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Kakoli Bhattacharya

SPEC, CEA Saclay, France

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!Thermoelectricity in fluids !Thermogalvanic cells !Ferrofluid based thermogalvanic cells !Ionic liquid based ferrofluids as thermoelectric materials !Summary and Perspectives

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Thermoelectricity in fluids

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Bulk thermoelectric field, E = S"#

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Thermogalvanic cells

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" contains a liquid electrolyte and a redox couple " temperature dependent electrode potential is termed as “Seebeck potential”.

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Ferrofluids for thermoelectric materials

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A ferrofluid (FF) is a colloidal suspension of single-domain magneticparticles, dispersed in a liquid carrier**.

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Physical characteristics of FF-SSC and FF-Y1SC

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@ hot-over-cold configuration Pmax (!SSC=0%) = 50 mW/m2 Pmax (!SSC=0,5%) = 100 mW/m2 And @ cold-over-hot configuration is: Pmax (!SSC=0,5%) = 900 mW/m2

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EAN-FF(!=1%) Nanoparticles: "-Fe2O3 (dNP= 7.34 nm) Redox couple : I2/I- Solvent : EAN Counter ion : Citrate ions

Redox reaction at the electrodes 3I2+2e

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Power measurements for EAN-FF at different !

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Conductivity as a function of FF concentration

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For EAN-FF, we know Di = 1.34 x 10-12 m2/s # = -60 d = 7,4 nm

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Summary and Perspectives

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c Seebeck coefficient in ferrofluid based electrolytes decreases with the increase in NP concentration. c Augmented power

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with increase in aqueous ferrofluid concentration due to forced convection. c First thermoelectric measurementsin ionic liquid based ferrofluids. c Many physical parameters are unknown in ionic liquids for correct analysis. c Maybe another physical effect on the electrode surface in complex ionic liquid based electrolytes c The theoretical model for weak electrolytes may not be suitable for complex electrolytes such as ionic liquids

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**B. Huang et al./ J. Chem. Phys. 143 (2015) 054902

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**B. Huang et al./ J. Chem. Phys. 143 (2015) 054902

where, tNP = Hitthorf transport number, and is represented as: %NP = ionic conductivity of the nanoparticles %T = total ionic conductivity of the electrolyte &(!eff) = isothermal osmotic compressibilityfrom the hard sphère model Di = diffusion coefficient of the NPs !eff = effective volume fraction of the NPs !0

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