III-V Nanoelectronics for Energy Efficient Information Processing
PhD Students: Vinay Saripalli (Intel), Dheeraj Mohata, Bijesh R., Mike Barth, Ashkar Ali Suman Datta Electrical Engineering Materials Research Institute (MRI)
III-V Nanoelectronics for Energy Efficient Information Processing - - PowerPoint PPT Presentation
III-V Nanoelectronics for Energy Efficient Information Processing PhD Students: Vinay Saripalli (Intel), Dheeraj Mohata, Bijesh R., Mike Barth, Ashkar Ali Suman Datta Electrical Engineering Materials Research Institute (MRI) March 01, 2012
PhD Students: Vinay Saripalli (Intel), Dheeraj Mohata, Bijesh R., Mike Barth, Ashkar Ali Suman Datta Electrical Engineering Materials Research Institute (MRI)
highest energy efficiency
transistor characteristics targeted for NTV computing
Variable precision floating point unit processor
Ge / InGaAs / InSb FINFETs
Enhanced CMOS Extended CMOS Beyond CMOS State of the Art CMOS
1E12 1E13 10
1
10
2
10
3
Si PMOS
Hole Mobility [cm
2/Vs]
Carrier Density [/cm
2]
Ga0.6In0.4Sb QW Layers
Stanford, NRL (IEDM '09)
1E12 1E13 10
1
10
2
10
3
10
4
10
5
Si NMOS
Electron Mobility [cm
2/Vs]
Carrier Density [/cm
2]
InAs1-xSbx QW Layers
Penn State, NRL (IEDM '10) x=0.2-0.3
InGaSb QW S.I. GaAs Nucleation and Buffer Layer Al0.8Ga0.2Sb buffer (Unified Buffer for NMOS and PMOS) InAsSb QW High-κ G S D NMOS High-κ G S D PMOS Isolation
InAlSb Barrier InAlSb Barrier
InAlSb Barrier InAlSb Barrier
4o(100) Offcut Si Substrate
ILD
Promising for III-V CMOS
Substrate Mismatch Accommodation Layer High Mobility QW Bottom Barrier Layer δ-doped Barrier Work Function Engineered S/D Metal High-k gate oxide Work Function Engineered Gate Metal Work Function Engineered S/D Metal
Device Architecture for Ultra-low VDD Logic
thin GaSb cap layer for dielectric integration
GaSb Cap: 2.5 nm Al0.8In0.2Sb Barrier: 9 nm InAs0.8Sb0.2 Channel: 12 nm Al0.8Ga.2Sb Buffer 5nm Al0.8Ga.2Sb Buffer GaAs Substrate QW Device Layers
1.5 µm
Device layers grown by Brian R. Bennett, NRL
10 20 30 40
0.0 0.4 0.8
EF E1 Al0.8In0.2Sb GaSb
Al0.8In0.2Sb InAs0.8Sb0.2 Al0.8Ga0.2Sb
Te δ−doping
E0
0.3eV
10
10
10
10
10
10
10
2
10
3
10
4
10
5
10
6
10
10
10
electrons holes 300K 2DEG 2DEG 2DEG 200K
77K
2/Vs]
4
5
6
Interface Charge
Model
Experiment
POP
ADP
Interface Roughness
Remote Ionized Impurity
Alloy
2/Vs]
Interface Charge Polar Optical Phonon Remote Ionized Impurity Acoustic Phonon Alloy Disorder Interface Roughness
10 20 30 40 50
% Contribution to 1/µ
T=300K
preparation prior to high-κ deposition
Surface clean on device layers with InAlSb surface Surface clean on device layers with GaSb cap on InAlSb barrier
300 nm
75kHz to 2MHz
300K
300K
250K
250K
Gate (Pd/Au)
n-GaSb (Te doping) ND=1x1018 /cm3 5nm Al2O3
Low Temp Plasma Enhanced ALD
High Temp ALD
75kHz to 2MHz
300K
300K
200K
200K
Gate (Pd/Au)
p-GaSb (unintentional doping) NA=1x1018 /cm3 5nm Al2O3
High Temp ALD Low Temp Plasma Enhanced ALD
12
13
2/eV]
High Temp ALD Low Temp PEALD
Dit extracted from multi-temperature CV/GV analysis of n&p GaSb MOSCAPs
Fermi Level movement at high-κ/GaSb interface for Sb QW MOSFET ON-OFF
10 20 30
0.0 0.5 1.0
GaSb Oxide
E
2
E
1
Buffer QW Barrier
E
F
E
V
Energy [eV] Distance [nm]
E
C
Sb QW MOSFET ON-State
10 20 30
0.0 0.5 1.0 1.5
GaSb Oxide
E
2
E
1
Buffer QW Barrier
E
F
E
V
Energy [eV] Distance [nm]
E
C
Sb QW MOSFET OFF-State
2]
Pd / (5 nm HfO
2-1 nm Al2O 3) / p & n-GaSb
Low Temperature ALD
12
13
ALD Al2O
3/HfO 2
TOXE=1.4 nm
2/eV]
PEALD Al2O
3
TOXE=3.1 nm
1nm Al2O3/10nm HfO2
S.I. GaAs Substrate Al0.8Ga0.2Sb Buffer : 1.5μm
InAs0.8Sb0.2 QW:12nm
GaSb : 1 nm
Al0.8In0.2Sb Barrier : 9nm
Te δ-doping
Pd/Pt/Au Drain Pd/Pt/Au Source
1nm Al2O3/10nm HfO2
S.I. GaAs Substrate Al0.8Ga0.2Sb Buffer : 1.5μm
InAs0.8Sb0.2 QW:12nm
GaSb : 1 nm
Al0.8In0.2Sb Barrier : 9nm
Te δ-doping
Pd/Pt/Au Drain Pd/Pt/Au Source Pd/Au Gate
As Grown Device Layers
S.I. GaAs Substrate Al0.8Ga0.2Sb Buffer : 1.5μm
InAs0.8Sb0.2 QW:12nm
GaSb : 2.5nm
Al0.8In0.2Sb Barrier : 9nm
Te δ-doping
S.I. GaAs Substrate Al0.8Ga0.2Sb Buffer : 1.5μm
InAs0.8Sb0.2 QW:12nm
GaSb : 2.5nm
Al0.8In0.2Sb Barrier : 9nm
Te δ-doping
Pd/Pt/Au Drain Pd/Pt/Au Source
Pd/Pt/Au Source-Drain Contacts and Device Isolation Gate Stack Processing
(HCl based surface clean)
Gate Patterning E-beam Lithography Final Processed Device
1nm Al2O3/10nm HfO2
S.I. GaAs Substrate Al0.8Ga0.2Sb Buffer : 1.5μm
InAs0.8Sb0.2 QW:12nm
GaSb : 1 nm
Al0.8In0.2Sb Barrier : 9nm
Te δ-doping
Pd/Pt/Au Drain Pd/Pt/Au Source Pd/Au Gate
stack(1 nm Al2O3 / 10 nm HfO2 on GaSb)
Pd/Au Gate LG= 150 nm
Devices Fabricated at the Penn State Nanofabrication Facility
10
10 10
1
10
2
Gm at VDS=0.5 V [µS/µm]
VDS=0.1V,0.5V LG=5µm
ID & IG [µA/µm] Gate Voltage [V] 100 200
10 10
1
10
2
ID & IG [µA/µm]
VDS=0.1V,0.5V LG=450 nm
Gate Voltage [V] 200 400 600 Gm at VDS=0.5 V [µS/µm]
10 10
1
10
2
VDS=0.1V,0.5V LG=150nm
Gate Voltage [V] 200 400 600 Gm at VDS=0.5 V [µS/µm] ID & IG [µA/µm]
performance)
device
In0.53Ga0.47As MOSFET InAsSb QW MOSFET
2/Vs]
Hall Mobility As Grown
2
charge density for trapped charge
2]
Measured Simulated
11
12
As Grown
Corrected for D
it
Extracted using Measured C-V
2/Vs]
10 10
1
10
2
VDS=0.1V,0.75V LG=450 nm
ID [µA/µm] Gate Voltage [V]
, DC , Pulsed (2µs)
15% 35%
VG-VT=1.25V VG-VT=0.75V
Closed - Pulsed (2µs) Open - DC
VG-VT=0.25V
31%
LG=450nm
DC due to reduced charge trapping from Dit
τ = Rtunnel x Cit τ ~ 0.5 – 2 µs
Gate
VG VD VS
Oxide GaSb Barrier Channel Barrier
JG
2
21
m
ω =
channel devices
eff T eff
+
B T
EC
L x
VG VD VS RD RS Qinj ID
Source Gate Drain
measured s-parameters of Sb NMOSFET
parameters obtained till 50 GHz
LG = 150 nm, WG=2x33 µm VGS-VT=0.6 V, VDS=0.75 V
0.2 0.5 1.0 2.0 5.0
0.2j
0.5j
1.0j
2.0j
5.0j
Measured Modeled
S11 2*S22 10*S12 S21
100 MHz to 50 GHz
InGaAs NMOS VDS=0.5V [2]
Strained Si [1]
7cm/s]
Si NMOS [1] VDS = 1.1-1.3V
[1] D. Antoniadis et al., IEDM 2008 [2] M. Radosavljevic et al.; IEDM 2009
4x higher than Si NMOS at 1.0-1.2 V VDD 1.5x higher than InGaAs NMOS at 0.5 V VDS
device electrostatics
1
2
1 5 m V / d e c
VDS=0.05V,0.5V
350mV/dec
D-Mode
1
2
2 5 m V / d e c
VDS=0.05V,0.5V LG=150 nm
7 m V / d e c
D-Mode
samples: E-Mode : 13000 cm2/Vs at ns=2.2x1012 /cm2 , D-Mode : 5,500 cm2/Vs at ns=1.8x1012 /cm2
Strained Si [1]
7cm/s]
Si NMOS [1] VDS = 1.1-1.3V
[1] D. Antoniadis et al.,IEDM 2008
Assume 5nm Sb Quantum well ION = q x ns x veff = (1.6 x 10-19 C ) x (3.5 x 1012 /cm2)x (2.7 x 107 cm/s)
Experimentally demonstrated Projected based
= 1.5 mA/µm ION = ? at VG-VT = 2/3 x VDD ~ 0.3V Assuming RS as in Si (~ 80 Ω.µm): ION = 960 µA/µm at VG-VT~ 0.3V Key Challenges:
Sw itching slope in TFETs can be less than kT/ q
TFET: SS < kT/ q possible MOSFET: SS > = kT/ q
Gate Gate
i-channel
P++ Source N+ Drain
high-k high-k
Tb TOX EFS EFD
Band-pass filter
Filled States Empty States Band-gap EFC
0.0 0.1 0.2 0.3 0.4 0.5 10-11 10-9 10-7 10-5 10-3 10-1 101 103
InSb TFET InAs TFET In0.53Ga0.47As TFET Si TFET Si MOSFET
Drain Current, IDS [µA/µm] Gate Voltage, VGS [V]
VDS=0.5V
60mV/dec
Silicon
I n 0 .5 3Ga 0 .4 7As
I nAs I nSb IOFF ION
Eb Wb
Both I ON and I OFF increase w ith reducing band-gap
LG=32nm EOT=0.5nm Tb=7nm Simulations
Gate Gate
i-channel
P++ Source N+ Drain
high-k high-k
Tb TOX
Si MOSFET Si TFET In0.53Ga0.47As TFET InAs TFET InSb TFET
VCC=0.5V
Simulations
Maxim ize stagger to get m axim um enhancem ent in I ON
Hom J TFET Eg Eg Source channel
) ) ( (
5 . 1
beff
E
β
−
High Stagger HetJ TFET ∆Ec Eg Eg Source channel
c g beff
TUD Ultrathin geometry for robust electrostatics Drain-Gate underlap to minimize ambi-polar leakage
Gate Gate
i-channel
P++ Source N+ Drain
high-k high-k
Tb TOX LG Electric Field Abrupt tunneling junction
Source Channel
III-V / high-k interface with low Dit
Source Channel Source Channel Drain
Mo i N+ Gate ILD Drain Gate III-V / high-k interface with low Dit Pillar based ultrathin Tb In situ doped Molecular Beam Epitaxially grown junctions Drain-Gate underlap structure
1nmAl2O3/3.5nmHfO2
39
39
Reduce Eg
High Stagger
N+ i P++ In0.53Ga0.47As Mo high-k Pt ILD Au Pd Ti
Cross-section TEM im age of the fabricated devices
350nm 450nm Ti 350nm
10 20 30 40 50 60 Drain Current, IDS [µA/µm] Drain Voltage, VDS [V] Vgs=0V to 2.5V at steps of 0.5V
20 40 60 Drain Current, IDS [µA/µm] Drain Voltage, VDS [V] Vgs=0V to 2.5V at steps of 0.5V
50 100 150 200 Drain Current, IDS [µA/µm] Drain Voltage, VDS [V] Vgs=0V to 2.5V at steps of 0.5V
(ION ↑ 2.5x)
W ith High HetJ TFET, I ON increases by 6 6 0 %
5 10 15 20 25 Drain Current, IDS [µA/µm] Drain Voltage, VDS [V] Vgs=0V to 2.5V steps of 0.5V
Sm all Eg Hom J Large Eg Hom J High Stagg. HetJ
Lg=100nm EOT=1.5nm Lg=100nm EOT=1.5nm Lg=150nm EOT=1.5nm Lg=150nm EOT=1.5nm
10-4 10-3 10-2 10-1 100 101 102 Drain Current, IDS [µA/µm] Gate Voltage, VGS [V] Vds=50mV Vds=250mV Vds=500mV
10-6 10-5 10-4 10-3 10-2 10-1 100 101 102 Drain Current, IDS [µA/µm] Gate Voltage, VGS [V] VDS=50mV VDS=250mV VDS=500mV
0.0 0.5 1.0 1.5 2.0 10-6 10-5 10-4 10-3 10-2 10-1 100 101 102 Drain Current, IDS [µA/µm] Gate Voltage, VGS [V] VDS=500mV VDS=250mV VDS=50mV
10-6 10-5 10-4 10-3 10-2 10-1 100 101 102 Drain Current, Id [µA/µm] Gate Voltage,VGS [V] VDS=50mV VDS=250mV VDS=500mV
Experim ental I OFF is increasing w ith stagger
Sm all Eg Hom J Large Eg Hom J High Stagg. HetJ
Lg=100nm EOT=1.5nm Lg=100nm EOT=1.5nm Lg=150nm EOT=1.5nm Lg=150nm EOT=1.5nm
60mV/dec
77K 300K 15.4mV/dec
BTBT TAT T=300K T=77K
VDS=50mV,500mV SRH
Measured I d-Vg Sw itching Slope
Source Channel
f=75kHz Due to Dit 1nmAl2O3/3.5nmHfO2 CET=2.3nm
Ideal n-In0.53Ga0.47As
1 m s and 1 µs
Measured
Simulations DC pulsed (tr=600ns) pulsed (tr=200ns)
VDS=300mV
Vcc +
S G 50Ω
To Oscilloscope
Sw itching slope im proves w ith ram p rate and appears approaching ideal sw ing
R1 Gain=100,000 ***Pulsed IV measurements conducted at NIST (John Suehle)
tr
Simulations DC Pulsed (tr=600ns) Pulsed (tr=200ns)
60mV/dec
VDS=0.3V
Point sw itching slope approaches kT/ q @ 3 0 0 K
***Pulsed IV measurements conducted at NIST (John Suehle) Vcc +
S G 50Ω
To Oscilloscope
R1 Gain=100,000 tr
High HetJ Small Eg HomJ M
Strained Si M OSFET (VT=0.2V) Large Eg Homj
For Vcc less than 3 0 0 m V, BTBT can potentially deliver MOSFET like on current
Experimental (EOT=1.5nm, Tb=200nm)
Large Eg HomJ Small Eg HomJ
High HetJ
Measured Simulations
VDS=0.5V
EOT=1.5nm TP=200nm
Junction
Ebeff (eV) mR (mO) In0.53Ga0.47As (Large Eg homJ) 0.74 0.023 In0.7Ga0.3As (Small Eg homJ) 0.59 0.019 GaAs0.5Sb0.5/In0.53Ga0.47As (Moderate stagger hetJ) 0.5 0.025 GaAs0.35Sb0.65/In0.7Ga0.3As (High stagger hetJ) 0.25 0.022
Need for Extrem ely Staggered / Nearly Broken I nAs/ GaAs0 .1Sb0 .9 tunnel junction to replace MOSFET @ Vcc= 3 0 0 m V
Strained Si MOSFET
Large Eg Nearly broken
VCC=0.3V High HetJ Simulations (EOT=0.5nm, Tb=7nm, LG=32nm)
VCC=0.5V
Large Eg Nearly broken High HetJ
Strained Si MOSFET
Si
Planar Tri-Gate Gate-All-Around
SiGe
1D strained QW nanowire New opportunity: 0D QD
III-V
Vout(mV) Vin(mV) 300 300
sub 500mV CMOS Logic
Vg(V) 0.1 0.2 10 Id (nA)
sub 250mV BDD Logic
QW epitaxy Fin definition and etching (BCl3/Ar) S/D contact (Au/Ge/Ni) High-K deposition (1nm Al2O3+3.5nmHfO2) Metal gate stack (Au/Pd) S/D Contact Opening QW
52
mode
InP 2 nm In0.52Al0.48As 2nm In0.53Ga0.47As 14nm In0.52Al0.48As 2nm δ-doping 2E12 cm-2 InAlAs virtual substrate
Gate
WFIN decreases
WFIN =10nm WFIN =40nm WFIN =100nm WFIN =500nm
WFIN decreases
WFIN =10nm WFIN =40nm WFIN =100nm WFIN =500nm
54
Mobility (cm2/V-sec)
structures
Sheet charge density NS (cm-2)
300K 300K
SG 80nm 40nm
CG SG source Drain Control gate (CG) CG Split Gate (SG) High-K
Binary Decision Diagram (BDD) Logic CMOS Logic
short
Source: L. Lu, V. Narayanan, S. Datta IEDM, Dec 2011 Supported by NSF
Planar Si MOSFET Silicon MuGFET InGaAs MuQFET III-V TFET SET
0.01 x10-16 J Si Planar (32nm) Si MuGFET (14/22nm) III-V MuGFET III-V Tunnel FET III-V SET
60
www.mri.psu.edu/facilities/Nanofab
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www.mri.psu.edu/facilities/Nanofab