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A New Look at Anthropogenic Atmospheric Carbon Dioxide David Hofmann and Pieter Tans NOAA Earth System Research Laboratory Global Monitoring Annual Conference Boulder, Colorado May 14-15, 2008 Atmospheric CO 2 Atmospheric CO Growth Rates


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SLIDE 1

A New Look at Anthropogenic Atmospheric Carbon Dioxide

David Hofmann and Pieter Tans NOAA Earth System Research Laboratory

Global Monitoring Annual Conference Boulder, Colorado May 14-15, 2008

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SLIDE 2

Mauna Loa Observatory

Atmospheric CO Atmospheric CO2 Growth Rates Have Been Increasing Growth Rates Have Been Increasing

1950 1960 1970 1980 1990 2000 2010

Parts per Million

300 325 350 375 400

1 ppm per year 2 1.5

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SLIDE 3

Surge in carbon levels raises fears of runaway warming

  • David Adam Environment correspondent
  • The Guardian,
  • Friday January 19 2007
  • Article history

About this article

Close This article appeared in the Guardian on Friday January 19 2007 on p1 of the Top stories section. It was last updated at 15:45 on September 07 2007.

Mist and pollution over London. Photograph: Matthew Fearn/PA

Carbon dioxide is accumulating in the atmosphere much faster than scientists expected, raising fears that humankind may have less time to tackle climate change than previously thought. From 1970 to

2000 the concentration rose by about 1.5ppm each year…. the carbon dioxide level has risen by an average 2.2ppm each year since 2001. Experts are puzzled because the spike, which

follows decades of more modest annual rises, does not appear to match the pattern of steady increases in human emissions….

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SLIDE 4

Processing the Mauna Loa and Global CO2 Records:

  • Remove the seasonal variation (technique for filtering data to remove the

seasonal variation first described by Thoning et al., J. Geophys. Res. 94, 8549-8565, 1989).

  • Remove the pre-industrial component. Reduce the CO2 concentration to

that which is changing, the anthropogenic component.

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SLIDE 5

Ice Core Data: Siegenthaler, U., E. Monnin, K. Kawamura, R. Spahni, J. Schwander, B. Stauffer, T.F. Stocker, J.-M. Barnola and H. Fischer.

  • 2005. Supporting evidence from the EPICA Dronning Maud Land ice core for atmospheric CO2 changes during the past millennium. Tellus

57B, 51-57(7).

1000 1200 1400 1600 1800 Carbon Dioxide (ppm) 270 275 280 285 290 295 AVERAGE = 280 ± 2 ppm

Antarctic Ice Cores – Preindustrial Carbon Dioxide

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SLIDE 6

1950 1960 1970 1980 1990 2000 2010 Anthropogenic Carbon Dioxide (ppm) 30 50 70 90 110 Mauna Loa Global

1.43 ppm/yr

The Mauna Loa and Global Deseasonalized The Mauna Loa and Global Deseasonalized Record Record

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SLIDE 7

Semi-logarithmic Presentation of the Data

(exponential functions are straight lines)

1950 1960 1970 1980 1990 2000 2010 Anthropogenic Carbon Dioxide (ppm) 100 Mauna Loa Global 50 30

dC/dt = 0.86[exp ( ln2(YR-1958)/31)] ppm/yr

Carbon Dioxide Growth Rate (ppm/yr) 1

C = 280 + 34.5[exp ( ln2(YR-1958)/31)] ppm

0.75 2.75 2

τd = 31 yr

dC/dt ~ C ~ e t/τ

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SLIDE 8

Ice Core Data: Siegenthaler, U., E. Monnin, K. Kawamura, R. Spahni, J. Schwander, B. Stauffer, T.F. Stocker, J.-M. Barnola and H. Fischer.

  • 2005. Supporting evidence from the EPICA Dronning Maud Land ice core for atmospheric CO2 changes during the past millennium. Tellus

57B, 51-57(7).

1800 1850 1900 1950 2000 Anthropogenic Carbon Dioxide (ppm) 0.1 1 10 100 Mauna Loa Antarctic Ice Cores

Extrapolating Back in Time

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SLIDE 9

1950 1960 1970 1980 1990 2000 2010 Growth Rate - (ppm per year) (% per year) 0.1 1 10 Linear Exponential 0.5 5

While the linear CO While the linear CO2 growth rate has growth rate has increased from increased from ~0.5 to ~2 ppm/yr, the ex ~0.5 to ~2 ppm/yr, the exponential growth ponential growth rate has rate has remained ~ constant at about 2.3 %/yr remained ~ constant at about 2.3 %/yr

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SLIDE 10

Anthropogenic Carbon Dioxide (ppm) 30 40 50 60 70 80 90 100 1950 1960 1970 1980 1990 2000 2010 Residual (%)

  • 5

5

34.5exp[0.693(T-1958)/31]

Using the residuals (data – function) for analysis

Agung Pinatubo

The two largest negative excursions of the residuals followed major volcanic eruptions. There were no significant changes following major ENSOs (e.g.,1982-83 and 1997-98), although the 1982 ENSO may have offset an effect from the 1982 El Chichón eruption.

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For the past 14 Years, the residual has been ~ ± 1 %

The annual average residual may be a useful index for detecting a deviation away from exponential growth in the future

Anthropogenic Carbon Dioxide (ppm) 70 80 90 100 1994 1996 1998 2000 2002 2004 2006 2008 2010 Residual (%)

  • 5

5

34.5exp[0.693(T-1958)/31]

110 Annual Average Residual

11

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SLIDE 12

1950 1960 1970 1980 1990 2000 2010 Fossil Fuel Emissions (billion tonnes CO2 per year) GDP (trillion US dollars), Population (billions) 10 100

24

Sources: United Nations: unstats.un.org Energy Information Admin: eia.doe.gov/iea/carbon.html Carbon Dioxide Information Analysis Center: cdiac.ornl.gov Hofmann et al. (2006)

36

3 5

Population GDP All Fossil Fuels

Uptake by Oceans and Terretrial Biosphere

Mauna Loa Global Coal Consumption

50 30

Anthropogenic C02 (ppm)

30

WHY EXPONENTIAL?

One would expect atmospheric carbon dioxide to follow fossil fuel emissions closely, however, this does not seem to be the case. The slowdown in emissions following the 1973 “oil crisis” was not reflected in the CO2 record, nor was the reduced emission rate after 1980 (τd increased from 16 to 45 years). Exponential increases are normal

  • utcomes when the increase in a

quantity depends on how much of the quantity exists: dC/dt ~ C. Some that affect carbon dioxide are the world population and domestic

  • production. They affect atmospheric

CO2 through both sources and sinks and have similar growth rates.

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SLIDE 13

1950 1975 2000 2025 2050

Parts per Million (logarithmic scale)

100

450 ppm - 2028 560 ppm (2 x CO2) - 2050

400 30

Time to 450 ppm and 2 x CO2 for Business as Usual

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SUMMARY

The deseasonalized anthropogenic component of atmospheric carbon dioxide has increased exponentially even before atmospheric measurements began. This explains why the linear growth rates have been increasing with time. The reduction in fossil fuel emissions following the “oil crisis” of 1973 did not appreciably affect the exponential growth in the CO2 level at Mauna Loa, nor has the recent upturn in coal consumption, a lesson for the future. Volcanic eruptions, on the other hand, seem to cause a near instantaneous response, reducing the growth rate. The exponential behavior of CO2 is expected considering that both Global Domestic Product and population are increasing exponentially with similar rates of growth. For these components, the exponential relation, dC/dt ~ C, is clearly expected (people and wealth beget more people and wealth). It is likely that exponential growth in CO2 will continue until the close tie to GDP and population is broken through alternate energy sources, CO2 sequestration and regulation.

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Acknowledgements: Thanks to the ESRL/GMD Carbon Cycle Greenhouse Gases group, in particular Ken Masarie and Kirk Thoning for data analysis.