EDFS VISION AND AMBITION ON HYDROGEN MITEIS 2019 SPRING SYMPOSIUM: - - PowerPoint PPT Presentation

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EDFS VISION AND AMBITION ON HYDROGEN MITEIS 2019 SPRING SYMPOSIUM: - - PowerPoint PPT Presentation

EDFS VISION AND AMBITION ON HYDROGEN MITEIS 2019 SPRING SYMPOSIUM: CAN HYDROGEN BECOME PART OF THE CLIMATE SOLUTION? E. BRIERE : Executive Vice President R&D programm on Renewable Energy, Storage, Hydrogen and Environment 1. CURRENT


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EDF’S VISION AND AMBITION ON HYDROGEN

  • E. BRIERE : Executive Vice President R&D programm on Renewable

Energy, Storage, Hydrogen and Environment

MITEI’S 2019 SPRING SYMPOSIUM: CAN HYDROGEN BECOME PART OF THE CLIMATE SOLUTION?

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CURRENT STATE OF THE HYDROGEN MARKET IN FRANCE

1.

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NH3 and fertilizer (19 %) Refining (42%)

Consumption (as a % of total consumption of 922,000 tonnes)

Operating (10%) Captive (30%) Co- production (60%)

Production chain

Diverse(3%)

COST between 1.5 and 4 €/kg per SMR depending on the flow rate Flow rate 1000 to 300 000 Nm3/h COST between 5 and 10 €/kg (by SMR with storage and transport) Flow rate <1000 Nm3/h 922,000 t/year 922,000 t/year

Burned Heat recovery (28%)

Chemistry (8%)

Production through SMR (40%)

Global vision of the hydrogen market in France

Unity of steam ref

MITEI’s 2019 Spring Symposium

10-15 kg CO2 Par kg d’H2

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Either20% of actual emissions

In addition to electric mobility. For example, on diesel rail lines that do not have enough traffic to be electrified.

By making new processes possible.

For example, the substitution of blast furnaces. by direct reduction furnaces. Avoidable emissions from French H2 production:

4 MtCO2/year

  • r 1% of France's total

emissions.

TOMORROW, Hydrogen could contribute to decarbonation:

Hydrogen can contribute to the decarbonation of the industry and heavy transport

0,9 Mt/y 0,36 Mt/y

TOTAL HYDROGEN PRODUCTION IN FRANCE

60% Fatal (co-produced) 40% Steam reformer (10kg of CO2 for 1kg of H2 produced)

OF TRANSPORT OF INDUSTRY

MITEI’s 2019 Spring Symposium

By substituting electrolytic hydrogen for the hydrogen produced by the steam reformer, the total French emissions would be reduced by 1% (reduction of CO2 emission during transportation of H2 is not take into account).

AS OF TODAY,

gCO2/kWh PCS

100 200 300 400

H2 produced by a steam reformer(cur rently used method) H2 produced by electrolysis with the French electric mix H2 produced by electrolysis with the European electric mix

EMISSIONS FROM DIFFERENT HYDROGEN PRODUCTION CHAINS

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COMPETITIVENESS OF ELECTROLYTIC HYDROGEN

2.

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Les différentes technologies d’électrolyse

§ Electrolyte polymère § Rendement : 70 – 80% pcs § Température : 50~60°C § Pression: 1 – 30 bar (200 bar possible) § Flexibilité, Pmin : 0 – 5%Pnom § Electrolyte céramique § Rendement : 75 – 95% pcs § Température : 750 - 850°C § Pression : 1 bar (30 bar démontrés echelle cellule) § Cellule (matériaux et architecture) identique aux piles à combustible céramique (SOFC)

Different electrolysis technologies

Technical features Advantages & Inconveniences Alkaline TRL _ 9

6 MW Alkaline electrolyser system (McPhy ex. Enertrag) – AUDI P2G plant Wertle

  • Potassium hydroxide electrolyte

(KOH)

  • Efficiency: 65 – 70% HHV
  • Temperature : 60~80°C
  • Pressure: 1 – 30 bars
  • Flexibility, Pmin = 20 to 40% of

Pnom

  • Reactivity: less than a min. in

warm strat

┼ Commercial technology, lowest investment costs today

(no noble metals)

┼ Large H2 production capacity (large surface of cells) ┼ Long and tested service life-span > 80,000 h

─ Limited flexibility and reactivity ─ Limited current density (0.2 to 0.4 A/cm²) = large footprint

PEM TRL _ 8/9

300 kW PEM electrolyser system (ITM) - Stadwerke Thüga Frankfort

  • Proton exhange polymer

electrolyte

  • Efficiency: 70 - 80% HHV.
  • Temperature: 50~60°C
  • Pressure: 1 - 30 bar (200 bar

possible)

  • Flexibility, Pmin = 0 to 5% of Pnom

┼ Flexibility and high reactivity (0% - 100% Pmax) ┼ High current density (up to 2 A/cm²)

  • CAPEX higher than alkaline à Noble metals (platinum,

iridium, ruthenium)

  • Limited lifetime: 40,000 h on baseload

SOEC TRL _ 5/6

150 kW SOE electrolyser system (Sunfire) – US Navy with Boeing California

  • Solid oxide ionic conductor

electrolyte

  • Efficiency: 75 - 95% HHV.
  • Temperature: 750 - 850°C
  • Pressure: 1 bar (30 bar

demonstrated at cell level)

  • Cell (materials and architecture)

identical to ceramic fuel cells (SOFCs)

┼ Yield > alkaline and pem ┼ CAPEX of the same order of magnitude as alkaline in

the long term >> absence of noble metals

┼ Production synergy with fuel cells to accelerate the

learning curve ─ No field return over the lifetime. 23,000 hours cell lifetime validated in the laboratory. ─ Flexibility and limited reactivity (same as alkaline)

MITEI’s 2019 Spring Symposium

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Decarbonizing Hydrogen … & remaining competitive Towards 3 €/kg

Le Levie viers Va Values Co Cost im impac act Re Remarks

Electricity price 60 €/MWh à 40 €/MWh

  • 1 €/kg

Spot market / self- consumption... Ability to modulate Technology / Efficiency 75 % HHV à 95% HHV

  • 0.8 €/kg

High Temperature Electrolysis with on- site heat supplying Technology / CAPEX 1000 €/kW à 600 €/kW

  • 0.5 €/kg

High capacity MW systems

ü Parameters keys of hydrogen cost àDistance production – consumption àProduction volume àà Electricity price(OPEX) àAnnual operation time duration (CAPEX) àCost of Heart of cell system (CAPEX) àEnergy efficiency

MITEI’s 2019 Spring Symposium

Hydrogen Price

Investment O&M O&M conditioning

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8 Possible additional transport costs linked to the geographical location of the production site if it is isolated (example: Atacama desert)

Limitations encountered

Solar in the Atacama Desert:

  • 2600 hours of

sunshine

  • 20 €/MWh of

LCOE CAPEX Electrolyser 800 €/kW Offshore wind turbine in the North Sea:

  • 4500 operating

hours

  • 50 €/MWh of

LCOE CAPEX Electrolyser 800 €/kW

3,5 €/kg

But if this decarbonated hydrogen is used locally and at an attractive cost: decarbonation of local uses without any particular additional cost.

The affiliation of H2 production to a dedicated ENR production is interesting if there is a sharp fall of electrolyzer’s production costs

Full production cost of an electrolyser (as a final output)

Number of operating hours of limited ENRs Impacts on the profitability of the electrolyser's CAPEX Unattractive to lower hydrogen production costs Increase in the cost of production at the end of the electrolyser

3 €/kg

With CAPEX at 500 €/kW : 2.5 €/kg 1) VARIABILITY OF RENEWABLE ENERGY 2) TRANSPORT OVER-COST

MITEI’s 2019 Spring Symposium

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DEVELOPMENT OF A CARBON- FREE HYDROGEN OFFER

3.

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§ Trains § Waste trucks § Bus § Fluvial

EDF, a key player in the energy transition and a low-carbon energy leader EDF GROUP Decarbonize the two most CO2-emitting sectors of the economy :

INDUSTRY MOBILITY

HYDROGEN

Small and medium industries Large industries

PROJETS FROM 0,5 TO 2 MW PROJETS FROM 20 TO 100 MW

Heavy Light

Light vehicle fleets, related to industrial projects

EDF's vision and ambition: Investing in hydrogen to reduce CO2 emissions in the economy

Reduce CO2 emissions from high energy and hydrogen consuming sectors On-site hydrogen production to replace bottles INDUSTRY MOBILITY

Building an H2 offer and creating and industrial and commercial tool for the group

H2 OFFER

MITEI’s 2019 Spring Symposium

SE SELECTED CO COUNTRIES

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Low-carbon production and on site Carbon-based and centralized production

  • Production via water

electrolysis

  • Production station as close

as possible to consumption

  • Production based on steam

methane reforming

  • H2 plant and truck delivery to

the place of consumption.

Gas reforming / by-product hydrogen Delivery Low-carbon electricity H2 Storage Distribution Water electrolysis

Hydrogen is reinjected Oxygen is evacuated

Usages

11 LOW-CARBON SOLUTION

The Hydrogen Supply Chain: From Production to consumption

MITEI’s 2019 Spring Symposium

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EDF’S EXPERTISE IN THE HYDROGEN DOMAIN & R&D CHALLENGES

4.

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Quelques projets d’EDF dans l’hydrogène

Site of « la Nouvelle », surrounding the experimentation Site of the Mafate micro-grid

Exemples of micro grid 100% ENR

CO2-free H2 for reducing the steel industry CO2 foot print - 2017

Few Hydrogen projects within EDF Group

Captive fleets and electrolyzers on site

MITEI’s 2019 Spring Symposium

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Quelques projets d’EDF dans l’hydrogène

R&D Hydrogen skills & facilities within EDF Group

ENERMAT PLATFORM Materials and Cells for Energy – Synthesis, Processing, Manufacture, Characterisation EIFER/ICT LAB High Temperature Electrochemistry Lab for Fuel Cells and Electrolysis Applications FCTESTLAB Individual Heat and /or Power Systems Supplied by Fuels

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Laboratories

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Patents

Benchmarking product [cells, stacks, system performance & endurance testing] Diagnosis product [ identification of parmater keys of degradation via Online EIS) & post-test (DRX, SEM/TEM…) analysis] An electrolyser test bench … at EDF Lab Les Renardières … directly connected to Concept Grid … connected to a 115 kW PV farm Test of electrolysis systems with units representative of production units of several hundred MW Characterization of systems Performances in normal and disturbed conditions, at different points and for different operation modes :

  • Understand degradation phenomena and main influencing parameters
  • Influence of electrolysis systems on the electricity grid
  • Impact on electrolysis systems from the power grid, including major disturbances
  • Characterization of the intrinsic flexibility of the systems
  • Economic studies of the value of flexibility in different scenario mix
  • Optimisation of the sizong of the systems : Power of the electrolyser / H2 storage

MITEI’s 2019 Spring Symposium

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CONCLUSION

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Conclusions : Low Carbon H2 can play a major role to decarbonize economy

"HEAVY INDUSTRY" (substitution of vapor reforming): carbon value and/or regulatory provisions necessary to promote carbon- free solutions "OTHER INDUSTRIES" (bottle substitution) close to cogeneration: capacity to lower H2 prices for industrial gases Segment according to volume , logistic costs and regulatory or tax provisions Limitation of the volume of injected H2 Need for important amount of subsidy for injection projects

INDUSTRY MOBILITY

Decarbonize the gas sector

POWER-TO-GAS

MITEI’s 2019 Spring Symposium Low-carbon H2 Low-carbon electricity Water electrolysis

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Thanks