COLD Spray POWDER REQUIREMENTS Selection criteria: only the powders - - PowerPoint PPT Presentation

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COLD Spray POWDER REQUIREMENTS Selection criteria: only the powders - - PowerPoint PPT Presentation

COLD Spray POWDER REQUIREMENTS Selection criteria: only the powders of materials that can deform plastically, can be sprayed by cold spray. Ceramics and polymers cannot be applied by cold spray. Thus Metals and Alloys are the main


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COLD Spray

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SLIDE 2

POWDER REQUIREMENTS

  • Selection criteria: only the powders of materials that can deform plastically, can be sprayed by

cold‐spray.

  • Ceramics and polymers cannot be applied by cold spray.
  • Thus Metals and Alloys are the main choice.

– Face Centred Cubic (F.C.C.): structure metals, such as Al, Cu, Ag, Au, Pt, Ni, and γ‐Fe Having large number of planes and thus can be deformed and are thus best for cold spray – Body Centred Cubic (B.C.C.): structure metals, such as W, Ta, Mo, Nb, V, Cr, α‐Fe and β‐Ti. – Hexagonal Close‐Packed (H.C.P.): structure metals, such as Cd, Zn, Co, Mg and Ti.

  • The H.C.P. metals have lesser deformability, while the B.C.C. metals have the lowest

deformability.

  • M.P. is Another indication of sprayability. The low value of melting temperature is beneficial for

the ability to spray.

  • On the other hand, materials that harden under mechanical stress, such as the stainless steel

316/304 or the alloy TiAl8V4, are difficult to spray.

  • In practice, the most popular material sprayed by cold‐spray is Cu.
  • Important technological metal and alloys, such as Ta, NiCr, NiCrAlY or CuAl, have been

successfully processed by this technique.

  • Helium was used to spray most of these. Coating of metal‐ceramic composites, such as NiCr +

Cr3C2, have also been obtained in this way .

  • Particle size: 5‐20μm.
  • Particle temperatures and velocities: 500oCand particle velocities 600m/s for Cu particles

(15μm) with an optimized initial working gas (nitrogen).

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Cold Spray

Plasma Giken Kogyo co., ltd

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SLIDE 4

S.No Parameter Value 1 Stagnation jet pressure, MPa (psi) 1‐3 (145‐435) 2 Stagnation jet temperature, °C 0–700 3 Gas flow rate, m3/min ( 1–2 4 Powder feed rate, kg/h 2–8 5 Spray distance, mm 10–50 6 Power consumption, kW (for heating gas) 5‐25 7 Particle size, μm 1–50 8 Operating gases Air, N2, He, and their mixtures Typical range of gas‐jet parameters for cold spray

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SLIDE 5

Advantages

  • Low temperature process, no bulk particle

melting

  • Retains composition/phases of initial

particles

  • Very little oxidation
  • High hardness, cold worked

microstructure

  • Eliminates solidification stresses, enables

thicker coatings

  • Low defect coatings
  • Lower heat input to work piece reduces

cooling requirement

  • Possible elimination of grit blast substrate

preparation

  • No fuel gases or extreme electrical

heating required

  • Reduce need for masking

Limitations

  • Hard brittle materials like ceramics can

not be sprayed without using ductile binders

  • Not all substrate materials will accept

coating

  • High gas flows, high gas consumption.
  • Helium very expensive unless recycled
  • Still mainly in research and development

stage, little coating performance/history data

Main Uses

  • Improved Corrosion protection, performance
  • Improved Electrical and thermal conductivity.
  • No grain growth – good methods for nano powders.
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MICROSTRUCTURES OF VARIOUS COATINGS HVOF Flame Spray Air Plasma

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Comparison of various Thermally Sprayed Coatings

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SLIDE 8
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Comparison of various Thermal spray

Processes

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Flame Spray Process

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Important Applications

Room temperature Coatings on structures in highly aggressive environments. Highly hard coatings High Temperature Oxidation, sulphidation and hot corrosion resistant coatings

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SLIDE 12
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SLIDE 13

Machinery

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SLIDE 14

Steel Industry

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Consumer Goods

High Temperature resistant Coating that can withstand heat during ironing

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Probe Tube of a Fludized bed Reactor

The probe (a) before the exposure and (b) after the 5900 h exposure in the biomass co‐fired boiler. On the left side the section with specimens at 550 C and on the right the specimens at 750 C

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SLIDE 17

HVOF Coating for 550‐750oC

Optical micrographs of the coatings and the T92 reference material after the exposure at 550 C. (a) T92, (b) NiCr‐F_CJS, (c) IN65_DJ, and (d) NiCr‐C_DJ. EDX analyses of the corrosion scales of T92 (1, 2) are presented below the images [wt.%]

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SLIDE 18

PROCES PARAMETERS OF CGDS AND HVOF Parameter He processing N2 processing Values Values Gun temperature 400 0C 450 0C Gun pressure 20 bars 38 bars Powder flow rate 18 g/min 15 g/min Carrier gas flow rate 3.0 m3/hr 3.0 m3/hr Number of passes 4 6

  • Table. Cold spray process parameters sprayed with helium and nitrogen gases

Sr.no Gas Flow (LPM) Operating pressure kg/cm3 1 Oxygen 350 10 2 LPG 70 7 3 Air 550 6 Sr.no. Parameter Values 1 Carrier gas (N2) 5 LPM 2 Powder feed rate 36 g/min 3 Average particle temperature 1900 0C 4 Average particle velocity 300 m/s 5 Standoff distance 30 cm 6 Deposition efficiency 40%

  • Table. Operating parameters of spray gun

(HIPOJET-2700)

  • Table. HVOF process parameters

IIT, BOMBAY MEC, Jodhpur ASB, Industries Ohio (US)

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SLIDE 19

SUBSTRATE AND POWDER USED

Chemistry of powder Powder particle size Method of manufacturing Co32Ni21Cr8Al0.5Y 10-42μm Gas atomized

  • Fig. Plot of cumulative volume % vs particle diameter

Mean = 32.20μm Median = 32.63μm Laser Diffraction Grade C Mn Si P S Cr Mo Ni N 316L 0.018 1.30 0.36 0.032 0.003 16.62 2.07 10.12 0.047

  • Table. Chemical composition of austenitic stainless steel (316L) (wt-%)
  • Table. As-received CoNiCrAlY powder
  • Fig. Powder morphology

IIT, BOMBAY Powder purchased from M/s. Metallizing Equipment Pvt. Ltd. Jodhpur, trade name MEC 9950 AMF

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Deposition properties He processing N2 processing HVOF processing Thickness of coating 320-360μm 105-115μm 165-299μm Microstructural features Dense and compact coating Pores and porosity Porosity and visible defect Surfaces roughness Values Ra (µm) 23.41±1.30 16.04±1 8.41±0.55 Porosity level (%) 0.9±0.8 5±0.9 16±0.9 Interface Mechanically bonded Interface between two particles and porosity present Shrinkage

  • f

the molten droplets, porosity and visible defect Extent

  • f

plastic deformation of powder particles High degree

  • f

plastic deformation Lower degree of plastic deformation High degree

  • f

plastic deformation and Shrinkage

  • f

the molten droplets

PROPERTIES OF HVOF AND CGDS HE AND N2 PROCESSED CoNiCrAlY SPRAYED DEPOSITION.

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AS-SPRAYED CROSS-SECTION OF HVOF AND CGDSPRAYED WITH He ANDN2 CARRIER GASES COATINGS

  • Fig. SEM images of CGDS and HVOF coatings in as-sprayed condition

IIT, BOMBAY

Sr.no. He N2 Density (kg/m3) 01785 1.250 Specific Heat ratio 1.660 at (200C) 1.404 at (150C)

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SLIDE 22
  • Fig. SEM images and EDX compositions at cross-section of CGDS and HVOF coatings

EDX COMPOSITION AT CROSS-SECTION OF CGDS AND HVOF COATINGS

IIT, BOMBAY

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SUMMARY

Deposition properties CGDS He processing CGDS N2 processing HVOF processing Thickness of coating 320-360μm 105-150μm 165-299μm Microstructural features Dense and compact coating Pores and porosity Porosity and visible defect Surfaces roughness Values Ra (um) 23.41±1.30 16.04±1 8.41±0.55 Porosity level (%) 0.9±0.8 5±0.9 10±0.9 Extent of plastic deformation of powder particles High degree of plastic deformation Interface between two particles and porosity present due to insufficient plastic deformation High degree of plastic deformation and Shrinkage of the molten droplets Hardness 6.60 6.35 5.04

IIT, BOMBAY

  • Table. Summary of as-sprayed coatings
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KINETICS OF HVOF AND CGDS SPRAYED WITH He AND N2 COATINGS

  • The parabolic law the rate is

inversely proportional to the square root of time, is found to be

  • beyed

when diffusion through the scale is the rate determining process

  • Where Δm = mass gain in g;
  • A= total surface area of the

sample in cm2;

  • Kp= constant in g2/cm4s-1;
  • t= time in s
  • Fig. Mass gain curve obtained during isothermal
  • xidation of the CGDS and HVOF coatings after

the oxidation at 900 0C for 1000 hrs Kp= 1.28x10-8 g2/cm4s-1; for HVOF and Kp= 0.510x10-8 g2/cm4s-1 for CGDS He coating Kp= 0.100x10-8 g2/cm4s-1 for CGDS N2 coating

IIT, BOMBAY

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SLIDE 25

IIT, BOMBAY

  • Fig. Oxide scale surface morphology of HVOF coating after the oxidation at 900 0C for different

exposure times

  • Fig. Cross-section microstructure of HVOF coating after the oxidation at 900 0C for different times

OXIDATION STUDY

SURFACE SCALE MORPHOLOGY OF THE HVOF COATING

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SLIDE 26

Fig.EDX analysis of the HVOF coating after the oxidation at 900 0C for different times

EDX analysis of the HVOF coating after the oxidation at 900 0C for different times

IIT, BOMBAY

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Fig.EDX analysis of cross-section of the HVOF coating after the oxidation at 900 0C for different times

EDX analysis of cross-section of the HVOF coating after the oxidation at 900 0C for different times

IIT, BOMBAY

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Coatings Weight (N) Track diameter (mm) Velocity (m/s) Rpm Bare 316L 5,10,15 40,60,80 0.4 190,127,96 HVOF 5,10,15 40,60,80 0.4 190,127,96 CGDS He 5,10,15 40,60,80 0.4 190,127,96 CGDS with N2 5,10,15 40,60,80 0.4 190,127,96

  • Table. Parameters for wear a studies

WEAR AND FRICTION BEHAVIOUR OF CoNiCrAlY POWDER The coating samples were prepared in the form of square pin with a dimension of 10x10x1 mm and fixed into the square pin fixture having dimension 10x10x0.5 mm size

IIT, BOMBAY

  • Fig. Experimental setup for pin-on disc
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SECTION - I WEAR AND FRICTION OF AS-SPRAYED COATINGS AND BARE 316L STAINLESS STEEL

IIT, BOMBAY

  • Fig. Wear rate and coefficient of friction of 316 L SS and coatings
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SECTION - I WEAR AND FRICTION OF AS-SPRAYED COATINGS AND BARE 316L STAINLESS STEEL

IIT, BOMBAY

  • Fig. wear rate and coefficient of friction of coatings
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Restoration of Structure

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Why lasers ?

Three important properties of lasers:

Directionality

High Intensity

(108W – compared to 8W of a normal incandescent bulb) &

Spatial Resolution

Make laser as one of the versatile heat source

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SLIDE 33

LASER stands for Light Amplification by Stimulated Emission of Radiation

Active Medium

Solid crystals such as ruby or Nd:YAG liquid dyes, gases like CO2 or Helium/Neon, semiconductors such as GaAs

Excitation Mechanism

Pump energy into the active medium by one or more of three basic methods; optical, electrical or hemical

High Reflectance Mirror

A mirror which reflects essentially 100% of the laser light

Partially Transmissive Mirror

A mirror which reflects less than 100% of the laser light and transmits the remainder.

This is a device to produce a beam of monochromatic light in which all the waves are in phase or are coherent. Components of laser

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Description of laser with lasing action

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Lasing Action

Coherent Beam Incoherent beam

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Important Laser Parameters

1. Power Density w/cm2 2. Interaction Time ( Laser Sweep Speed) 3. Type of laser – Continuous/ Pulse 4. Shape of beam & extent of overlapping 5. Shape and size of laser beam

Continuous Pulse

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Domain of Laser Material Processing

IIT Bombay, India

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1. Gas lasers – CO2 Laser 2. Solid State lasers – Nd-YAG Laser 3. Semi-conductor ( Diode) laser 4. Fiber-lasers (Ytterbium )- (Output power, pulse energy, repetition rate and pulse width)

Types of lasers

Commercially Available lasers have power up to 12-20 kW in CW made Diode lasers of power upto 10 kW are available For surface Engineering – solid State lasers/Diode lasers are equally good

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For improving Corrosion and Oxidation

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IIT Bombay, India

Example of laser Alloying

750 mm/min 625 mm/min 575 mm/min 500 mm/min

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Oxidation behaviour at 800oC Corrosion behaviour in 1N H2SO4 Consequence of Laser Alloying on the Oxidation and Corrosion Behaviour Of Steel

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Development of Super‐austenitic SS using Ni‐Cr‐Mo Alloying

Sample designation Scan speed (mm/min) Laser power (watts) Spot Size (mm2) Melt Depth ( µm) Effect of laser Scan Speed LSA 1 500 3000 0.5x6.0 405 LSA 2 750 3000 0.5x6.0 383 LSA3 1000 3000 0.5x6.0 361 LSA4 1250 3000 0.5x6.0 432 Effect of laser Power LSA 5 750 1000 0.5x6.0 364 LSA 6 750 2000 0.5x6.0 431 LSA 2 750 3000 0.5x6.0 383 LSA 7 750 4000 0.5x6.0 425 Effect of Spot Size LSA 2 750 3000 0.5x6.0 383 LSA 9 750 3000 0.75x6.0 649 LSA 8 750 3000 1.0x6.0 683

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Corrosion Behaviour of laser alloyed 304 SS – better than commercially Available SM) 254

Showing Better Pitting Behaviour Plasma Coating of Ni % Mo.

Cross section after laser Treatment

Surface Morphology

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Performance of laser clad heat exchanger tube with Ni-25Cr alloy exposed in coal fired power plant for a year

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Optical micrographs showing the fire cracks

  • n the heat exchanger tube exposed in a

coal-fired power plant

Without Cladding After Cladding with Ni-25Cr-alloy

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Laser Parameters

Sample No. Scan Speed (mm/min) 1 400 100Ni 2 500 3 600 4 1000 100WC 5 1200 6 800 7 800 35WC 8 1000 9 600

Laser Glazed Coatings

Laser Type :::: Nd:YAG Laser Power :::: 2000 W Shielding gas :::: Ar at 30 lt /min Nozzle Substrate :::: 260mm Distance

Laser Alloying Process and Coated Samples

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Characterization of Coatings Surface Characteristics Sample Ra (μm) 100%NiCrBSi 9.011 15%WC/Co 85%NiCrBSiFe 5.558 35%WC/Co 65%NiCrBSiFe 8.467 60%WC/Co 40%NiCrBSiFe 9.387 100%WC/Co 7.644 100%NiCrBSiFe Coating 15%WC/Co- 85%NiCrBSiFe 35%WC/Co 65%NiCrBSiFe Coating 60%WC/Co 40%NiCrBSiFe Coating 100%WC/Co Coating

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Schematic Representation

  • f Laserforming Process
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Arrangement of the Process Set Up

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IIT Bombay, India

MECHANICAL PROPERTIES OBTAINED

Sample Name Yield Strength (MPa) UTS (MPa) Elongat ion (%) A1 (along the layers) 550 840

22

A2 (Heat treated) 602 1051

11

B1(Perpe ndicular to layers) 415 688

11

B2 (Heat treated) 306 370

5

0.5 1 1.5 2 2.5 3 200 400 600 800 1000 1200

Weight gain in gms/cm2 Time in hrs

  • xidation behavior of laserformed Incoenl 718 at 950°C

conventional Inconel 718 Laser formed alloy

0.0001 0.0002 0.0003 0.0004 0.0005 0.0006 0.0007 0.0008 0.0009 100 200 300 400 500 600 700

Weight change in gms/cm2 Time in Hrs Sulphidation Behaviour

Conventional alloy 718 Laserformed Inconel 718

RESULTS

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Halfway Turbine Blade

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Laser Cladded Inconel 718

Ingomar Kelbassa1, Ernst Wolfgang Kreutz1, Patrick Albus1, Leping Zhu2 FIL, Aachen

UTS) and YS of laser cladded Inconel 718 T = 20 °C and at T = 650 °C Green – NO HT Red HT 730oC 4H