Spatial and temporal dynamics of nitrogen biogeochemistry along a - - PowerPoint PPT Presentation

spatial and temporal dynamics of nitrogen biogeochemistry
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Spatial and temporal dynamics of nitrogen biogeochemistry along a - - PowerPoint PPT Presentation

Spatial and temporal dynamics of nitrogen biogeochemistry along a wetland-stream sequence Patrick Hurley a H.M. Valett a,c Ben Colman a Marc Peipoch b *b *a *c Acknowledgements Project Partners: Field & Lab Techs: Jim Ford, NRDP Claire


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Spatial and temporal dynamics of nitrogen biogeochemistry along a wetland-stream sequence

Patrick Hurleya H.M. Valetta,c Ben Colmana Marc Peipochb

*a *b *c

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SLIDE 2

Acknowledgements

Project Partners:

Jim Ford, NRDP Doug Martin, NRDP Beau Downing, NRDP Marisa Sowles, Geum Consulting Tom Parker, Geum Consulting Heggelund Ranch Ueland Ranch Kelley Ranch Lambert Ranch

Field & Lab Techs:

Claire Utzman Ash Micklewright Fischer Young Kate Perkins Carly Andlauer Kim Bray

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Nutrients in the Upper Clark Fork River (UCFR) N and P spikes in the UCFR

Ingman & Kerr 1989

P N

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Clark Fork Coalition MT DNRC

Longitudinal Study

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0.0 10.0 20.0 30.0 40.0 50.0 60.0 70.0 80.0 10 20 30 40 Nitrate-N (ug/L) River km from Warm Springs Put-in October-NO3 April-NO3 Lost Creek UCFR

UCFR Longitudinal Nitrate

October 2016 April 2017

Valett & Peipoch 2018

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SLIDE 6

Warm Springs Put-in

Silver Bow Creek Warm Springs Creek

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Research Questions

I. How does biogeochemical processing change along a wetland-stream sequence?

  • II. How do spatial and temporal patterns

characterize nutrient dynamics in linked ecosystems?

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Project Summary

Using a mass-balance approach….

Key objectives:

  • 1. Characterize biogeochemical dynamics of wetland-stream

sequence

  • 2. Quantify nutrient magnitude, processing efficiency, and fate
  • ver time and space
  • 3. Identify drivers of material cycling and delivery to the UCFR

Silverthorn 2015

Outputs – Inputs =

Nutrient Processing?

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SLIDE 9

Lost Creek Dutchman Complex (LCDC)

  • MT’s largest peat fen
  • 22 km channel
  • 157 km2 catchment
  • 150 L/sec baseflow
  • 0.5 km2 of open water
  • 11.5 km2 of wetlands
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Math

𝑀𝑦 = 𝑅𝑦 ∗ [𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜]𝑦 𝑀𝑝𝑝𝑝 = 𝑀𝑗𝑗 + 𝑀𝑝 − 𝑀𝑚 + Δ𝑀

𝑛𝑛 𝑡𝑡𝑡 = 𝑀 𝑡𝑡𝑡 ∗ 𝑛𝑛 𝑀

∗ 0.0864 

𝑙𝑛 𝑒𝑏𝑏

Mass Balance Load Calculation

Biology? Hydrology?

t=tributary; l=irrigation losses

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Nitrate concentration over time and space

Site 3 Site 6 Site 9 Site 11 Site 12

Site 3 Site 6 Site 9 Site 11 Site 12

DATE

Upstream Downstream

May 15 June 19 July 17 August 14

  • Sept. 19

15 MAY 19 JUNE 17 JULY 14 AUGUST 19 SEPT.

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Nitrate loads over time and space

May 15 June 19 July 17 August 14

  • Sept. 19

Site 3 Site 6 Site 9 Site 11 Site 12

15 MAY 19 JUNE 17 JULY 14 AUGUST 19 SEPT.

DATE

Upstream Downstream

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Nitrate concentration on a 22km gradient

AUGUST 22 JUNE 7 Diversion Dam Reach I Reach II Reach III Reach IV

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June LNO3 vs. net groundwater exchange

Reach I Reach II Reach III Reach IV

  • 64%

18% 60% 14%

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August LNO3 vs. net groundwater exchange

Diversion Dam Reach I Reach II Reach III Reach IV

  • 194%
  • 27%

6% 51%

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Baseflow groundwater N concentrations

Mean NO3-N Mean NH4-N NO3-N NH4-N FORM

n = 20

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Ground-surfacewater interactions & microbial processing: implications for N loads in the LCDC

Dutchman Creek Dutchman Dyke Lost Creek Fen

*Nitrification of NH4-N from anoxic groundwater to NO3-N at oxic hyporheic interface

Reach I Reach II Reach III Reach IV

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LNO3 LNH4 Q % Increase Relative to UCFR

Contributions to the UCFR

May 15 June 19 July 17 August 14

  • Sept. 19

15 MAY 06 JUNE 19 JUNE 03 JULY

DATE

Peak Flood

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Questions?

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Nitrate loads on a 22km gradient

August 15 June 7 Reach 1 Reach 2 Reach 3 Reach 4

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Ammonium concentration over time

May 15 June 19 July 17 August 14

  • Sept. 19

Site 3 Site 6 Site 9 Site 11 Site 12

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Ammonium loads over time

Site 3 Site 6 Site 9 Site 11 Site 12 May 15 June 19 July 17 August 14

  • Sept. 19
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Phosphate concentration over time

Site 3 Site 6 Site 9 Site 11 Site 12 May 15 June 19 July 17 August 14

  • Sept. 19
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Phosphate loads over time

Site 3 Site 6 Site 9 Site 11 Site 12 May 15 June 19 July 17 August 14

  • Sept. 19
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DOC concentration over time

Site 3 Site 6 Site 9 Site 11 Site 12 May 15 June 19 July 17 August 14

  • Sept. 19
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DOC loads over time

Site 3 Site 6 Site 9 Site 11 Site 12 May 15 June 19 July 17 August 14

  • Sept. 19
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DOC concentrations on a 22km gradient

Reach 1 Reach 2 Reach 3 Reach 4

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DOC loads on a 22km gradient

Reach 1 Reach 2 Reach 3 Reach 4

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ΔL along a 22km gradient

Reach 1 Reach 2 Reach 3 Reach 4 June 7

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ΔL along a 22km gradient

Reach 1 Reach 2 Reach 3 Reach 4 June 7 August 22