on the emissions of hcfcs and cfcs potentially related to
play

On the Emissions of HCFCs and CFCs Potentially Related to HFC - PowerPoint PPT Presentation

On the Emissions of HCFCs and CFCs Potentially Related to HFC Production Martin K. Vollmer 1 , Matt Rigby 2 , Cathy Trudinger 3 , L. Paul Steele 3 Jens Mhle 4 , Stephan Henne 1 , Sunyoung Park 5 AGAGE+ Team 6 . 1 Empa, Material Science and


  1. On the Emissions of HCFCs and CFCs Potentially Related to HFC Production Martin K. Vollmer 1 , Matt Rigby 2 , Cathy Trudinger 3 , L. Paul Steele 3 Jens Mühle 4 , Stephan Henne 1 , Sunyoung Park 5 AGAGE+ Team 6 . 1 Empa, Material Science and Technology, Dubendorf, Switzerland 2 University of Bristol, School of Chemistry 3 CSIRO Oceans and Atmosphere 4 Scripps Institution of Oceanography 5 Kyungpook Nat Univ, South Korea 6 Advanced Global Atmospheric Gases Experiment and contributions from Firn Air Community, NOAA, ... NOAA ESRL, Boulder, 23 – 24 May. 2017

  2. Halocarbons 1 st Generation 2 nd Generation 3 rd Generation 4 th Generation Montreal Protocol CFCs PFCs Halons HCFCs HFOs CCl 4 / CH 3 CCl 3 HFCs / CH 3 Br Kyoto Protocol Hydrochloro- fluorocarbons Perfluorocarbons Hydrofluoroolefines Chlorofluorocarbons Hydrofluorocarbons HFO-1234yf, HFO- CFC-11, CFC-12, HCFC-22, HCFC-141b, HFC-32, HFC-125, 1234ze(E), HCFO- CFC-13, CFC-113, HCFC-142b, HCFC-31, HFC-134a, HFC-245fa, 1233zd(E), .... CFC-114, CFC-115 HCFC-133a, HCFC- PFC-116, PFC-218 ... H-1211, H-1301, .... 131, HCFC-132b.... Materials Sci ence & Technolog y

  3. HCFC-133a (CF 3 CH 2 Cl, lifetime 4.5 yr) Medusa- GCMS Empa-2013 calibration scale AGAGE 12-box model updates of Vollmer et al., 2015 Materials Sci ence & Technolog y

  4. HCFCs as intermediates in the HFC production HCFC-133a Trichloroethylene HF HF HCFC-133a (Chlorotrifluoroethane) HF Global Emissions: HF 2 kt/yr HF HFC-134a (Tetrafluoroethane) Global Emissions: 180 kt/yr Materials Sci ence & Technolog y

  5. HCFC-133a at selected AGAGE sites Gosan Mol Fraction [ppt] Jungfraujoch Cape Grim Time (years) Materials Sci ence & Technolog y

  6. HCFC-133a (CF 3 CH 2 Cl, lifetime 4.5 yr) Materials Sci ence & Technolog y

  7. HCFC-31 (CH 2 ClF, lifetime 1.2 yr) updates of Schoenenberger et al., 2015 Materials Sci ence & Technolog y

  8. HCFCs as intermediates in the HFC production HCFC-31 HCFC-133a Methylene Trichloroethylene Chloride HF HF HCFC-31 HCFC-133a (Chlorofluoromethane) (Chlorotrifluoroethane) HF Global Emissions: Global Emissions: HF 0.6 kt/yr 2 kt/yr HF HFC-134a HFC-32 (Tetrafluoroethane) (Difluoromethane) Global Emissions: Global Emissions: 20 kt/yr 180 kt/yr Materials Sci ence & Technolog y

  9. Global CFC-115 Observations (CClF 2 CF 3 , lifetime 540 yr) Materials Sci ence & Technolog y

  10. Global CFC-115 emissions C 2 Cl 4  C 2 ClF 5 (CFC-115)  C 2 HF 5 (HFC-125) ~0.4 kt/yr (excess) 40 kt/yr Materials Sci ence & Technolog y

  11. CFC-115 Impurities in the refrigerant HFC-125 (leaking ACs) Relationship dependent on AC Refill Batch CFC-115 / HFC-125 = 1 – 7 x 10 -4 mol/mol 40 kt/yr HFC-125  4 – 28 t/yr CFC-115 Materials Sci ence & Technolog y

  12. CFC-115 at selected AGAGE sites Gosan Cape Grim Jungfraujoch Time (years) Materials Sci ence & Technolog y

  13. Conclusions Find Halocarbons with no known purposeful end use  Speculate to leak out as intermediates/byproducts from HFC synthesis  Observe and determine emission / use as tracers  Acknowledgments Halclim (Swiss Federal Office for the Environment, FOEN)  International Foundation High Altitude Research Station Jungfraujoch and  Gornergrat (HFSJG) AGAGE (Advanced Global Atmospheric Gases Experiment)  Station personnel at sites  Provider of archived air samples  Materials Sci ence & Technolog y

  14. Title Materials Sci ence & Technolog y

  15. Title Materials Sci ence & Technolog y

  16. Title Materials Sci ence & Technolog y

  17. CFC-115 emission hotspots (based on Gosan Measurements) Materials Sci ence & Technolog y

  18. End Halclim (Swiss Federal Office for the Environment, FOEN)  International Foundation High Altitude Research Station Jungfraujoch and  Gornergrat (HFSJG) AGAGE (Advanced Global Atmospheric Gases Experiment)  Station personnel at sites  Provider of archived air samples  Materials Sci ence & Technolog y

  19. Title Materials Sci ence & Technolog y

  20. HCFCs/CFCs as intermediates in the HFC production HCFC-31 HCFC-133a CFC-115 Tetrachloro- Methylene Trichloro- ethylene Chloride ethylene HF HF CFC-115 HCFC-133a HCFC-31 (Chlorofluoro- (Chlorotrifluoro methane) HF ethane) HF HF HFC-134a HFC-32 HFC-125 (Tetrafluoro (Difluoro- (Pentafluoro- ethane) methane) ethane) Materials Sci ence & Technolog y

  21. HCFCs as intermediates in the HFC production HCFC-31 HCFC-133a Methylene Trichloroethylene Chloride HF HF HCFC-133a HCFC-31 (Chlorofluoromethane) (Chlorotrifluoroethane) HF HF HF HFC-134a HFC-32 (Tetrafluoroethane) (Difluoromethane) Materials Sci ence & Technolog y

  22. HCFCs as intermediates in the HFC production HCFC-31 HCFC-133a Methylene Trichloroethylene Chloride HF HF HCFC-133a HCFC-31 (Chlorofluoromethane) (Chlorotrifluoroethane) HF HF HF HFC-134a HFC-32 (Tetrafluoroethane) (Difluoromethane) Materials Sci ence & Technolog y

  23. Global CFC-115 Observations (CClF 2 CF 3 , lifetime 540 yr) Materials Sci ence & Technolog y

  24. Global CFC-115 emissions C 2 Cl 4  C 2 ClF 5 (CFC-115)  C 2 HF 5 (HFC-125) Materials Sci ence & Technolog y

  25. Halocarbons 1 st Generation 2 nd Generation 3 rd Generation 4 th Generation Greenhouse Gases Montreal Protocol CFCs PFCs Halons HCFCs HFOs CCl 4 / CH 3 CCl 3 HFCs / CH 3 Br Ozone Depletion Substances Kyoto Protocol Hydrochloro- fluorocarbons Perfluorocarbons Hydrofluoroolefines Chlorofluorocarbons Hydrofluorocarbons HFO-1234yf, HFO- CFC-11, CFC-12, HCFC-22, HCFC-141b, HFC-32, HFC-125, 1234ze(E), HCFO- CFC-13, CFC-113, HCFC-142b, HCFC-31, HFC-134a, HFC-245fa, 1233zd(E), .... CFC-114, CFC-115 HCFC-133a, HCFC- PFC-116, PFC-218 ... H-1211, H-1301, .... 131, HCFC-132b.... Materials Sci ence & Technolog y

  26. HCFC-31 at an urban site (Zurich-Dubendorf) Time (years) Materials Sci ence & Technolog y

Download Presentation
Download Policy: The content available on the website is offered to you 'AS IS' for your personal information and use only. It cannot be commercialized, licensed, or distributed on other websites without prior consent from the author. To download a presentation, simply click this link. If you encounter any difficulties during the download process, it's possible that the publisher has removed the file from their server.

Recommend


More recommend