Vapor Intrusion (VI) Investigation Using the TAGA Mobile - - PowerPoint PPT Presentation

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Vapor Intrusion (VI) Investigation Using the TAGA Mobile - - PowerPoint PPT Presentation

Vapor Intrusion (VI) Investigation Using the TAGA Mobile Laboratories CLU-IN Webinar 29 August 2018 David Mickunas US EPA/ERT TAGA MOBILE LABORATORY Trace Atmospheric Gas Analyzer (TAGA) Mobile Laboratories Trace Atmospheric Gas Analyzer


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Vapor Intrusion (VI) Investigation Using the TAGA Mobile Laboratories CLU-IN Webinar 29 August 2018

David Mickunas US EPA/ERT

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SLIDE 2

TAGA MOBILE LABORATORY

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SLIDE 3

Trace Atmospheric Gas Analyzer (TAGA) Mobile Laboratories

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Trace Atmospheric Gas Analyzer (TAGA)

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SLIDE 5

Low Pressure Chemical Ionization (LPCI) Source

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TAGA Operational Process Animation

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SLIDE 7

Parent/Daughter Ion Concentration Profile for Trichloroethene

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SLIDE 8

Parent/Daughter Ion Profile for Trichloroethene

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SLIDE 9

Gas Chromatograph/Mass Spectrometer with Loop Injector for Analysis of Volatiles Compounds Collected in Tedlar Bags

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SLIDE 10

1 1 9 2 3 4 5 7 6 8

Carrier In Carrier Out To GC 50 uL Loop Internal Standard Load Internal Standard Vent 5 mL Loop Sample Load Sample Vent

10-Port Valve Load Position

(flow in direction of arrow)

10-Port Valve Injecton Position

(flow in direction of arrow)

Carrier In 50 uL Loop Internal Standard Load Internal Standard Vent 5 mL Loop Sample Load Sample Vent Carrier Out To GC

1 2 3 4 5 6 7 8 9 1

10-Port Gas Valve Sample Introduction System For The GC/MS

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SLIDE 11

Driver and Passenger Seating with Monitor

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SLIDE 12

VAPOR INTRUSION

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Comparison Between Water And Air Contamination

WATER Basis: 2 liters/day Assume: TCE concentration is 5 ppb or 5 micrograms/liter (µg/L) Daily impact: 2 L/day * 5 µg/L = 10 µg/day AIR Basis: 20 cubic meters/day Assume: TCE concentration is 1 ppbv or 5.4 micrograms/cubic meter (µg/m3) Daily impact: 20 m3/day * 5.4 µg/m3 = 108 µg/day

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SLIDE 14

Lines of Evidence:

  • Groundwater spatial (and vertical profiling, if appropriate) data with modeling
  • Potable groundwater analysis
  • Soil gas spatial concentrations (and vertical profiling, if appropriate), including subslab,

with vertical profiling

  • Ambient, crawlspace, and inside air concentrations and source determinations
  • Building construction and conditions
  • Constituent ratios
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Groundwater Spatial (and Vertical Profiling, if Appropriate) Data With Modeling

Membrane Interface Probe with Geoprobe Overburden Groundwater Installation Oil Bailer Operations Drilling Operations Well Field Site Groundwater Sampling Operations Soil Gas Probe Installation Drilling Operations Hollow Stem Augers with Geoprobe

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Soil Gas Spatial Concentrations (and Vertical Profiling, if Appropriate), Including Subslab, with Vertical Profiling Sampling Analyses

Tedlar Bag Sampling Sorbent Tubes Summa Canister with Flow Regulator and 3-Way Valve TAGA Mobile Laboratory Permanent Gas – Gas Chromatograph Volatile Organic Compounds – Gas Chromatograph/Mass Spectrometer Slab-Slab Probe

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Ambient, Crawlspace, and Inside Air Concentrations and Source Determinations

A B C D E F G H I J K L M N O P Q R S T U V W X Y Z A A B B C C D D E E F F G G H H I I J J . 0 . 5 1 . 0 1 . 5 2 . 0 2 . 5 3 . 0 3 . 5 5 1 1 5 2 2 5 3 D L Q L H L B E N Z E N E ( H A Z 4 1 9 0 ) U n i t s i n P P B T i m e I n M i n u t e s A B C D E F G H I J K L M N O P Q R S T U V W X Y Z A A B B C C D D E E F F G G H H I I J J 1 2 3 4 5 6 7 8 5 1 1 5 2 2 5 3 D L Q L T O L U E N E ( H A Z 4 1 9 0 ) U n i t s i n P P B T i m e I n M i n u t e s A B C D E F G H I J K L M N O P Q R S T U V W X Y Z A A B B C C D D E E F F G G H H I I J J . 0 . 5 1 . 0 1 . 5 2 . 0 2 . 5 3 . 0 3 . 5 4 . 0 4 . 5 5 . 0 5 1 1 5 2 2 5 3 D L Q L X Y L E N E ( H A Z 4 1 9 0 ) U n i t s i n P P B T i m e I n M i n u t e s A B C D EF G H I J K L M N O P Q R S T U V W X Y Z AA BB CC DD EE FF GG HH II 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5 10 15 20 25 30 DL QL HL BENZENE (HAZ4291) Units in PPB Time In Minutes A B C D EF G H I J K L M N O P Q R S T U V W X Y Z AA BB CC DD EE FF GG HH II 1 2 3 4 5 6 7 8 9 5 10 15 20 25 30 DL QL TOLUENE (HAZ4291) Units in PPB Time In Minutes A B C D EF G H I J K L M N O P Q R S T U V W X Y Z AA BB CC DD EE FF GG HH II 1 2 3 4 5 6 7 8 9 10 5 10 15 20 25 30 DL QL XYLENE (HAZ4291) Units in PPB Time In Minutes A B C D E F G H I J K L M N O P QR S T U V W X Y Z AA BB CC DD EE FF GG HH II JJ KK LL MM 100 200 300 400 500 600 700 800 900 1000 5 10 15 20 25 30 DL QL HL BENZENE (HAZ6039) Units in PPB Time In Minutes A B C D E F G H I J K L M N O P QR S T U V W X Y Z AA BB CC DD EE FF GG HH II JJ KK LL MM 1 2 3 4 5 6 5 10 15 20 25 30 DL QL TOLUENE (HAZ6039) Units in PPB (Thousands) Time In Minutes A B C D E F G H I J K L M N O P QR S T U V W X Y Z AA BB CC DD EE FF GG HH II JJ KK LL MM 1750 2000 2250 XYLENE (HAZ6039)

Monitoring Lifestyle Sources

Fig u r e 18 a M ob ile M on ito ring P a th T w o , A R M N 02 2 Fig u r e 18 a M ob ile M on ito ring P a th T w o , A R M N 02 2 A B C D E F G H I J K L M N O 5 1 0 1 5 2 0 2 5 3 0 0 . 0 2 . 5 5 . 0 7 . 5 1 0 . 0 1 2 . 5 1 5 . 0 Q L D L T e t r a c h l o r o e t h e n e ( A R M N 0 2 2 ) U n i t s i n p p b v T i m e i n m i n u t e s

Ambient Air Sampling Crawlspace Air Sampling Indoor Air Sampling Monitoring Outside Ambient Air Sources

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Building Construction And Conditions

Historical Pre-Revolutionary Era Brick House Dover, DE Split-Level House Hopewell, NY Multi-Apartment Building Ann Arbor, MI Historical Revolutionary Era Stone House Hereford Township, PA Single –story House with Crawlspace San Antonio, TX 2-Story New Construction House Hopewell, NY Hand-Dug Earthen Tunnel Basement Stone-Walled Basement Rough Poured Cement Floor with Hand-Hewned Posts

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Vapor Intrusion Sites

ABC One Hour Cleaners, Jacksonville, NC – Region 4 Armen Cleaners Site, Ann Arbor, MI – Region 5 Army Corps of Engineers Raritan Center Site, Edison, NJ – Region2 Berkley Products Site, Akron, PA – Region 3 Brewster Site , Brewster, NY – Region 2 Brick Township Landfill, Ocean City, NJ – Region 2 Brook Indsutries Bound Brook, NJ – Region 2 Butz Landfill Site, Jackson, PA – Region 3 Carter Carburetor Site, St. Louis , MO – Region 7 Charlevoix Groundwater Site, Charlevoix, MI – Region 5 Chemical Leaman Site, Gloucester, NJ – Region 2 Chillum Site, Chillum, MD – Region 3 Coldwell Trucking Site, Essex City, NJ – Region 2 Conell Dublier Site, South Plainfield, NJ – Region 2 Corry Site, Corry, PA – Region 3 Crossley Farm Site, Hereford Township, PA – Region 3 Crown Cleaners Site, Carthage, NY – Region 2 Delforge Site, Grand Prairie, TX – Region 6 Delmar Water Supply Well Site, Dalmar, DE - Region 3 Diaz Site, Holley, NY – Region 2 Dover Gas Light Site, Dover, DE - Region 3 Facet Enterprise Site, Elmira Heights, NY – Region 2 Federal Creosote Site, Manville, NJ – Region 2 Former Kelly Air Force Base, San Antonio, TX – Region 6 Former Manufactured Gas Plant Site, West Palm Beach, FL – Region 4 Fulton Site, Garden City, NY - Region 2 Garden State Cleaners Site, Buena Borough, NJ – Region 2 Grenada Manufacturing Site, Grenada, MS - Region 4 Georgia Street Site, Washington DC - Region 3 Glendive Site, Glendive, MT – Region 8 Grand Rapids VI ER, Grand Rapids, MI - Region 5 Grand Traverse Overall Supply Site, Traverse City, MI – Region 5 Grants Site, Grants NM – Region 6 Henry’s Dry Cleaners Site, Laconia, NH – Region 1 Hidden Lane Landfill, Sterling, VA - Region 3 Higgins Disposal Site, Franklin Township, NJ – Region 2 Highway 71/72 – Region 6 Hopewell Precision Site, Hopewell Junction, NY – Region 2 Kaufman and Minteer Site, Jobstown, NJ – Region 2 Kentucky Avenue Site, Horseheads, NY – Region 2 Laureldale Groundwater Site – Grants Pass, OR – Region 10 Lawrence Aviation Site, Port Jefferson, NY – Region 2 Lehigh Valley Railroad Derailment Site, LeRoy, NY – Region 2 Liberty Industrial Finishings Site, Oyster Bay, NY – Region 2 Lillis Drive Site, Cuhahoga, Falls, OH - Region 5 Little Valley Site, Little Valley, NY – Region 2 Love Canal, Love Canal, NY – Region 2 Mackenzie Chemical Works, Suffolk County, NY – Region 2 Macon Naval Ordnance Plant, Macon, GA - Region 4 Mansfield Dump Site, Byram Township, NJ – Region 2 Marathon Battery Site, Putman City, NY – Region 2 Mattiace Site, Glen Cove, NY – Region 2 Mayfield Road Site - Mayfield Heights, OH - Region 5 McGaffey and Main Site, Roswell, NM – Region 6 MEW Site, Mountain View, CA – Region 9 Mills Gap Road Site, Skyland, NC - Region 4 Mitral Site, Harwinton, CT – Region 1 Moffett Field, Moffett, CA – Region 9 Mohonk Site – High Falls, NY – Region 2 Motorola 52nd Street Site, Phoenix, AZ – Region 9 Mueller Copper Tubing Site, Wynne, AR- Region 6 Murray Laundry Site, Salt Lake City, UT – Region 8 Nebraska Former Ordnance Plant Site, Mead, NE – Region 7 Olean Cleaners, Olean, NY – Region 2 Parker Solvent Site, Little Rock, AR – Region 6 Passyunk Soil Gas Site, Philadelphia, PA – Region 3 Peninsula Blvd Site, Hewlett, NY – Region 2 Perkasie Site, Perkasie, PA – Region 3 Pohatcong Site, Franklin Township, NJ – Region 2 Port Washington Site, North Hemstead, NY – Region 2 Radiation Technologies Site, Rockaway, NJ – Region 2 Railroad TCE, Warminster, PA - Region 3 Raritan Arsenal, Edison, NJ – Region 2 Raymark Site, Stratford, CT – Region 1 Rittenhouse Road, Norristown, PA - Region 3 Rockaway Boro Site, Rockaway Township, NJ – Region 2 San Gabriel Valley Site, Eouth El Monte, CA - Region 9 Scientific Chemical Processing Site, Carlstadt, NJ – Region 2 Scovill Schrader Site, Dickson, TN - Region 4 Shenandoah Road Site, East Fishkill, NY – Region 2 Sherwin Williams, Gibbsboro, NJ - Region 2 South Jersey Clothing Site. Buena Borough, NJ – Region 2

  • St. Louis Park Site, St. Louis Park, MN - Region 5

Sugarhouse VI PCE Site, Salt Lake City, UT - Region 8 Tranguch Site, Hazleton, PA – Region 3 Trex Properties Site, Charlotte, NC - Region 4 Trex Site, Grand Rapids, MI - Region 5 USMC Camp Lejeune, Jacksonville, NC – Region 4 Valmont Site, Hazleton, PA – Region 3 Vestal Site, Vestal, NY -Region 2 White Swan Site, Wall Township, NJ – Region 2

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SLIDE 20

TAGA Monitoring

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TAGA Monitoring with the Teflon Tube Using the Low Pressure Chemical Ionization (LPCI) Source

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Vapor Intrusion Discussion Points

  • Impacts Due to Vapor Intrusion
  • Impacts Due to Household Material Impacts
  • Impacts Due to Adjacent Building
  • Impacts Due to Adjoining Buildings
  • Impacts Due to Contaminated Potable Well Water
  • Impacts Due to Crawlspace Concentrations
  • Impacts Due to Presence in Contaminated Water in Sumps
  • Impacts Due to Same Source - Constituent Ratios
  • Impacts Due to Self-Polluting Operations
  • Impacts Due to Accidental/Intentional Releases
  • Impacts Due to Releases at Distances
  • Impacts Due to Groundwater Becoming Surface Water
  • Impacts Due to Groundwater Being Used for Irrigation
  • Impacts Due to Sub-slab Contamination
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Impacts Due to Vapor Intrusion Sources TCE Site Region 2

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Region 2 - TCE Site

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SLIDE 25
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Impacts Due to Lifestyle Sources TCE Site Region 2

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Region 2 - TCE Site

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Impacts Due to Outside Ambient Air Sources PCE Site Region 5

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Region 5 – PCE Site

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Fig u r e 18 a M ob ile M on ito ring P a th T w o , A R M N 02 2 Fig u r e 18 a M ob ile M on ito ring P a th T w o , A R M N 02 2

A B C D E F G H I J K L M N O 5 1 0 1 5 2 0 2 5 3 0 0 . 0 2 . 5 5 . 0 7 . 5 1 0 . 0 1 2 . 5 1 5 . 0 Q L D L

T e t r a c h l o r o e t h e n e ( A R M N 0 2 2 )

U n i t s i n p p b v T i m e i n m i n u t e s

Wind: 10 mph/050o

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Northeast – 13 mph North – 12 mph

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Impacts Due to Attached Facilities Solvent Site Region 6

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Region 6 – PCE/Xylene Site

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SLIDE 37
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SLIDE 38
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Impacts Due to Contaminated Well Water TCE Site Region 3

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Region 3 - TCE Site

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SLIDE 41
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Impacts Due to Crawlspace Areas TCE Site Region 6

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Region 6 - TCE Site

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SLIDE 44
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SLIDE 45
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Impacts Due to Meteorological Effects TCE Site Region 3

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Region 3 - TCE Site

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SLIDE 48 A B C D E F G H I J K L M N O P Q R S T U V W X Y Z A A B B C C D D E E F F G G H H I I J J 2 5 5 0 7 5 1 0 0 1 2 5 5 1 0 1 5 2 0 2 5 3 0 Q L D L

T r i c h l o r o e t h e n e ( V A L 2 0 4 9 )

U n i t s i n p p b T i m e i n m i n u t e s A B C D E F G H I J K L M N O P Q R S T U V W X Y Z A A B B C C D D E E F F G G H H 0 . 0 2 . 5 5 . 0 7 . 5 1 0 . 0 1 2 . 5 1 5 . 0 1 7 . 5 2 0 . 0 2 2 . 5 5 1 0 1 5 2 0 2 5 3 0 Q L D L

T r i c h l o r o e t h e n e ( V A L 2 0 6 1 )

U n i t s i n p p b T i m e i n m i n u t e s

1ST 2ND

TRICHLOROETHENE CONCENTRATIONS

~ 120 PPBV ~21 PPBV Rainfall - 0.9 inch 11/06 1500 – 2300 Wind ~ 5 mph 11/07 0000 – 1200 Wet Sumps Rainfall - 1.9 inch 11/12 0500 – 2300 Wind ~ 25 mph 11/13 0000 – 1100 Dry Sumps

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Impacts Due to Signature Compounds from Subsurface Gas Intrusion Chlorinated Solvent Site Region 1

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Region 1 – TCE Site

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Constituent Ratios

A B C D E F G H I J K L M N 5 1 0 1 5 2 0 2 5 3 0 3 5 0 . 0 2 . 5 5 . 0 7 . 5 1 0 . 0 1 2 . 5 1 5 . 0 1 7 . 5 Q L D L D I C H L O R O E T H E N E ( r a y 0 1 0 ) U n i t s i n P P B T i m e i n m i n u t e s A B C D E F G H I J K L M N 5 1 0 1 5 2 0 2 5 0 . 0 2 . 5 5 . 0 7 . 5 1 0 . 0 1 2 . 5 1 5 . 0 1 7 . 5 Q L D L 1 , 1 , 1 - T R I C H L O R O E T H A N E ( r a y 0 1 0 ) U n i t s i n P P B T i m e i n m i n u t e s A B C D E F G H I J K L M N 0 . 0 0 0 . 0 1 0 . 0 2 0 . 0 3 0 . 0 4 0 . 0 5 0 . 0 6 0 . 0 7 0 . 0 8 0 . 0 2 . 5 5 . 0 7 . 5 1 0 . 0 1 2 . 5 1 5 . 0 1 7 . 5 Q L D L C H L O R O B E N Z E N E ( r a y 0 1 0 ) U n i t s i n P P B T i m e i n m i n u t e s A B C D E F G H I J K L M N 1 2 3 4 5 6 7 8 9 1 0 0 . 0 2 . 5 5 . 0 7 . 5 1 0 . 0 1 2 . 5 1 5 . 0 1 7 . 5 Q L D L T R I C H L O R O E T H E N E ( r a y 0 1 0 ) U n i t s i n P P B T i m e i n m i n u t e s A B C D E F G H I J K M N O P Q 2 . 5 5 . 0 7 . 5 1 0 . 0 1 2 . 5 1 5 . 0 1 7 . 5 Q L D L D I C H L O R O E T H E N E ( r a y 0 1 1 ) T i m e in m in u t e s A B C D E F G H I J K M N O P Q 0 . 0 2 . 5 5 . 0 7 . 5 1 0 . 0 1 2 . 5 1 5 . 0 1 7 . 5 Q L D L T R I C H L O R O E T H E N E ( r a y 0 1 1 ) T i m e in m in u t e s

Children’s Gymnasium Residence Adjacent to the Gymnasium

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Impacts Due to Self-polluting Operations PCE Site Region 4

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Region 4 – PCE Site

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SLIDE 54 A B C D E F G H I J K L M N O P Q R S T U V W 1 2 3 4 5 6 7 8 9 1 0 0 . 0 2 . 5 5 . 0 7 . 5 1 0 . 0 1 2 . 5 1 5 . 0 1 7 . 5 2 0 . 0 2 2 . 5 Q L D L

T r i c h l o r o e t h e n e ( A B C 0 1 2 )

U n i t s i n p p b v T i m e i n m i n u t e s A B C D E F G H I J K L M N O P Q R S T U V W 0 . 0 0 0 . 0 5 0 . 1 0 0 . 1 5 0 . 2 0 0 . 2 5 0 . 3 0 0 . 3 5 0 . 4 0 0 . 4 5 0 . 5 0 0 . 5 5 0 . 6 0 0 . 0 2 . 5 5 . 0 7 . 5 1 0 . 0 1 2 . 5 1 5 . 0 1 7 . 5 2 0 . 0 2 2 . 5 Q L D L

T e t r a c h l o r o e t h e n e ( A B C 0 1 2 )

U n i t s i n p p b v T i m e i n m i n u t e s

Region 4 PCE Site

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Impact Due to Accidental or Intentional Releases Gasoline Spill Site Region 3

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Region 3 - Benzene Site

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SLIDE 57 A B C D E F G H I J K L M N O P Q R S T U V W X Y Z A A B B C C D D E E F F G G H H I I J J . 0 . 5 1 . 0 1 . 5 2 . 0 2 . 5 3 . 0 3 . 5 5 1 1 5 2 2 5 3 D L Q L H L B E N Z E N E ( H A Z 4 1 9 0 ) U n i t s i n P P B T i m e I n M i n u t e s A B C D E F G H I J K L M N O P Q R S T U V W X Y Z A A B B C C D D E E F F G G H H I I J J 1 2 3 4 5 6 7 8 5 1 1 5 2 2 5 3 D L Q L T O L U E N E ( H A Z 4 1 9 0 ) U n i t s i n P P B T i m e I n M i n u t e s A B C D E F G H I J K L M N O P Q R S T U V W X Y Z A A B B C C D D E E F F G G H H I I J J . 0 . 5 1 . 0 1 . 5 2 . 0 2 . 5 3 . 0 3 . 5 4 . 0 4 . 5 5 . 0 5 1 1 5 2 2 5 3 D L Q L X Y L E N E ( H A Z 4 1 9 0 ) U n i t s i n P P B T i m e I n M i n u t e s A B C D EF G H I J K L M N O P Q R S T U V W X Y Z AA BB CC DD EE FF GG HH II 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5 10 15 20 25 30 DL QL HL BENZENE (HAZ4291) Units in PPB Time In Minutes A B C D EF G H I J K L M N O P Q R S T U V W X Y Z AA BB CC DD EE FF GG HH II 1 2 3 4 5 6 7 8 9 5 10 15 20 25 30 DL QL TOLUENE (HAZ4291) Units in PPB Time In Minutes A B C D EF G H I J K L M N O P Q R S T U V W X Y Z AA BB CC DD EE FF GG HH II 1 2 3 4 5 6 7 8 9 10 5 10 15 20 25 30 DL QL XYLENE (HAZ4291) Units in PPB Time In Minutes A B C D E F G H I J K L M N O P QR S T U V W X Y Z AA BB CC DD EE FF GG HH II JJ KK LL MM 100 200 300 400 500 600 700 800 900 1000 5 10 15 20 25 30 DL QL HL BENZENE (HAZ6039) Units in PPB Time In Minutes A B C D E F G H I J K L M N O P QR S T U V W X Y Z AA BB CC DD EE FF GG HH II JJ KK LL MM 1 2 3 4 5 6 5 10 15 20 25 30 DL QL TOLUENE (HAZ6039) Units in PPB (Thousands) Time In Minutes A B C D E F G H I J K L M N O P QR S T U V W X Y Z AA BB CC DD EE FF GG HH II JJ KK LL MM 250 500 750 1000 1250 1500 1750 2000 2250 5 10 15 20 25 30 DL QL XYLENE (HAZ6039) Units in PPB Time In Minutes

1st

2nd 3rd

BENZENE CONCENTRATIONS

< 1.0 PPBV < 1.0 PPBV > 900 PPBV

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Monitoring For Fractured Bedrock Contribution TCE Site Region 3

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Injection Well Impacted Residence 3585 Feet

Crossley Farm Site Satellite Overview

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Region 3 - Trichloroethene Site

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Region 3 - TCE and PCE Site

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Monitoring For Fractured Bedrock Contributions TCE Site Region 4

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Mills Gap Road Site Topographical Map

Site

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SLIDE 64 A B C D E F G H I J K L M N O P 0 . 0 0 0 0 . 0 2 5 0 . 0 5 0 0 . 0 7 5 0 . 1 0 0 0 . 1 2 5 0 . 1 5 0 5 1 0 1 5 2 0 2 5 Q L D L

T e t r a c h l o r o e t h e n e ( M G R 0 0 2 )

U n i t s i n p p b v T i m e i n m i n u t e s A B C D E F G H I J K L M N O P 5 1 0 1 5 2 0 2 5 5 1 0 1 5 2 0 2 5 Q L D L

T r i c h l o r o e t h e n e ( M G R 0 0 2 )

U n i t s i n p p b v T i m e i n m i n u t e s

Mobile Monitoring Route 10 December 2007

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SLIDE 65

Monitoring For Contributions From Activities Utilizing Contaminated Groundwater Chlorinated Contamination Site Region 7

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SLIDE 66

Site Map for Former Nebraska Ordnance Plant – Region 7-TCE Site

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SLIDE 67

A

A B C D E F G H I J 0 . 0 0 0 . 0 1 0 . 0 2 0 . 0 3 0 . 0 4 0 . 0 5 0 . 0 6 0 . 0 7 0 . 0 8 0 . 0 9 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 Q L D L

T r i c h l o r o e t h e n e ( N O P 0 2 3 )

U n i t s i n p p b v T i m e i n m i n u t e s

a

Mobile Monitoring Adjacent to an Active Irrigation Sprayer Region 7 – TCE Site

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SLIDE 68

INDOOR ANALYSIS Comparison of the TAGA Triple Quadrupole Mass Spectrometer Real-time Monitoring 1- Minute Average Results to the Off-site GC/MS Results of 6-Liter 24-Hour Time-weighted-averaged Summa Canister Samples

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SLIDE 69

Hopewell Junction Site – Hopewell, NY 37 INDOOR LOCATIONS

TCE TAGA vs Summa Data

y = 1.2693x R2 = 0.8074 1 2 3 4 5 6 7 1 2 3 4 5 TAGA (ppbv) Summa (ppbv)

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SLIDE 70

Additional Information ERT TAGA Website - https://www.epa.gov/ert/environmental- response-team-trace-atmosphere-gas-analyzer-taga

Video - https://www.ertvideo.org/content.aspx?video_id=7180

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SLIDE 71

For further information concerning the scheduling, capabilities, and applications of the TAGA mobile laboratories, contact:

David Mickunas

US EPA/ERT-Research Triangle Park, NC Telephone - (919) 541 4191 E-mail - mickunas.dave@epa.gov.