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Pennycress Product Development & Preliminary Business Case Alberta Agriculture & Rural Development Kwesi Ampong-Nyarko April 2010 for Peace Region Economic Development Alliance What is the Bio-based Economy The bio-based economy


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Pennycress Product Development & Preliminary Business Case

Alberta Agriculture & Rural Development Kwesi Ampong-Nyarko April 2010 for Peace Region Economic Development Alliance

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What is the Bio-based Economy

  • The bio-based economy is a vision of a future society no longer wholly

dependent on fossil fuels for energy and industrial raw materials.

  • Bio-fuels (like ethanol and diesel) made directly from agricultural crops, will

become increasingly competitive

  • Fossil fuels are used as industrial feedstocks, to produce chemicals,

plastics etc. Most of this use could, over time, be replaced by biomass - starch, straw etc - fermented and converted to a vast range of materials using enzymes or micro-organisms developed specially for the task.

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Biodiesel Driving Forces

  • The federal government mandate requiring an annual

renewable content of two percent in diesel by 2012 is creating demand for vegetable oil for biodiesel production.

  • Most current biodiesel processes use edible oils as the
  • il feedstock.
  • To meet this demand and deal with the concerns

regarding food, non-food sources of non food source of vegetable oil have to be found.

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Pennycress

  • Contains 36% oil in the

seed.

  • Contains a glucosinolate

which has potential as a herbicide

  • Producing where most

crops fail

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Surface 2.5cm deep 100 200 300 400

Spring Winter Number of seedlings

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250 500 750 1000 1250 1500 1750 2000 10 20 30 40 50 60 70 80 90 100

Day0 Day28 Gibberellic acid (ppm) Seeds germinated (%)

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Evaluate the economic feasibility of combine harvesting of wild stands of pennycress using conventional combines

Location Yield/kg/ha Bushels/acre Rycroft 2283.3 46.8 High Prairie (E) 2288.5 47.1 High Prairie (R) 2506.0 51.4 Edmonton Farmer's Field 3098.3 63.6 CDC North Winter 2588.3 53.1

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Seedlings that emerge in the fall overwinter as a rosette and flower early in the growing season

  • It takes advantage of spring

snow melt

  • is competitive against weeds

and thus

  • ffers option to produce

pennycress as a low input crop

Pennycress growing on 31 March 2010

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Control Pennycress Corn gluten 10 20 30 40 50 60

White Cockle Cow cockle Green foxtail Lamb's-quarters Stinkweed Downy brome Redroot pigweed Dandelion Common groundsel Number of plants

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Crop safety to pennycress meal

  • Pennycress meal as herbicides can be applied as

preplant incorporated (applied before planting,

  • mixed into the soil), pre-emergence
  • (applied to soil before plant/weed emergence), post-

emergence (applied after crop emergence)

  • Timing of application can also impact herbicide

selectivity.

  • the time when the target organism is introduced to the

glucosinolate-containing medium.

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Canola

10 20 30 40 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160

0 kg/m2 2 kg/m2 4 kg/m2 8 kg/m2 Days Seedling emergence (%)

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Tomato

10 20 30 40 25 50 75 100 125 150 175

0 kg/m2 2 kg/m2 4 kg/m2 8 kg/m2 Days Seedling emergence (%)

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Pennycress meal nutrient analysis

  • Per cent nitrogen ranged 3.97 -4.17 % and P

0.70-0.76 %.

  • Total organic carbon in the two samples was

5.16 and 56.2 % respectively.

  • Organic matter was 56.5% and 59.5%.
  • The ph ranged between 5.1 to 5.4
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Pennycress oil

  • The maximum pennycress meal oil content (excluding

residual oil in meal) was 29.28%

  • The oil in canola was 43.7%.
  • Residual oil was 9.66%.
  • Allyl glucosinolate content varied from 146.0 µmoles/g to

184.8 µmoles/g.

  • Fatty acid composition Erucic (38.89 wt %), linoleic

(20.81 wt %), and linolenic (12.53 wt %)

  • The amount of saturated fatty acid in pennycress was

low 3.5 1 wt% mainly palmitic acid.

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Pennycress oil - Cold Weather Performance

  • Pennycress oil exhibited a desirable low temperature

fluidity, as indicated by cloud point (CP) value of >-15. In the literature the actual measured value −28 ◦C.

  • Based on these results, it is expected that pennycress oil

would be better suited for industrial applications where sub-ambient conditions are prevalent.

  • The relatively low level of saturated fatty acid contained

in pennycress oil (4.6 wt%)

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Achievement

  • Pennycress was originally classified as a class 3 weed by the CFIA.

The project submitted a science advice to the Canadian Food Inspection Agency on the benefits of pennycress as a crop. As a result, pennycress is no more classified as weed because.

  • Pennycress is also no longer listed as a weed in the Provincial

Weed Act.

  • Recognized as potential Feed stock promoted the scientific

merits of using pennycress as a feedstock. Pennycress is now considered as one of the potential sources of feedstock along side yellow grease and tallow, off-grade canola seed and camelina.

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Advantages of using Pennycress as feedstock for biodiesel

  • 1. Low break-even cost crop requiring none or little inputs

(pesticides)

  • 2. It is a winter annual
  • 3. It can be grown on marginal lands
  • 4. Non-food source of oil
  • 5. Capability to serve in rotational crop cycles (short

duration crop)

  • 6. Cold filter plugging point Pennycress oil exhibited a

desirable low temperature fluidity, as indicated by cloud point value −280C.

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Cropping System

  • Strictly a winter annual
  • Alternate Crop
  • seeding delayed into June, we have an extra short-

season crop that matures in 80 days

  • Rotation with winter cereal
  • Winter pennycress - Winter pennycress - winter

pennycress – winter cereal

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Pennycress Industry Development Model

  • The final biodiesel composition depends on the initial

feedstock

  • Substitution among fats and oils of different

feedstocks

  • Feedstocks can account for more than seventy percent
  • f the total cost of producing biodiesel
  • Hence feedstock cost and availability are very important

in determining the feasibility of a biodiesel industry

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Biodiesel Reaction

Vegetable Oil or Animal Fat (100 lbs.) + Methanol or Ethanol (10 lbs.) Biodiesel (100 lbs.) + Glycerin (10 lbs.)

In the presence of a catalyst (Sodium hydroxide, Potassium hydroxide Combining Yields

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Oil extraction Pennycress seed Production Oil Meal Transesterfication Saponification Lubricants Bio-fumigation Bio-pesticide Amendments and Fertilizers Glycerin Biofuel Polypropel glycol, acrolein, animal feed

Pennycress: A first generation Biorefinery

High value molecules, eg glucosinolates, myrosinase, enzyme effectors Animal Feed

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Example of canola vs. pennycress as feedstock for I000 kg

Attribute Canola Pennycress Oil yield (%)@ $0.50/litre 40.3 =$201.5 30 =$150.0 Meal value ($)/T) 200.00 100.00 Total revenue ($) 401.5 250.0 Cost of seed /tonne 420.00 268.5 Profit

  • 18.5
  • 18.5
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Project Net revenue from crops in 2010

Crop Price/bu Yield/bu /acre Gross Income ($) Cost ($) Net Revenue ($) Pennycress $3.75 - 5.53 40 150 -221 70 $60-$130 Camelina $6.73/bu 25 168.25 80 88.25 HRS wheat $5.36 /bu 35 187.60 100 87.60 Durum $4.79 /bu 40 191.6 100 91.60 Peas $4.85 /bu 35 169.75 100 69.75 Canola $8.76 /bu 25 219.00 150 69.00 Feed barley $3.00 /bu 50 150.00 100 50.00

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Sensitivity analysis of pennycress as feedstock for 40 bushel (789 kg)/acre

$0.60/litre $0.50/litre $0.40/litre $0.30/litre Meal value ($0.10/kg) per acre 79.0 79.0 79.0 79.0 Oil value 142.0 118.0 94.7.0 71.01 Total revenue 221.0 197.0 173.7 150.0 Crush prod ($) 20.0 20.0 20.0 20.0 Price/kg seed (revenue from

  • ne acre

$0.28 =$130 $0.25 $107.2 $0.22 $83.0 $0.19 =$60

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Acknowledgments

  • Lesser Slave Lake Economic Alliance

– Greg Radstaak – Alvin Billings

  • Peace Region Economic Development Alliance

– Bob Hall – Jack O’Toole

  • All Peace Industries Inc

– Stan Peacock – Marion Peacock

  • Olds College

– Tanya McDonald – Abimbola Abiola

  • Alberta Agriculture and Rural Development

– Zhixiong Zhang – Yingli Wang