the unnatural smells of hydrogen sulphide, which exudes along with water during excavating soil for construction works. The Kuwaiti Government has many times called together the best world specialists in order to solve this

  • problems. Once Her Highness Sheikha Amthal Al Sabah personally applied

to Petrik with the request to render help in such a misfortune. Soon thereafter V.I.Petrik delivered a high-performance installation to Kuwait for catalytic oxidation of sulphur dioxide by atmospheric oxygen.

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Her Highness Sheikha Amthal Al Sabah has given a valuable gift to the scientist as a token of gratitude and has prepared dinner for the first time in her life and personally served it to the scientist. Basing on HRCM, V.I. Petrik has created a unique technology for the recovery of water from radioactive elements and their reliable fixation in carbon matrixes. In particular, using the technology of gaseous phase application of platinum group metals onto graphenes, he created a highly effective hydrophobic catalyst for the recovery of water from heavy isotopes

  • f hydrogen.

On the basis of this technology, V. Petrik established an industrial production of light water with the residual content of deuterium being equal to 2-3 ppm. Such water has passes certification in the Test Centre at the US Department of the Interior.

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In the photo: commercial production of light water with the residual content of deuterium being equal to 2 ppm. The minister of nuclear energy V. Kirienko and Academician V. Petrik.

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A unique installation for cleaning water from tritium is being created in Russia with participation of the Ministry of nuclear energy under the sponsorship of the United Russia party on the basis of V. Petrik’s

  • developments. This technology will solve the main problem of CANDU

reactors, i.e. contamination of heavy water with tritium. In the photo: The Chairman of the Duma, Chairman of the Supreme Council of the United Russia party B.V. Gryzlov, minister of nuclear energy V. Kirienko and Academician V. Petrik. In the course of conduction of research developments under a commission of the Ministry of defence of the Russian Federation, a number

  • f HRCM-based systems for water cleaning from bacteria and viruses have

been developed.

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These filters will become indispensable in a rescue kit during ecological catastrophes.

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The minister of defence A.E. Serdyukov congratulated V. Petrik with a regular scientific achievement. V.I. Petrik is conducting joint investigations with the S.M. Kirov Military medical academy, The unique data have been obtained on medical treatment of burning wounds by means of HRCM. In the photo: Chief of the Military medical academy lieutenant-general B.V. Gaidar and V.I.Petrik on scientific advice .

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Minister of healthcare and social development of the Russian Federation T.A. Golikova has acquainted herself with the results of HRCM use as a biologically active additive. Progressive scientific community support V.I. Petrik's unique scientific achievements. The minister of science of the Russian Federation A.A. Fursenko and RANS Academician V.I. Petrik.

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Leading academicians of the Russian academy of sciences have held a number of meetings devoted to V. Petrik’s works, have heard his reports, And, having acquainted with V. Petrik’s unique technology for the production of graphenes by the graphite cold destruction method have given their appreciation to V. Petrik’s works: “The effects discovered by V.I. Petrik are of significant scientific interest. It is necessary to organise working groups at the corresponding institutes for scientific support of the above-mentioned inventions and technologies.”

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Research institute of supramolecular systems and nanotechnologies LLC has been registered in Russia on 15. 01. 2007. The Institute founders are: 1) Joint institute for nuclear research, an international intergovernmental research organization. 2) International university of nature, society and man, a state educational institution of higher professional education, Dubna, Moscow Region. 3) Victor Ivanovich Petrik, a natural person. Victor Ivanovich Petrik was elected the scientific leader of the Institute. Within the framework of the target-oriented program “Research and investigations on priority directions of development of the Russian scientific and engineering complex for 2007-2012”, a competition has been announced

  • n the topic: “Development of methods for production and treatment of a

new class of functional rare-metal materials”. The winner of the competition was Research institute of supramolecular systems and nanotechnologies LLC, and a research on the topic: “Production of high-purity nanocrystalline rhenium” has been performed under V.I. Petrik’s leadership during the period of 2007 -2008. The technology developed as a result of this research has been called as follows: “A method for the production of rhenium powder by chemical deposition from the gaseous phase”. It has a patent and legal protection and ensures the production of nanocrystalline rhenium with purity of at least 99.995% and grain size of 30-125nm. Rhenium is one of the most rare elements in the Earth’s core. At the present time only three rhenium deposits are known, in USA, Kazakhstan and in Russia in the form of gas emissions from the Kudryaviy volcano. In doing so, the extraction is performed in the USA (30 tons a year) and in Kazakhstan (10 tons a year).

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Another source of rhenium is technogenous raw material (waste turbines, blades, thermally-loaded parts of aircraft engines, etc.), which is strategic and has been accumulating for many decades already pending the establishment of industrial technology for rhenium extraction. The results of the research performed have been highly appreciated by A.M. Chekmaryov, leading Russian specialists in rhenium research, associate member of RAS (Russian Academy of Sciences), Professor of Russian university of chemistry and technology. The technology for rhenium production has passed comprehensive experimental and industrial testing and strict expert examination in various research institutions and organisations. ROSNANO, a state corporation, has approved the project basing on the technical commission’s resolution and has made a decision to co-finance construction of a rhenium production factory, which process system is based on V.I. Petrik’s ideas and inventions.

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Chairman of the State Duma B.V. Gryzlov and Rosnano OJSC’s Chairman of the Board A.B. Chubais are familiarizing themselves with new HRCM-based materials at V. Petrik’s laboratory. Chairman of the State Duma B.V. Gryzlov , Director of the Joint institute

  • f nuclear research, RAS Academician A.N. Sisakyan, Rosnano OJSC’s

Chairman of the Board A.B. Chubais are familiarizing themselves with the

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technology of gaseous-phase application of platinum group metals onto graphenes (HRCM). Chairman of the State Duma B.V. Gryzlov , Director of the Joint institute

  • f nuclear research, RAS Academician A.N. Sisakyan, Rosnano OJSC’s

Chairman of the Board A.B. Chubais , Chief designer of the Dollezhal research and development institute (NIKIET) V.P. Smetannikov and other well-known scientists near the personal laboratory of V.I. Petrik, Academician of RANS (Russian Academy of Natural Sciences).

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On January 27 2013, leading scientists from the European Union arrived to study inventions and technologies formulated by V.I.Petrik:

Michael Grätzel a professor at the École Polytechnique Fédérale de Lausanne, Member of the European Academy of Sciences.(Switzerland) Bernhard Kräutler, Head of the Institute of Organic Chemistry at the University of Innsbruck, Member of the European Academy of Sciences.(Austria) Gabriele Centi is as full professor of Industrial Chemistry of the University of Messina and President of the European Federation of Catalysis Societies (EFCATS). Director of the European Laboratory of Surface Science and Catalysis (ELCASS) .(Italy) Antonio Bianconi- Director of the Rome International Center for Materials Science Superstripes RICMASS and full professor of the University of Rome, Member of the European Academy of Sciences.(Italy) Paul Lecoq- PhD, technical director of European Centre for Research in Medical Imaging (Cerimed) (France) Yanusz Lewinski-Professor of Chemistry, Warsaw University of Technology, Member

  • f the European Academy of Sciences.(Poland)

Paolo Pizzichemi- Vice-President of the “National Association of companies and company top management for development of science, education and culture” Italy) Luca Mazzotti- Auditor,Bachelor’s degree from the University of Milano in business administration.(Italy) This visit was organized by “National Association of companies and company top management for development of science, education and culture” (Italy)

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Abstract from findings of leading European scientists: «His inventions may have substantial effect in practical and academician spheres». «Delegation also stressed that Petrik’s inventions may have important commercial value and powerful economic effect. European delegation expressed interest to set up co-operation for a number of Petrik’s inventions and for further application of these results in numerous sectors of European industry».

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On March 12 2013, a delegation of scientists and industry leaders from China visited V.I.Petrik laboratories.

In his interview for TV, Mister Chan Kui, the President of Huaxing Corporation said: “…Society development depends on such persons as Mr. Petrik, whose achievements we have seen today and his achievements define many aspects of life spheres”.

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Findings made by Chinese delegation indicate: “Delegation members made a conclusion that reviewed technologies represent crucial interest for Chinese industry and science. Relevant reports will be made for the Government of China based on results of some studies performed by Mr. Petrik”.

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The Indian scientific delegation visit on 22 July 2013 - 29 July 2013.

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