TUBALL Single wall carbon nanotubes USE LESS, DO MORE, PERFORM - - PowerPoint PPT Presentation

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TUBALL Single wall carbon nanotubes USE LESS, DO MORE, PERFORM - - PowerPoint PPT Presentation

Nov 15, 2023 361 likes •722 views

Michael Enotiades SALES MANAGER EMEA OFFICE: +352 2799 0373 MOBILE: +352 661 184 007 michael.enotiades@ocsial.com TUBALL Single wall carbon nanotubes USE LESS, DO MORE, PERFORM BETTER MPG Seminar 15 th May 2017 SINGLE WALL CARBON

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SLIDE 1

TUBALL™

Single wall carbon nanotubes USE LESS, DO MORE, PERFORM BETTER MPG Seminar 15th May 2017

Michael Enotiades SALES MANAGER EMEA OFFICE: +352 2799 0373 MOBILE: +352 661 184 007 michael.enotiades@ocsial.com

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SLIDE 2

Diameter 1.6 nm Length > 5 μm Wall thickness 1 atom

SINGLE WALL CARBON NANOTUBES ARE EXCEPTIONAL

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SWCNT EXCEPTIONAL PROPERTIES

EXCELLENT CONDUCTOR 5 times lighter than copper STRONGER THAN STEEL 100 times THERMAL STABILITY up to 1000 °C THE HIGHEST LENGTH TO DIAMETER RATIO up to 5000 LARGE SURFACE AREA Up to 1300 m2/g 1 G = 5,000,000 KM length of line 1 nanotube thick

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SLIDE 4

CARBON NANOFIBERS Concentration of particles ~0,1% MICROPARTICLES

A B C

0,5 mm 0,5 mm 0,5 mm 1 1 0 1

SWCNT FORMS ITS OWN CONDUCTIVE 3D NETWORK AT ULTRA LOW CONCENTRATIONS

TUBALL™ SINGLE WALL CARBON NANOTUBES

SWCNTs DISPERSION POWER

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SLIDE 5

MATERIAL’S PROPERTIES THRESHOLD OF CHANGE

MWCNT 1 - 6%

SWCNT 0.01 - 0.1%

CARBON FIBERS 3 – 12% CARBON BLACK 10 - 40%

DRASTIC CHANGE OF ELECTRICAL CONDUCTIVITY = 3D NETWORK

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SLIDE 6

TUBALL™ OUTSTANDING QUALITY

TUBALL ™ Environment Health and Safety l OCSiAl November 2016

TUBALLtm CA n° IWTN/COA/W663/001 SPECIFICATIONS VALUE METHOD Total Carbon ~85% W/W TGA Nanotube Purity (T1%) ~74% ± 1.5% TGA Raman G/D Ratio 86.5 ± 7.1 Raman, 633 nm Tube Diameter (approximate average) ~1,5 Nm TEM SPECIFICATIONS VALUE METHOD Carbon content > 85wt.% EDX, TGA CNT content ≥75wt.% TGA, TEM Number of walls CNT 1 TEM Mean diameter CNT 1.6nm ± 0.4 Raman, TEM Length of CNT >5μm AFM TUBALLtm TDS

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SLIDE 7

HISTORICAL CHANGE IN INDUSTRY - BY OCSIAL

HIGH QUALITY SINGLE WALL CNTS PRODUCED LARGE VOLUMES AVAILABLE ACCEPTABLE PRICE FOR INDUSTRY FOR THE FIRST TIME

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SLIDE 8

OCSiAl

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SLIDE 9

ONE OF THE WORLD’S LEADING PHYSICISTS

Corresponding member of Russian Academy

  • f Science, professor. Inventor of the plasma-chemical

reactor and head of the technical division of the project. Completed R&D projects for large international corporations such as: Hewlett Packard, Samsung, Air Products & Chemicals, etc.

MIKHAIL PREDTECHENSKIY

Inventor of OCSiAl Technology. Senior vice-president and Chief Technology Officer, OCSiAl

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SLIDE 10

ABOUT OCSiAl

2009

Founded to develop scalable synthesis of single wall carbon nanotubes (SWCNT)

2013

Awarded patent for scalable SWCNT production Graphetron V1.0 reactor 10 t/y capacity

2014

Began large scale industrial sampling TUBALL™ product

2017

260+ people Product lines: batteries, plastics, composites, coatings, elastomers Graphetron V50 reactor 50 t/y capacity

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SLIDE 11

Novosibirsk

GRAPHETRON 1.0

OCSiAl WORLDWIDE

Columbus Berlin Moscow India Seoul Hong Kong Singapore Palo Alto China

Manufacturing Sales Office Future Manufacturing

Malaysia

OCSiAl is the largest commercial manufacturer of high quality SWCNTs. Our products are made possible by a breakthrough for industrial SWCNT synthesis.

Luxembourg Tel-Aviv

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SLIDE 12

10 T/YEAR  60 T/YEAR

98% OF GLOBAL SWCNT PRODUCTION

OCSiAl PRODUCTION FACILITY GRAPHETRON 1.0 SWCNT REACTOR GRAPHETRON 50 SWCNT REACTOR

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SLIDE 13

TUBALL™ - PRODUCTION PLAN

Production capacity, t/y 50 10 1 800 3 000 1 10 60 800 3000 2015 2016 2017 years 2020 2022

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SLIDE 14

COAT COMP_M INK RUBBER BATT PLAST_M COMP_E

TUBALL™ - PRODUCTS AT INDUSTRIAL SCALE

TUBALL™ IS THE FIRST MASS PRODUCED SWCNT PRODUCT ON THE MARKET − 90% OF GLOBAL PRODUCTION CAPACITY − RANGE OF DEDICATED PRODUCTS

MATRIX

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SLIDE 15

TUBALL™ - REACH REGISTERED

TUBALLTM is REACH-registered for sales up to 10 tons Registration n°01-2120130006-75-0000 TUBALLTM will be REACH-registered for sales up to 100 tons in Q1 2018

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SLIDE 16

TUBALL™ FOR RUBBER

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SLIDE 17

TUBALL™ IMPACT IN RUBBER TENSILE STRENGTH ABRASION COMPRESSION SET HYSTERESIS LOSSES ELECTRICAL CONDUCTIVITY RESISTANCE TO CHEMICALS STABILITY VS AGEING WET GRIP FATIGUE

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SLIDE 18
  • Rubber polymer (NR, SBR, NBR,…)
  • Processing oil

TUBALL™ RUBBER Suspension Suspensions based on: TUBALL™ RUBBER Masterbatch TUBALL™ MATRIX Masterbatches based on:

  • Solvents
  • H2O

HOW TO INTRODUCE?

During polymerisation During compound mixing

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SLIDE 19

TYRE PERFORMANCES

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SLIDE 20

TYRE PERFORMANCE: CURRENT SITUATION

Current technologies: Performance trade-offs

Reference compound

80 85 90 95 100 105 110 115 120 Electrical conductivity Stiffness Abrasion resistance Wet grip Energy efficiency 80 85 90 95 100 105 110 115 120 Electrical conductivity Stiffness Abrasion resistance Wet grip Energy efficiency 80 85 90 95 100 105 110 115 120 Electrical conductivity Stiffness Abrasion resistance Wet grip Energy efficiency

Better Rolling Resistance Higher Wet Grip Higher Abrasion Resistance

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SLIDE 21

TYRE PERFORMANCE: TUBALL™ FIRST RESULTS

Next slide: Results from the 3 first experiments run on Tyre Tread Compounds

  • Addition of TUBALL™ - 0.1 to 0.2% weight
  • No formulation optimization
  • 3 different recipes and formulations – 3 different partners
  • Sample testing in independent laboratories
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SLIDE 22

TIRE PERFORMANCE: NEW SPACE

With TUBALL™ : Strong extension of performance space

Manufacturer recipe #1 0.2% TUBALLTM in compound Manufacturer recipe #2 0.1% TUBALLTM in compound Manufacturer recipe #3 0.1% TUBALLTM in compound

80 85 90 95 100 105 110 115 120 Electrical Conductivity Stiffness Abrasion resistance Wet Grip (TanD 0°C) Energy efficiency (TanD 60°C) 80 85 90 95 100 105 110 115 120 Electrical Conductivity Stiffness Abrasion resistance Wet Grip (TanD 0°C) Energy efficiency (TanD 60°C) 80 85 90 95 100 105 110 115 120 Electrical Conductivity Stiffness Abrasion resistance Wet Grip (TanD 0°C) Energy efficiency (TanD 60°C)

Reference compound

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SLIDE 23

OTHER RUBBER APPLICATIONS

Hoses and Seals for oil and gas industry O-rings, Seals and Gaskets for high temperature and high pressure environments Hoses and Flexible Parts for automotive industry Conveyor Belts for mining, food, electronic industry

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+20%

reduced property loss after rapid gas decompression

+10%

saving properties after heat aging

EXPERIMENTAL RESULTS HNBR RUBBER O-RING COMPOUND

+ 33°C

temperature before degradation of material (thermal resistance )

  • 18%

Compression set

+12%

Shore A Hardness

x 103

Electrical conductivity

+29%

Tensile strength

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SLIDE 25

COMPANY European producer

  • f Industrial and Off the Road Tyres

PRODUCT Truck tyre for mining and earth moving REQUIREMENTS

  • Abrasion resistance 15% higher than existing compounds
  • Rubber running temperature reduced by 10 to 20
  • C

TURNING POINT 0.3% of TUBALL single wall carbon nanotubes added to existing formulation KEY BENEFITS

  • Higher mileage than existing tyres in ssame

category

  • Longer tyre carcass life
  • More robustness versus speed and hot

qweather

Application case TUBALL single wall carbon nanotubes for EARTHMOVER TYRES

COMPANY European producer

  • f Motorcycle Tyres

PRODUCT Original Equipment tyre for electrical 2 wheeled vehicle REQUIREMENTS

  • Resistivity to earth <106 Ohm
  • Weight < 1650g
  • Wear resistance and wet grip 15% better than existing tyre in the same category

TURNING POINT 0.1% of TUBALL single wall carbon nanotubes added to existing formulation KEY BENEFITS

  • Protection of user and electronic ccomponents

against electrostatic discharge

  • Energy saving
  • Higher mileage and better grip than

cconventional tyres in the same category

Application case TUBALL single wall carbon nanotubes for MOTORCYCLE TYRES

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TUBALL™ FOR CONDUCTIVE SILICONE

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SLIDE 27

Gaskets, profiles for electronics Cable elements Adhesive/encapsulant for solar cells High voltage resistor packs

MARKET REQUIREMENTS FOR CONDUCTIVE SILICONE

High consistency silicone (HCR)

10–108 Ω•сm

Liquid silicone rubber (LSR)

101–105 Ω•сm

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SLIDE 28

TUBALL™ MATRIX FOR SILICONES

TUBALL™ MATRIX 601 Carrier: polydimethylsiloxane oil LSR (liquid silicone rubber), and RTV (room temperature vulcanized) silicones TUBALL™ MATRIX 602 Carrier: vinyl-terminated polydimethylsiloxane LSR (liquid silicone rubber), and RTV (room temperature vulcanized) and HCR (high consistency rubber) silicones TUBALL™ MATRIX 605 Carrier: silicone gum HCR (high consistency rubber) silicones

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SLIDE 29

STANDARD COMPOUNDING PROCESS

Same technique as other masterbatch introduction (pigments, etc.)

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TUBALL™ MATRIX 605

HCR ELECTRICAL RESISTANCE 10-1011 Ω•cm*

* Tested in HCR (Shore 60). Measurements conducted according to ASTM D991 standard.

Volume resistivity, Ω∙cm TUBALLTM MATRIX 605 content, wt.%

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SLIDE 31

PHYSICAL PROPERTIES OF HCR (50-60 SHORE) WITH 3% TUBALL™MATRIX 103 -104 Ω•cm

HCR (Base) 50% of Carbon Black based masterbatch Ultimate elongation, % 11 Tensile strength, Mpa 580 Hardness Shore A, pts. 61 0.3% TUBALLTM 5 9 576 150 56 67

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THANK YOU

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OCSiAl ASIA PACIFIC Hong Kong: Suite 1207 100, Queen’s Road Central Hong Kong +852 3180-9388 China: #2004, 20th Floor , Block B, Dachong Business Centre,

  • No. 9678, Shennan Road , Nanshan

District, Shenzhen, Guangdong, China+86 135 9012 5295 china@ocsial.com Korea: 406-840 Republic of Korea, Incheon, Incheon Technopark 12, Gaetbeol-ro, Yeonsu-gu, Pilot Plant Bldg., Office 208. +82 32 260 0407 asiapacific@ocsial.com OCSiAl LLC 500 S Front St, Suite 860, Columbus, OH 43215 +1 415 9065271 640 W California Ave, Suite 210, Sunnyvale, CA 94086 +1 415 906 5271 usa@ocsial.com OCSiAl.ru LLC 107078, Russia, Moscow Kalanchevskaya str., 2 bld. +7 499 653 5152 630090, Russia, Novosibirsk, Inzhenernaya str., 24 +7 383 201 8387 russia@ocsial.com OCSiAl Europe Sarl Luxembourg: 1, rue de la Poudrerie, L-3364, Leudelange Grand Duchy of Luxembourg +352 27990373 europe@ocsial.com

OCSiAl CONTACTS