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RETURN TO EQUILIBRIUM V.Jak si c, C. A. Pillet, J. Derezi nski. - PowerPoint PPT Presentation

RETURN TO EQUILIBRIUM V.Jak si c, C. A. Pillet, J. Derezi nski. Conventional wisdom (1) In a generic situation, a small system interacting with a large reservoir at temperature T goes to equi- librium at the same temperature. (2) The


  1. RETURN TO EQUILIBRIUM V.Jakˇ si´ c, C. A. Pillet, J. Derezi´ nski. Conventional wisdom (1) In a generic situation, a small system interacting with a large reservoir at temperature T goes to equi- librium at the same temperature. (2) The behavior of a small system interacting with reservoirs at distinct temperatures is much more dif- ficult to desribe than in the case of a reservoir at a fixed temperature.

  2. Rigorous expression of conventional wisdom Rigorous theorems proven for nontrivial, explicit and realistic models: (1) Return to equilibrium for a generic small system interacting with a thermal reservoir. (2) Absence of normal stationary states for a generic small system interacting with a non-equilibrium reser- voir.

  3. Mathematical techniques involved in the study of return to equilibrium. • Operator algebras: – KMS states, – Standard forms, Liouvilleans; • Quantum field theory: – Quasi-free (Araki-Woods) representations of the CCR; • Spectral theory: – Fermi Golden Rule, the Feshbach method, – The positive commutator (Mourre) method.

  4. Plan of the lecture (1) Small system interacting with a bosonic reservoir (2) W ∗ -algebraic background. (3) Fermi golden rule

  5. SMALL SYSTEM INTERACTING WITH A BOSONIC RESERVOIR Bosonic Fock space ∞ Γ s ( L 2 ( R d )) := n =0 ⊗ n s L 2 ( R d ) . ⊕ Creation/annihilation operators: [ a ∗ ( ξ 1 ) , a ∗ ( ξ 2 )] = 0 , [ a ( ξ 1 ) , a ( ξ 2 )] = 0 , [ a ∗ ( ξ 1 ) , a ( ξ 2 )] = δ ( ξ 1 − ξ 2 ) . √ � a ∗ ( ξ ) f ( ξ )d ξ Φ := Φ ∈ ⊗ n s L 2 ( R d ) . n + 1 f ⊗ s Φ , Vacuum: Ω = 1 ∈ ⊗ 0 s L 2 ( R d ) = C . Free Hamiltonian of fotons or phonons: � | ξ | a ∗ ( ξ ) a ( ξ )d ξ. H =

  6. Quasi-free representations of the CCR Radiation density: R d ∋ ξ �→ ρ ( ξ ) ∈ [0 , ∞ [ . We look for creation/annihillation operators a ∗ ρ, l ( ξ ) /a ρ, l ( ξ ) , with a quasi-free state of density ρ given by a cyclic vector Ω : [ a ∗ ρ, l ( ξ 1 ) , a ∗ ρ, l ( ξ 2 )] = 0 , [ a ρ, l ( ξ 1 ) , a ρ, l ( ξ 2 )] = 0 , [ a ρ, l ( ξ 1 ) , a ∗ ρ, l ( ξ 2 )] = δ ( ξ 1 − ξ 2 ) . � i � � ( f ( ξ ) a ∗ √ W ρ, l ( f ) := exp ρ, l ( ξ ) + f ( ξ ) a ρ, l ( ξ ))d ξ . 2 − 1 � � � | f ( ξ ) | 2 (1 + 2 ρ ( ξ ))d ξ (Ω | W ρ, l ( f )Ω) = exp . 4

  7. Araki-Woods representation of CCR We will write a ∗ l ( ξ ) /a l ( ξ ) , a r ( ξ ) /a ∗ r ( ξ ) for the creation/ annihilation operators corresponding to the left and right L 2 ( R d ) resp. acting on the Fock space Γ s ( L 2 ( R d ) ⊕ L 2 ( R d )) . Left Araki-Woods creation/annihillation operators are defined as a ∗ 1 + ρ ( ξ ) a ∗ � � ρ, l ( ξ ) := l ( ξ ) + ρ ( ξ ) a r ( ξ ) , ρ ( ξ ) a ∗ � � a ρ, l ( ξ ) := 1 + ρ ( ξ ) a l ( ξ ) + r ( ξ ) . Left Araki-Woods algebra is denoted by M AW and de- ρ, l fined as the W ∗ -algebra generated by the operators W ρ, l ( f ) . The vacuum Ω defines a quasi-free state of density ρ .

  8. Commutant of the Araki-Woods algebra Define an involution ǫ on L 2 ( R d ) ⊕ L 2 ( R d ) by ǫ ( f 1 , f 2 ) := ( f 1 , f 2 ) . Set J := Γ( ǫ ) . Then J is the modular involution for the state (Ω | · Ω) . Right Araki-Woods creation/annihillation operators: a ∗ 1 + ρ ( ξ ) a ∗ � � ρ, r ( ξ ) := ρ ( ξ ) a l ( ξ ) + r ( ξ ) , ρ ( ξ ) a ∗ � � a ρ, r ( ξ ) := l ( ξ ) + 1 + ρ ( ξ ) a r ( ξ ) . generate the right Araki-Woods algebra denoted by M AW ρ, r . Note that J M AW ρ, l J = M AW ρ, r is the commutant of M AW ρ, l .

  9. Dynamics of the quasifree bosons The Liouvillean of free bosons: � � | ξ | a ∗ | ξ | a ∗ L = l ( ξ ) a l ( ξ )d ξ − r ( ξ ) a r ( ξ )d ξ. Note that JLJ = − L . e i tL · e − i tL defines a dynamics on M AW ρ, l . The state (Ω |· Ω) is β -KMS iff the density is given by the Planck law: ρ ( ξ ) = (e β | ξ | − 1) − 1 .

  10. Small quantum system in contact with Bose gas at zero density Hilbert space of the small quantum system: K = C n . The Hamiltonian of the free system: K . The free Pauli-Fierz Hamiltonian: � | ξ | a ∗ ( ξ ) a ( ξ )d ξ. H fr := K ⊗ 1 + 1 ⊗ R d ∋ ξ �→ v ( ξ ) ∈ B ( K ) describes the interaction: � v ( ξ ) ⊗ a ∗ ( ξ )d ξ + hc V := The full Pauli-Fierz Hamiltonian: H := H fr + λV. The Pauli-Fierz system at zero density: B ( K ⊗ Γ s ( L 2 ( R d )) , e i tH · e − i tH � � .

  11. Small quantum system in contact with Bose gas at density ρ . The algebra of observables of the composite system: � � K ⊗ Γ s ( L 2 ( R d ) ⊕ L 2 ( R d )) M ρ := B ( K ) ⊗ M ρ, l ⊂ B . The free Pauli-Fierz semi-Liouvillean at density ρ : �� � � L semi | ξ | a ∗ | ξ | a ∗ := K ⊗ 1 + 1 ⊗ l ( ξ ) a l ( ξ )d ξ − r ( ξ ) a r ( ξ )d ξ . fr The interaction: � v ( ξ ) ⊗ a ∗ V ρ := ρ, l ( ξ )d ξ + hc . The full Pauli-Fierz semi-Liouvillean at density ρ : L semi := L semi + λV ρ . ρ fr The Pauli-Fierz W ∗ -dynamical system at density ρ : where σ ρ,t ( A ) := e i tL semi A e − i tL semi ( M ρ , σ ρ ) , . ρ ρ

  12. Relationship between the dynamics at zero density and at density ρ . Set ρ = 0 . M 0 ≃ B ( K ⊗ Γ s ( L 2 ( R d )) ⊗ 1 . � L semi | ξ | a r ( ∗ ( ξ ) a r ( ξ )d ξ. ≃ H ⊗ 1 − 1 ⊗ 0 σ 0 ,t ( A ⊗ 1) = e i tH A e − i tH ⊗ 1 . If we formally replace a l ( ξ ) , a r ( ξ ) with a ρ, l ( ξ ) , a ρ, r ( ξ ) (the CCR do not change!) then M 0 , L semi , σ 0 trans- 0 form into M ρ , L semi , σ ρ . In the case of a finite num- ρ ber of degrees of freedom this can be implemented by a unitary Bogoliubov transformation. ( M ρ , σ ρ ) can be viewed as a thermodynamical limit of ( M 0 , σ 0 ) .

  13. Theorem I: Return equilibrium in the thermal case. Let the reservoir have inverse temperature β . Assume some conditions about the regularity and effective- ness of v ( ξ ) . Then there exists λ 0 > 0 such that for 0 < | λ | ≤ λ 0 , ( M ρ , σ ρ ) has a single normal stationary state ω . This state is β -KMS and for any normal state φ and A ∈ M ρ , we have lim | t |→∞ φ ( σ ρ,t ( A )) = ω ( A ) . Jakˇ si´ c- Pillet, Jakˇ si´ c-D., Bach-Fr¨ ohlich-Sigal, Fr¨ ohlich-Merkli Theorem II: Absence of normal stationary states in the non-equilibrium case. Suppose that the reservoir has parts at distinct temperatures. Assume some con- ditions about the regularity and effectiveness of v ( ξ ) . Then there exists λ 0 > 0 such that for 0 < | λ | ≤ λ 0 , ( M ρ , σ ρ ) has no normal stationary states. Jakˇ si´ c-D.

  14. Standard representation of M ρ . In order to prove the above theorems we need to go to the standard representation: π : M ρ → B ( K ⊗ K ⊗ Γ s ( L 2 ( R d ) ⊕ L 2 ( R d )) , π ( A ⊗ B ) = A ⊗ 1 ⊗ B, J Φ 1 ⊗ Φ 2 ⊗ Ψ = Φ 2 ⊗ Φ 1 ⊗ Γ( ǫ )Ψ . The free Pauli-Fierz Liouvillean: L fr := K ⊗ 1 ⊗ 1 − 1 ⊗ K ⊗ 1 a ∗ l ( ξ ) a l ( ξ ) − a ∗ � � � �� +1 ⊗ 1 ⊗ | ξ | l ( ξ ) a l ( ξ ) d ξ, v ( ξ ) ⊗ 1 ⊗ a ∗ � π ( V ρ ) = ρ, l ( ξ )d ξ + hc , 1 ⊗ v ( ξ ) ⊗ 1 ⊗ a ∗ � Jπ ( V ρ ) J = ρ, r ( ξ )d ξ + hc . The full Pauli-Fierz Liouvillean at density ρ : Lρ = L fr + λπ ( V ρ ) − λJπ ( V ρ ) J.

  15. Theorem I’: Let the reservoir have inverse tempera- ture β . Assume some conditions about the regularity and effectiveness of v ( ξ ) . Then there exists λ 0 > 0 such that for 0 < | λ | ≤ λ 0 , dim Ker L ρ = 1 and L ρ has abso- lutely continuous spectrum away from 0 . Theorem II’: Absence of normal stationary states in the non-equilibrium case. Suppose that the reservoir has parts at distinct temperatures. Assume some con- ditions about the regularity and effectiveness of v ( ξ ) . Then there exists λ 0 > 0 such that for 0 < | λ | ≤ λ 0 , dim Ker L ρ = 0 .

  16. Spectrum of Pauli-Fierz Liouvillean Spectrum of L fr is R . Point spectrum of L fr is sp K − sp K . Φ fr := e − βK/ 2 ⊗ Ω is a β -KMS vector of L fr . By Araki-Jakˇ si´ c-Pillet-D, e − ( L fr + λπ ( V ρ )) β/ 2 Φ fr is a β -KMS vector of L ρ . Therefore, Ker L ρ ≥ 1 . By a rigorous version of the Fermi Golden Rule, if the interaction is sufficiently regular and effective, then there exists λ 0 > 0 such that for 0 < | λ | ≤ λ 0 Ker L ρ ≤ 1 .

  17. W ∗ -ALGEBRAIC BACKGROUND 2 approaches to quantum systems (1) C ∗ -dynamical system ( A , α t ) : A – C ∗ -algebra, t �→ α t ∈ Aut( A ) – strongly contin- uous 1-parameter group. (2) W ∗ -dynamical system ( M , σ t ) : M – W ∗ -algebra, t �→ σ t ∈ Aut( M ) – σ -weakly con- tinuous 1-parameter group. We use the W ∗ -dynamical approach

  18. The GNS representation Suppose that ω is a state on M . Then we have the GNS representation π : M → B ( H ) with Ω ∈ H – a cyclic vector for π ( M ) such that ω ( A ) = (Ω | π ( A )Ω) , A ∈ M . If ω is normal, then so is π . If in addition ω is stationary wrt a W ∗ -dynamics σ , then we have a distinguished unitary implementation of σ : π ( σ t ( A )) = e i tL π ( A ) e − i tL , A ∈ M , L Ω = 0 .

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