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Steel Underground Storage Tank Cathodic Protection Testing Seminar Presented by STEEL TANK INSTITUTE Repeatability Methods that help increase repeatability of results Test in same locations from year to year Always add water to


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SLIDE 1

1

Steel Underground Storage Tank Cathodic Protection Testing Seminar

Presented by STEEL TANK INSTITUTE

Repeatability

  • Methods that help increase

repeatability of results

–Test in same locations from year to year –Always add water to reference cell location –Aim for clean, tight connections to structures

Objectives to Understand

Basic principles of corrosion Basic principles of cathodic protection Criteria for adequate cathodic protection Types of instruments & equipment required

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SLIDE 2

2

Objective to Understand

Effects of field conditions on measurements Importance of reference cell placement Determination of electrical continuity Need for documentation DEMONSTRATE Use of standard equipment to obtain field data Knowledge of continuity verification techniques Techniques to minimize measurement errors Monitoring of cathodic protection systems

Exam Requirements

  • Written Exam

–Passing grade is 75% or higher –Open book –Most questions multiple choice

  • Practical Exam

–Uses labs from class

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SLIDE 3

3

Practical Exam

  • Must be able to demonstrate:

– Take accurate tank to soil potentials

  • n both galvanic & IC systems.

– From readings obtained, identify which structures pass/fail.

  • Must be able to identify what criteria (e.g.
  • 850 mV) you used to determine pass/fail.

– Test and identify continuity/isolation.

Purpose Of Lab A

1) Become familiar with meters & reference cells. 2) Become familiar with test boards. 3) Measure potentials of 4 metals. 4) Determine which is most anodic. 5) Learn proper way to record measurements.

Purpose Of Lab B

  • Determine which metal is the anode

for the 4 combinations of metals given.

  • Determine which metal is the

cathode for the 4 combinations of metals given.

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SLIDE 4

4

Purpose Of Lab C

  • Learn two methods to test

underground structures for continuity and isolation.

  • Isolation is the opposite of continuity.
  • Learn what the criteria is to

determine if two structures are either continuous or isolated.

Purpose Of Lab D

  • Add cathodic protection to a metal.
  • Learn what is:

–Native potential –On potential

  • Learn how to measure Instant off

potential.

  • Calculate polarization shift
  • Learn if 100 mv criteria met.

Purpose Of Lab E

  • Learn to measure output voltage and

current of operating rectifier in Impressed Current System (ICCS)

  • Record tap settings
  • Measure resistance of potentiostat.
  • Calculate output current of each

shunt.

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SLIDE 5

5

Purpose Of Lab C

  • Determine if system is protected

using 100 mv shift criteria.

–Measure “on” potential, –Measure “instant off” potential, – Calculate polarization decay, – Is decay greater than 100 mv? – If so, 100 mv shift criteria is met.

Section 2 Corrosion Basics Corrosion

  • Corrosion is defined as the

degradation of a material or its properties due to a reaction with the environment.

  • While corrosion exists in virtually all

materials, it is most often associated with metals.

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SLIDE 6

6

Naturally Occurring Corrosion Process

Metals Corrode in an attempt to

achieve a Balance of Energy

The making of a tank...

Iron Ore

Furnace

Steel Tank or Pipe Steel

Rolling & Welding & Bending & Tightening

METALS HAVE DIFFERENT ENERGY LEVELS

NOBLE OR PASSIVE (+) ACTIVE (-)

THE ENERGY HILL

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SLIDE 7

7

Relative Energy Levels of Various Refined Metals

GOLD COPPER STEEL IN CONCRETE WITHOUT Cl ZINC MAGNESIUM ALUMINUM CARBON SILVER PLATINUM STEEL STEEL IN CONCRETE WITH Cl

  • NOBLE OR PASSIVE (+)

ACTIVE (-)

  • Relative Energy Levels of

Various Refined Metals

  • 1.7

+1.2 GOLD

  • 0.1

COPPER

  • 0.1

STEEL IN CONCRETE WITHOUT Cl

  • 1.0

ALUMINUM MAGNESIUM

  • 1.1

ZINC +0.4 CARBON +0.5 SILVER +0.9 PLATINUM

  • 0.6

STEEL

  • 0.5

STEEL IN CONCRETE WITH Cl

  • Energy Level in Volts vs. Cu/CuSO Reference

4

Terminology

  • Cathodic protection always uses DC

units

  • Volts = V or E, a measure of the

change in energy between two points

  • Current = A, a measure of the flow of

electric charge

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SLIDE 8

8

Terminology

  • Amps = the unit of current,

Example: we measure distance in feet just as current is measured in amps

  • R = Resistance

Unit of measurement is ohms, Ω

  • Ohm’s law : V = R * I

Piping Analogy

  • Voltage is equivalent to water

pressure

  • Current is equivalent to flow rate
  • Resistance is like the pipe size
  • Ohm’s law : V = R * I

Piping Analogy

Analogy: If you have a garden hose, and water pressure is increased, you get more water. The same happens if you increase your flow rate or your hose dia.

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SLIDE 9

9

Corrosion Cell

Anode Cathode Electrolyte Metallic Path DC Current Flow

Corrosion Cell

  • Cathode

Metal that receives energy and does not corrode

  • Metallic Path

Metal connection that moves energy from anode to cathode

  • Electrolyte

Material surrounding anode and cathode that permits ion transfer and supplies oxygen Anode Metal that loses energy

All four components required for corrosion to occur

Corrosion Cell

Carbon Rod Zinc Casing Conductive Paste

Dry Cell Battery

Switch

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SLIDE 10

10

A COMMON DRY CELL BATTERY IS A GALVANIC CORROSION CELL

CARBON ROD (CATHODE) ZINC CASE (ANODE) MOIST PASTE (ELECTROLYTE) WIRE (CONDUCTOR) CONVENTIONAL CURRENT

Zn++ H+ OH - OH -

ENERGY LEVEL DIFFERENCE BETWEEN CARBON AND ZINC

GOLD COPPER STEEL IN CONCRETE WITHOUT Cl

ZINC

MAGNESIUM ALUMINUM

CARBON

SILVER PLATINUM STEEL STEEL IN CONCRETE WITH Cl

  • Energy Level in Volts vs. Cu/CuSO Reference

4

1.5V

  • 1.1

+0.4

Galvanic Corrosion Process

  • Metals Corrode in an attempt to

achieve a Balance of Energy

  • Anode - Corroding Metal Surface
  • Cathode - Non-Corroding Metal

Surface

  • Metal Connection - Path for electron

energy transfer Electrolyte Connection - Path for ionic energy transfer

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SLIDE 11

11

Corrosion Control

  • Isolation

–Breaks the connection between different metals

  • Coatings

–Isolates the structure from the electrolyte

  • Cathodic Protection

–Creates a corrosion cell where structure is the cathode instead of the anode

Corrosion Cell

Anod e Cathode Electrolyte Metallic Path DC Current Flow

Coatings

Anod e Metallic Path Electrolyte Cathode Coatin g

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SLIDE 12

12

Cathodic Protection

Cathode (Anode) Metallic Path Cathode Electrolyt e Anode

Cathodic Protection

  • Galvanic

–Uses the energy inherent in different materials to create current flow.

  • Impressed Current

–Uses an outside power source to create current flow.

Galvanic Cathodic Protection

  • Low Cost
  • Limited current output
  • Often used in new construction

applications

  • Typically used with coatings for

corrosion control

  • Typically used with dielectric fittings

to contain current

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SLIDE 13

13

Galvanic Cathodic Protection

  • Magnesium and Zinc are common

materials for underground applications

  • Most common UST application is

the sti-P3 tank

  • Common application is for flex

connectors used with FRP piping

  • Does not require monthly

monitoring

Galvanic Cathodic Protection

DIRECT ANODE CONNECTION

Anode Tank Current Flow

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SLIDE 14

14

STI-P3 DESIGN FEATURES

  • Coating: Urethane, Coal Tar

Epoxy,FRP

  • Electrical Isolation: Nylon

Bushing, Flange Isolation

  • Galvanic Anodes: Magnesium,

Zinc or both

Impressed Current Cathodic Protection

  • Unlimited power available
  • Typically used where large surface

areas must be protected

  • Often the only choice for upgrade of

existing tank systems

  • Requires bi-monthly rectifier monitoring
  • Allows maximum flexibility in design
  • Can create electrolytic corrosion
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SLIDE 15

15

Typical Impressed Current System

24” 10 ’

Section 3 Testing Equipment

Testing Equipment

10 A V/OHM OFF

V V

300mV

  • 850

300 mA COM

A A

Reference Cells Voltmeters Test Leads

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SLIDE 16

16

Multimeters

OFF ON AMPROBE AM-12 V V A

1000 200 20 2000

m

20K 2000 K 200 K 200 2000 2000

m

200m 20m

10A

2000 u 2000

m

m 200 20m

10A

200 750

A V COM A

2A MAX ! !

10A

10A MAX ! 500V MAX 1000V 750V MAX

LO BAT

  • High input

impedance 10 MΩ minimum

  • High internal

resistance limits error in measurements

Multimeters

10 A COM

OFF V V 300 mV A A

mA 300 V FUSED

FLUKE 75 SERIES II MULTIMETER

Auto Scale – Useful, not mandatory

V

UNITS OF MEASURE

MILLIVOLT = 0.001 VOLTS VOLT = 1.000 VOLTS KILOVOLT = 1,000.000 VOLTS MEGAVOLT = 1,000,000.000

Do not mix units, i.e., use Volts with Amps and millivolts with milliamps

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SLIDE 17

17

Which TERMINAL CONNECTIONS are used for each type of measurement?

Multimeter

10 A V/OHM OFF

V V

300mV 300 mA COM

A A

Multimeters

OFF ON AMPROBE AM-12 V V A

1000 200 20 2000

m

20K 2000 K 200 K 200 2000 2000

m

200m 20m

10A

2000 u 2000

m

m 200 20m

10A

200 750

A V COM A

2A MAX ! !

10A

10A MAX ! 500V MAX 1000V 750V MAX

LO BAT

  • Calibrate

meters at least annually, in accordance with manufacturers instructions Copper/Copper Sulphate Reference Cell

–Use 99% pure Copper Sulphate crystals –Add distilled water or special antifreeze solution, about ¾ full, at least night before use –Crystals must be visible to know that solution is saturated and good for use –Reference cell liquid should be clear blue, not milky 4

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18

REFERENCE CELLS

Calibrate at least yearly, If used frequently, calibrate

weekly or when exposed to contaminants

Reference cells are calibrated

by comparing to “virgin” reference cell that is not used in field (See procedure, sect 1)

4

TEST LEADS

Check your Test Leads

FRAYED ENDS SPLICES

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SLIDE 19

19

TEST LEADS

Poorly insulated test lead in puddle of water will create error in measurement

POND

V

Section 4 CP test – sti-P3 tank

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SLIDE 20

20

  • 0.00

0.00 + +

  • Basic Test Equipment

Basic Test Equipment

DC DC Voltmeter Voltmeter Meter Leads Meter Leads Reference Reference Electrode Electrode (Cell) (Cell)

volts with amps

  • 0.90

0.90

+ +

  • TANK

TANK Reference cell Reference cell placed over placed over structure structure Negative meter lead to reference Negative meter lead to reference Positive meter lead to structure Positive meter lead to structure via test station connection via test station connection

Tank to soil potential Tank to soil potential

Tank to soil potential readings

  • Place reference cell in moist soil or

backfill

  • Fuel, frost, vegetation will affect

readings

  • Do not place reference cell on

concrete

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SLIDE 21

21

Make good electrical connection to tank

Galvanic Cathodic Protection

WITH TEST STATION

Anode Tank Current Flow

Test Station

Summary of Test Procedure for sti-P3 Structure Potentials

  • Set Meter to 2 DC Volts (unless auto-

adjusting)

  • Take the cap off the reference cell
  • Plug black lead into the negative terminal
  • n multi-meter and clip to reference cell.
  • Place red lead into the positive terminal and

clip to the structure under test.

  • Place reference cell in remote earth –

normally 30 ft from tank, adding water to dirt as needed

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22

Summary of Test Procedure For sti-P3 Structure Potentials

  • Record the measurement and

reference cell placement on site map

  • Move reference cell to center of tank
  • Continue moving reference as needed

to obtain required number of readings & accurate test.

  • Record all measurements and

reference cell placements on site map

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SLIDE 23

23

CP Test Stations

Local Potential

Reference cell is directly over tank

LOCAL & REMOTE TESTING OF GALVANIC CP SYSTEMS

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24

Remote Potential

Reference cell is 25-100 feet away from tank

LOCAL & REMOTE TESTING OF GALVANIC CP SYSTEMS

  • Mitigate environmental factors that

can influence test measurements

  • ver tank (“shielding”)
  • Eliminate influence nearby anodes

can have on test measurements

  • ver tank (“raised earth”)

WHY MEASURE THE REMOTE? WHAT DOES THE LOCAL POTENTIAL MEASURE?

Reference Cell radius of influence = 4X height above structure 4X Only the top portion of tank is measured 3 test point rule commonly applied

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SLIDE 25

25

Accurate Structure Potentials

Observe the potential. If it's jittery or unstable re-adjust clips Check electrode contact Check the test leads

CIRCUIT RESISTANCE

STRUCTURE CONTACT RESISTANCE V

R

c

( )

STRUCTURE CONNECTIONS

STRUCTURE CONNECTIONS

Poor Cadweld Connection Test Lead

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SLIDE 26

26

TEST LEADS

TEST LEADS

FRAYED ENDS SPLICES

TEST LEADS

POORLY INSULATED TEST LEAD

POND

V UNDERGROUND PIPELINE

Concrete Asphalt Frozen Soil Gravel, Rock, Stone Dry Soil Plastic Lines Beneath Flower Beds

Improper Reference Cell Placement

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SLIDE 27

27

COMMON SENSE

Put on your thinking

  • cap. If the data

doesn't make sense it's probably wrong!! Testing other structures

  • When testing a galvanic cathodic

protection system, you should test all metal structures that routinely contain product

  • Flex connectors
  • Metal product piping
  • Place reference cell away from

anodes

Electrical Isolation

  • Structures that are electrically

isolated do not touch in any way

  • Structures that are electrically

continuous are grounded to each

  • ther
  • Galvanic cathodic protection

normally requires the structure to be isolated.

  • sti-p3 tanks are designed to

electrically isolated from all other

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SLIDE 28

28

Nylon bushings

Not if conduit is sitting on tank Not if conduit is sitting on tank

Electrical Continuity

  • Structures that are electrically

continuous are grounded to each

  • ther
  • Impressed current cathodic

protection requires all underground structures to be continuous with the system.

  • Continuity is critical for ICCS
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SLIDE 29

29

METHODS TO TEST CONTINUITY

  • Do not attempt to test continuity with

an ohm meter (flashlight method).

  • An ohm meter is not a good

instrument for continuity measurements

  • f buried structures due to galvanic

voltages between structures

METHODS TO TEST CONTINUITY FIXED CELL MOVING GROUND

  • Reference cell is placed in remote soil at

least 30 feet from all metallic structures

  • Measure the potentials of various structures

within the facility with respect to the reference cell

  • Potential differences between

measurements should be less than 0 or 1 millivolt

Methods To Test Continuity

FIXED CELL MOVING GROUND

  • Reference cell is placed in remote soil at

least 30 feet from tank and away from all metallic structures

  • Measure the potentials of various structures
  • n site with respect to the reference cell,

such as tank rises, pump, ATG

  • Potential differences between

measurements should be greater than 10 millivolts

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SLIDE 30

30

METHODS TO TEST CONTINUITY POINT TO POINT METHOD

–Electrical contact is made directly to the tank and a separate contact made to another structure –Potential difference should be 0 or 1 mV to verify continuity –Potential difference should be greater than 10 mV to verify isolation –Readings between 2 and 9 mV unsure

Lab C - Continuity

  • Learn two methods to test

underground structures for continuity and isolation.

  • Isolation is the opposite of continuity.
  • Learn what the criteria is to

determine if two structures are either continuous or isolated.

Section 6 CP Test – Impressed Current Cathodic Protection System (ICCS)

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SLIDE 31

31

Rectifier Anode Junction Box

Rectifier Used for Impressed Current Cathodic Protection

Rectifier models differ by manufacturer and project specifications Transformer Taps For Adjusting AC To Diodes Circuit Breaker Panel Meter Shunt Fuse Structure Connection (Negative) Anode Connection (Positive)

Typical Rectifier Components

Diodes To Convert AC To DC Located Behind Panel

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32

TYPICAL RECTIFIER

  • 10. Positive
  • 9. Negative
  • 8. Shunt
  • 7. Voltage
  • 6. Amperage
  • 5. Hour Meter
  • 3. Tap Settings
  • 1. Data Plate
  • 2. On/Off Switch
  • 4. Fuse

3 1 2 4 5 7 8 6 9 10

Impressed Current System

  • The negative

connection from the rectifier ALWAYS goes to the structure being protected!

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SLIDE 33

33

Impressed Current Cathodic Protection

Anode Tank Current Flow Rectifier

+ -

Typical Impressed Current System

24” 10 ’

One math fact you need to know! OHMS LAW

E R I

I = E R E = I x R R = E I

E = Volts, I = Current, R= Resistance

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SLIDE 34

34

SAFETY FIRST!!!! Rectifier Testing

There is 110 or 220 Volts AC to rectifiers Tap the rectifier with the back of your hand before grabbing for the lock. If you’re not comfortable working on a live unit

ƒTurn it off ƒMake your connections ƒTurn it back on ƒMake measurements ƒTurn it off ƒDisconect test leads ƒTurn it back on

DO NOT TURN THE RECTIFIER OFF PRIOR TO INITIAL TEST

Test Procedure for ICCS Structure Potentials

  • 1. Set Meter to 20 DC Volts (unless auto-

adjusting)

  • 2. Take the cap off the reference cell
  • 3. Plug black lead into the negative terminal
  • n multi-meter and clip to reference cell.
  • 4. Place red lead into the positive terminal

and clip to the structure under test.

  • 5. Place reference cell directly over center of

tank, or as close as possible adding water to backfill as needed

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SLIDE 35

35

Test Procedure for ICCS Structure Potentials

  • 6. At rectifier, measure output voltage
  • f rectifier
  • 1. Connect negative end of voltmeter

to negative on rectifier

  • 2. Connect positive end of voltmeter

to positive on rectifier

MEASURE RECTIFIER OUTPUT VOLTAGE Set voltmeter to DC volts Select scale (or auto ranging) Read directly off voltmeter

25 V

Rectifier Voltage Measurements

Shunt 50 mV = 15 A

10 A V/OHM OFF V V 300mV 300 mA COM A A

xxxx

Rectifier Volts

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SLIDE 36

36

Test Procedure for ICCS Structure Potentials

  • 7. At rectifier, using rectifier shunt,

measure output current

  • 1. The following series of slides will

illustrate how to do this.

RECTIFIER SHUNTS Common Ratings 50 mV = 5 A 50 mV = 10 A 50 mV = 15 A The Shunt Rating will be provided on the rectifier or the shunt

OHMS LAW

E R I

I = E R E = I x R R = E I E = Volts, I = Current, R= Resistance

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SLIDE 37

37

RECTIFIER SHUNTS

Common Sizes 50 mV = 5 A 50 mV = 10 A 50 mV = 15 A 10 50 = 0.2 Calculate Shunt Factor 50 mV = 5 A 50 mV = 10 A 50 mV = 15 A 5 50 15 50 = 0.3 = 0.1

Measure Rectifier Current Output

Rectifier Shunt 50 mV=10A Shunt Factor 10 50= 0.2

Current = 20 mV x 0.2 = 4 Amps = 4000 mA

Set voltmeter to mV scale

20 mV

Rectifier Current Measurements

Turn Meter to millivolt scale Connect Red Test Lead to one screw as shown Connect Black Test Lead to other screw as shown Record the millivolt reading Record the shunt rating Calculate the actual current output and compare to the Rectifier Ammeter.

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SLIDE 38

38

Rectifier Current Measurements

Shunt 50 mV = 15 A

10 A V/OHM OFF V V 300mV 300 mA COM A A

xxxx

Rectifier Current

Test Procedure for ICCS Structure Potentials

  • 8. Record “on” reading at first reference

cell location for Structure #1

  • 9. Take instant off potentials at same

location 10.Take minimum 3 readings on all tanks 11.Each time reference cell is moved, take instant off potential

STRUCTURE CONNECTIONS

RUST

Good electrical contact to structure critical Use test wires if present. Probe interior of tanks to verify wires are continuous Do not use rectifier negative cables for potential measurements Verify continuity between fills, tank risers, etc.

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SLIDE 39

39

Instant off readings:

1) See Procedure in Section 1 2) Record tank potential “on” readings 3) Temporarily interrupt rectifier 4) Record 2nd reading on voltmeter when anode disconnected as “Instant Off” 5) The 2nd number is used because of the way digital voltmeters display data Current Interrupters

On CHARGER SYNC CURRENT INTERRUPTER Model JR-1 On Off Open Closed START RELAY M.C. Miller Ringwood, New Jersey 07456 MCM Clock Set Clock Set On Cy cle Off Cy cle 1 2 3 7 8 9 4 5 6 Stop Set Enter

Shunt 50 mV = 15 A

To Anodes To Tank

Eliminate IR Drop by temporarily turning the rectifier off When I = 0, I x R =0 and IR Drop error is removed from measurement. A Current Interrupter is an ON-OFF switch that

  • perates on an operator

determined timing cycle

Test Procedure for ICCS Structure Potentials

12.Record the measurement and reference cell placement on site map

  • 13. Continue moving reference as

needed to obtain required number of readings & accurate test.

  • 14. If needed for 100 mV criteria, turn

rectifier off and repeat after 1 – 24 hours to obtain static reading

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SLIDE 40

40

REFERENCE CELL LOCATIONS FOR TANK-TO-SOIL POTENTIALS

  • Over or near the

tank and piping

  • Maximize distance

from anodes Place reference cell directly

  • nto soil

Static potential

  • Static reading is sometimes called

the depolarized potential… it is the potential of the structure without the influence of any cathodic protection

  • n it.
  • The static potential can be obtained

by leaving rectifier off until a steady reading is obtained on the voltmeter. Test Procedure for ICCS Structure Potentials

  • 15. Check all structures for continuity

with tanks and ICCS

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SLIDE 41

41

Cathodic Protection Monitoring

Anode Tank

Current Flow

+ -

Voltmeter Reference Cell

Must have: Electrical continuity of all protected facilities Good electrical contact with tanks Adequate records/drawings of buried facilities and cathodic protection equipment

At rectifier record: Rectifier operating DC Volts and DC Amperes Hour of operations if meter present Site Location Rectifier Serial No.

Test Procedure for ICCS Structure Potentials

  • 16. If anode box is present, calculate

current through each anode. Anode Circuit Shunts

Common Size = 0.01 ohm

Instead of using Ohm’s Law - A shunt “factor” of 100 can be used for these wire type shunts when calculating circuit current

Anode Leads (8 in this system) Rectifier Positive Lead “Bus Bar” Calibrated Shunt JUNCTION BOX

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SLIDE 42

42

Measure Circuit Current

7 mV

Calibrated Shunt = 0.01 ohm Current = 7 mV x 100 = 700 mA

Shunt “Factor” = 100

Test Procedure for ICCS Structure Potentials

  • 17. Compare total anode current output

to measured rectifier output from step 7. Comparing Total Circuit Current To Rectifier Current Output

Positive Circuit Anode 1 = 700 mA Anode 2 = 450 mA Anode 3 = 0 mA Anode 4 = 550 mA Anode 5 = 1200 mA Anode 6 = 680 mA Anode 7 = 0 mA Anode 8 = 400 mA TOTAL = 3980 mA Negative Circuit Tank 1 = 1125 mA Tank 2 = 880 mA Tank 3 = 1000 mA Tank 4 = 620 mA TOTAL = 3625 mA Remember: Rectifier Output measured as 4000 mA

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SLIDE 43

43

Comparing Total Circuit Current To Rectifier Current Output

  • Conclusions
  • Current distribution among anodes good
  • 2 of the anodes are “dead” (0 current measured)
  • Anode output (3900 mA) nearly equal to rectifier output

(4000 mA)

  • Most of the current is reaching tanks (only lost 300 mA)
  • Impressed Current system is probably providing adequate

protection

Use Ohm's Law to find Current

E R I

Practice Problem #1 E = 6 mV R = 0.01 ohm Cover up the I And you're left with E R = 6 mV 0.01 ohm = 600 mA

How much Current is Flowing?

E R I Practice Problem #2 Shunt resistance = R = 0.001 ohm E = 6.5 mV E = 3.2 mV E = 4.7 mV

1 2 3

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SLIDE 44

44

Practice Problem #2

E R I

E R = 6.5 mV 0.001 ohm = 6500 mA = 6.5 Amps How much Current is Flowing through Shunt 1 ? Cover up the I And you're left with

Cathodic Protection Surveys

  • Surveys must be performed by a

cathodic protection tester

  • Surveys should include:

– Potential survey – Continuity testing (for impressed systems) – Rectifier operation (for impressed systems) – Shunt readings (for impressed current systems)

  • Always include a detailed report of

findings and recommendations for continued operation.

Cathodic Protection Surveys

  • At rectifier record:

–Rectifier operating DC Volts and DC Amperes –Hour of operations if meter present –Site Location –Rectifier Serial No.

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SLIDE 45

45

Section 8 Criteria

Cathodic Protection Criteria

measured with a copper/copper sulfate reference cell

  • -850 mV Structure to Soil

Potential

–Measurement must allow for IR Drop.

  • 100 mV Polarization

NACE CRITERIA FOR STEEL AND CAST IRON

100 mV Polarization

–Polarization formation –Polarization decay

_ _ _ _ _ Instant "Off" Polarization Decay

  • 0.9
  • 0.8
  • 0.7
  • 0.6
  • 0.5
  • 0.4

_

}

> 100 mV

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SLIDE 46

46

IR DROP IN VOLTAGE MEASUREMENTS

Current flow through a resistor creates a voltage drop

E R I

IR drop must be removed from the measurement to obtain the actual potential of the structure.

1 2 3 TIME POTENTIAL (MV) 1400 1200 1000 800 600 400 200 4 5 6 7 8

Eliminate the current flow for a short time period, I = 0 AND I x R = 0

100 MV shift

  • A tank meets the 100 mV shift

criteria, if:

–The tank is not connected to significant amounts of copper or stainless steel, and –The difference between the instant off potential and the native potential (depolarized potential) is at least 100 mV. V “instant off” – V “off” ≥ 100 mV

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SLIDE 47

47

Cathodic Protection Criteria

measured with a copper/copper sulfate reference cell

  • -850 mV Structure to Soil Potential

–Measurement must allow for IR Drop.

  • 100 mV Polarization
  • STI-P3 Criterion -850 mV Structure

to Soil Potential.

Anodes permanently connected to

LAB

  • Criteria

–100 mV

Man made corrosion An external source of direct current (DC) traversing through the soil (electrolyte) strays onto the structure Cathodic reactions occur (protection) where the current is picked up by the structure Anodic reactions occur (corrosion) where the current leaves the structure

STRAY CURRENT

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SLIDE 48

48

+

  • DC

GENERATOR TRANSIT POWER LINE ANODIC AREA CATHODIC AREA RAIL EARTH

Steel Pipe

CORROSION Protection

STRAY CURRENT

Section 9 Paperwork Cathodic Protection Monitoring

  • All systems must provide the ability

to test the cathodic protection system

  • Impressed Current Rectifiers must

be inspected at least every two months.

  • Cathodic protection systems must

be surveyed by every three years (or more often if state requires it )

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SLIDE 49

49

Cathodic Protection Surveys

  • Surveys must be performed by a

cathodic protection tester

  • Surveys should include:

– Potential survey – Continuity testing (for impressed systems) – Rectifier operation (for impressed systems) – Shunt readings (for impressed current systems)

  • Always include a detailed report of

findings and recommendations for continued operation.

Section 10 Additional Field Tests

  • Continuity testing

Continuity testing

  • Fixed cell moving ground

Fixed cell moving ground

  • Point to point contact method

Point to point contact method

  • Current requirement test

Current requirement test

  • Soil resistivity testing

Soil resistivity testing

Troubleshooting Troubleshooting tests tests

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SLIDE 50

50

Soil Resistivity Measurements

5 FT 5 FT 5 FT

C1 P1 P2 C2

NULL 1 2 3 4 5 6 7 8 9 10 11

HIGH LOW NULL SENSITIVITY

P2 C2 C1 P1

BATTERY CHECK

MODEL 400 SOIL RESISTANCE METER .01 .1 1 100 100K 1K 10K 10

MULTIPLY BY

Soil Resistivity values are used to determine the number of anodes required if an STI-P3 tank requires supplemental anodes.

NULL 1 2 3 4 5 6 7 8 9 10 11

HIGH LOW NULL SENSITIVITY

P2 C2 C1 P1

BATTERY CHECK

MODEL 400 SOIL RESISTANCE METER .01 .1 1 100 100K 1K 10K 10

MULTIPLY BY

Soil Resistivity Test

(Big dial) * (Small dial) * (Multiplier) Example: Pin spacing = 10 ft 5” (therefore M = 2000) Big dial = 2.2 Small dial = 1 2.2* 1 * 2000 = 4400 ohm-cm

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SLIDE 51

51 Terminology Terminology

  • Resistance (R)= measured in ohms

Resistance (R)= measured in ohms S

S

  • Soil Resistivity is measured in

Soil Resistivity is measured in

  • hm
  • hm-
  • cm (ohm

cm (ohm-

  • centimeters)

centimeters)

  • Soil resistivity is a measure of how

Soil resistivity is a measure of how corrosive the soil is corrosive the soil is

  • The lower the number, the more

The lower the number, the more corrosive corrosive

Current Requirement Test Current Requirement Test

Limited to sti-P3 tanks that require no more than 30 milliamps of current to bring the tank to protected levels.

Anode Tank

Current Flow

Rectifier

Impressed Current

10 A 300 mA V/OHM COM OFF V V 300 mV A A
  • 1.120
10 A 300 mA V/OHM COM OFF V V 300 mV A A

0.030

(+) (-)

Temporary Anode Rod at least 100' from tank end

  • pposite reference

cell location driven to depth necessary to achieve required current Positive Battery Terminal Connection to Temporary Anode Rod 12 Volt Battery Negative Battery Terminal Connection to STI-P3 UST thru milliammeter Digital VOM meter set to DC Milliampere range Digital VOM meter set to DC Volts range Good Electrical Connection to Tank - PP2 or equal Good Electrical Connection to Tank through Fill Pipe or equal Copper-Copper Sulfate Reference Electrode at least 30' from end of tank opposite temporary anode location Negative (Common/Black) meter leads Positive (Red) Meter Leads 100' Min.

STI-P Tank

3 30' Min.

Figure 1 Current Requirement Test Setup

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SLIDE 52

52

Recommended Practice for Addition of Recommended Practice for Addition of Supplementary Anodes Supplementary Anodes

  • STI R972

STI R972-

  • 01 (In Section 4, class book)

01 (In Section 4, class book)

  • Available on STI Web Site

Available on STI Web Site www.steel tank.com www.steel tank.com

  • History behind original formation of

History behind original formation of document was to assist tank owners in document was to assist tank owners in testing their P3 tanks for cathodic testing their P3 tanks for cathodic protection protection

Record Record -

  • Keeping

Keeping

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SLIDE 53

53

Lorri Grainawi Lorri Grainawi Director of Technical Services Director of Technical Services Steel Tank Institute Steel Tank Institute Phone: (847) 438 Phone: (847) 438-

  • 8265 x244

8265 x244 lgrainawi@steeltank.com lgrainawi@steeltank.com www.steeltank.com www.steeltank.com