Overview of Hydrogen Project in Mianz, Germany Hydrogen Mobility - - PowerPoint PPT Presentation

1

Ghufran Bala July 1, 2017 Hydrogen, Carbon-Free-Fuel, Democratizing the Energy

Overview of Hydrogen Project in Mianz, Germany Hydrogen Mobility

2

Contents

—The Linde Group - Introduction —Gases Division – Brief Overview —Hydrogen Solution —Energiepark Mainz —Proton Exchange Membrane) Process – H2 Production —H2 Value Chain Concept – Energy Storage —H2 Production in Pakistan

3

Linde corporate heritage

• History of over 130 years
• The company’s founder, Professor

Doctor Carl von Linde

• Invented refrigeration technology

and air separation.

• Global market leader in gases and

engineering solutions.

• In the 2016 financial year, The Linde

Group generated revenue of EUR 16.944 bn 65,000 employees working in more than 100 countries worldwide.

7/17/2017 3

4

Cylinder

Gases Division Integrated Gases Model

Bulk On-site

Filling sites Filling sites Retailer Transport of liquefied gas On-site supply Pipeline Pipeline Gas Production Plant e.g. Air Separation Unit (ASU)

Value creation

4 7/17/2017

5

Gases Division Wide range of products, services and applications

Air Gases — Nitrogen (N2) — Oxygen (O2) — Argon (Ar) — Rare Gases Krypton (Kr) Neon (Ne) Xenon (Xe) Other Gases — Acetylene (C2H2) — Helium (He) — Propane (C3H8) — Carbon Dioxide (CO2) — Carbon Monoxide (CO) — Hydrogen (H2) Specialty Gases — Pure Gases — Specialty Gas Mixtures Medical Gases — Medical Oxygen — Nitric Oxide (NO) — Nitrous Oxide (N2O)

5

Gases Services

Applications

Healthcare Chemistry & Energy Metallurgy & Glass Manu- facturing Retail Food & Beverages Elec-tronics Other

Linde gases are used, for example, in the energy sector, steel production, chemical processing, environmental protection and metal fabrication, as well as in glass production, food processing and electronics. The company is also a leading global supplier of premium healthcare products and services for patients with respiratory disorders.

Administrative Efficiency Process Know-how Quality and Safety Supply Reliability

7/17/2017

6

Hydrogen solutions | Linde covers the full value chain From production to fuelling and infrastructure

Production & Storage Distribution H2 Fuelling Stations Infrastructure

Conventional (e.g. Steam Methane Reformer) Renewable (e.g. Electrolysis) Onsite Electrolysis Ionic compressor Cryopump LH2 Liquid Hydrogen CGH2 Compressed Gaseous Hydrogen

7

Hydrogen value chain | Projects around the world Power-to-Gas activities and hydrogen fuelling stations

— Hydrogen mobility and Power-to-Gas activities have a good geographic fit. — Power-to-Gas enables zero emissions well-to-wheel in transport.

Countries with power-to-gas projects in planning and operation Rising interest in power-to-gas projects

8

Hydrogen value chain | Production & storage Variety of feedstock for diversification and CO2 reduction

Electrolysis Chemical processes Coal gasification Bioliquid reforming Biomass gasification Biological metabolism Steam methane reforming Natural gas Coal By product H2 Grid electricity Wind/Water/Solar power Solid biomass (e.g. wood) Biological processes (e.g. algae) Liquid biomass (e.g. glycerol) Biogas (e.g. landfill-, sewage gas)

Conventional Renewable — Hydrogen serves as an energy carrier which is storable and transportable. — Hydrogen can connect the energy and the transport systems.

9

Production & storage | Solving the storage problem Hydrogen – Interconnector between energy-systems

Power generation

− Increasing amount of volatile energy feeding into the power grid − Power-generation exceeds demand in local grid and in transmission systems − Conventional power-plants are still necessary as safeguards but low operating hours affect operating results

Renewables need energy storage Power-to-Gas / hydrogen has unique strengths

Better than any other storage type, hydrogen can: − create cross-links from renewable electricity to other sectors (fuels, chemicals) − store large amounts of energy at reasonable costs (~170 GWh in one typical salt cavern ≙ ~ 2 hours of electricity consumption of Germany) − facilitate seasonal storage (weeks to months) − From a renewable power share of 30-50% and above, overgeneration (i.e. curtailment) and load ramping become critical and hinder further deployment − Only storage can take up overgeneration, provide back-up capacity and ramping − But: No single technology can fulfill all requirements

10

Production & storage | Energiepark Mainz Hydrogen energy storage scaled up to grid relevance

— Connected to a wind-farm (8 MW) — 6.3 MW peak electrolyzer stacks (each 2.1 MW) — 800 kg storage (25 MWh) — 200 tons target annual output from 2017 onwards — Injection in local gas grid and multi-use trailer-filling — Budget: total 17 m€, funding: ~50% (BMWi)

Key facts Objectives

• 1. Local grid integration by storing fluctuating renewable power
• 2. Provision of ancillary services in the electricity grid (including

negative control reserve)

• 3. Testing and further development of megawatt class PEM

electrolysis

• 4. Intelligent and efficient hydrogen conditioning, storage and

handling, smart management structure

• 5. Research of effects of the increased hydrogen concentrations in

the gas grid and end devices

• 6. Public relations and public acceptance

11

Hydrogen value chain | Infrastructure H2 infrastructure initiatives in USA, Europe, and Japan

California Fuel Cell Partnership H2 USA HySUT JHFC H2 Mobility Germany CEP Germany H2 M UK H2M Netherlands H2M France SHHP Scandinavia

• HyNor
• H2 Sweden
• H2 Link, Denmark

North America Europe Asia

H2

as fuel

− California H2 Stations Road Map: By 2016: 51 stations

H2

infra- structure

− 50 HFS Program of BMVI (NIP) − EU: Clean Power for Transport Directive, Alternative Fuels Strategy, FCH JU, CEF − Hot Spot Germany: Focus of German OEMs due to funding structure (NIP ,CEP): H2Mobility − Various other projects in UK, Benelux, Scandinavia, etc. − Japanese NEV funding 2016: > 80 stations − Regional Korean HFS roll-out initiatives − Hot Spots Japan & Korea: Focus of OEMs due to funding structure (esp. METI in Japan) − China: growing activities

SHHP: Scandinavian Hydrogen Highway Partnership, JHFC: Japan Hydrogen & Fuel Cell Demonstration Project, HySUT: The Research Association of Hydrogen Supply/Utilization Technology, CARB: California Air Resources Board, ZEV: Zero Emission Vehicle, BMVI: Federal Ministry of Transport and Digital Infrastructure (DE), NIP: National Innovation Programme (DE), FCH JU: Fuel Cell and Hydrogen Joint Undertaking (EU), CEF: Connecting Europe Facility, CEP: Clean Energy Partnership (DE), NEV: New Energy Vehicle, METI: Ministry of Economy, Trade and Industry (JP)

− Hot Spot California: CARB Advanced Clean Cars Programm/ZEV regulations − First commercial market for utility fleet vehicles (FLT)

12

Hydrogen value chain | Hydrogen as a fuel Fuel Cell Electric Vehicles (FCEV) best alternative

Benefits of Fuel Cell Electric Vehicles (FCEV) — Zero emission tank–to-wheel — With renewable hydrogen: near zero emission well-to-wheel — Current ranges: 500 - 600 km — Refuelling time: 3 – 4 min — Silent driving like battery electric vehicles (BEV) Hyundai ix35 FCEV Start of production:

• Feb. 2013

Toyota „Mirai“ FCEV Start of production:

• Dec. 2014

Emission targets in major markets*

* Source: icct 2014

Honda FCEV “Clarity” Start of production: 2016

13 Metropolitan areas Motorways H2 corridors

H2 Mobility Goals

− Synchronize HRS roll-

• ut with FCEV ramp-up

− Create a common structure to de-risk HRS deployment − 100 hydrogen refuelling stations in the next four years − 200 to 400 hydrogen refuelling stations by 2023, distributed all

• ver the country

− 250,000 FCEVs on the roads in 2023 − 350 MEUR planned investments

Action plan for the construction of a hydrogen refuelling network in Germany by 2023

~400

stations

will Germany´s publichydrogen refueling network cover by 2023

~90

kilometres

lie between the H2 fuelling stations on the motorways around the metropolitan areas by 2023

>10 H2

fuelling stations

will be available in each metropolitan area from 2023

Hydrogen as a fuel | H2 mobility Hydrogen refuelling infrastructure in Germany

14

Hydrogen as a fuel | Bee Zero World‘s first hydrogen car sharing model

Create awareness and bring “H2-as- fuel” closer to the customer Collect data and learn about user behaviour Leverage learning experience for future H2 projects Demonstrate validity of the technology and foster market development H2 as fuel Data Learning Technology

Targets

15

The Fundamentals

• The plant works with up to 6 megawatt electric power.
• The central link between green power from wind energy and hydrogen are innovative hydrogen

electrolyzers from Siemens.

• Electrolyzers use modern PEM-electrolysis technology (Proton Exchange Membrane). This

enables a highly dynamic system operation, which is mandatory for a power supply from fluctuating renewable energy sources.

• The operation of PEM-electrolyzers in this performance category is a worldwide first, because

until now PEM-based systems were only used for small scale hydrogen production. Other essential system components include a two-stage ionic compressor, the gas feed, filling appliances and the switchgear.

• The “ionic compressor”, which was developed by Linde, compresses the produced hydrogen so

that it can be filled into storage tanks, gas pipes and tank trucks.

16

Electrolysis System

• Three SILYZER 200 electrolyzers equipped with

innovative proton exchange membrane (PEM) technology split water into hydrogen and oxygen using electrical direct current.

• The proton conducting membranes used in the

electrolyzer cells keep the gases apart reliably and offer a high safety level, also thanks to the innovative cell design.

17

Ionic Compressor

The ionic compressor, an in house development by Linde, is the core component of hydrogen

• conditioning. An “ionic liquid” (a liquid salt) lubricates, cools and seals the hydraulically driven

piston compressor, without adding any impuritues to the hydrogen. The unit has been designed for multivariable operation, including fast load changes and high efficiency at part load. With its two stages it can be used to feed both the storage vessels and the trailers. A further feature is the integrated drying of the hydrogen.

18

Trailer Filling

19 19

For Targeted segment only

H2 Production in Pakistan

20

Linde Pakistan Limited

7/17/2017

20

21

Linde Pakistan – A Success Story

Linde Pakistan has led the development of the industrial gases industry for more than 65 years

21

2015

Successful commissioning of PARCO GAN plant. 100% OEDAB 1-10 compliance.

2016

Installed Co2 compression Plant at WW Karachi Installed H2 Cyl filling in PQ Karachi

7/17/2017

22

Linde Pakistan

National Footprint - Plant Locations

22 Balochistan Sindh Punjab Khyber Pukhtunkhwa Gilgit - Baltistan

Afghanistan Iran Arabian Sea India Qasba Gujrat CRYOSS 1200 GAN plant 1200 m3/hr WW Karachi Head Office Dissolved Acetylene Special Gases blending and testing Cylinder filling – O2, N2, Ar, Co2 Process mixture blending and testing Port Qasim ASU 100 + 30 TPD Electrolytic Hydrogen 390 m3/hr CO2 23 TPD Dry Ice 8 TPD Multan CO2 60 TPD Lahore Sundar ASU 150 TPD Taxila Cylinder filling – O2, N2, Ar Hassanabdal Electrolytic Hydrogen 30m3/hr Wah DA Lahore Shalimar Nitrous Oxide 40 kg/hr Cylinder filling O2, N2, Process Mixture blending & testing

7/17/2017

23

H2 in PK

23

24 24

Thank You