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Tier II and You Utilizing EPCRA Tier II Reports to Protect Your Community Kansas LEPC Conference July 2018 July 2018 Kansas LEPC Conference 1 Todays Agenda Regulatory Background Tier II Reports Information in Reports


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Kansas LEPC Conference

July 2018

Tier II and You Utilizing EPCRA Tier II Reports to Protect Your Community

July 2018 Kansas LEPC Conference 1

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Today’s Agenda

Kansas LEPC Conference 2 July 2018

  • Regulatory Background
  • Tier II Reports
  • Information in Reports
  • Accessing Reports in Kansas
  • Finding Information on Chemicals
  • Emergency Planning Next Steps
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What is the Emergency Planning and Community Right‐to‐Know Act (EPCRA) of 1986

  • Established local, tribal, and state emergency

planning groups

  • Facilities required to
  • Inform emergency planners what chemicals

are on‐site and facility contacts

  • Immediately report accidental releases
  • Annually inform communities about routine

and accidental chemical releases (EPCRA 313)

  • Also known as the Superfund Amendments and

Reauthorization Act Title III (SARA Title III)

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www.youtube.com/watch? v=Qeo9WBRwF8s ABC West Texas

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What Facilities Submit EPCRA 312 Tier II Inventory Reports

  • Any facility where amount on‐site meets or exceeds
  • EPCRA extremely hazardous substance (EHS) threshold

planning quantity (TPQ)

  • Any other substance where OSHA requires a Safety Data

Sheet (SDS)

  • 10,000 or more pounds

July 2018 Kansas LEPC Conference 4

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EPCRA Tier II Reports

  • Include
  • Facility name
  • Address and GPS coordinates
  • Contact information
  • Amount of hazardous chemicals stored on‐site
  • Potential hazards
  • Locations of hazardous chemicals
  • Submitted to State Emergency Response Commission (KDHE), Local

Emergency Planning Committee, and fire department by March 1

July 2018 Kansas LEPC Conference 5

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Where to Find TPQs List of Lists

  • Includes thresholds for several

regulations

  • EPCRA extremely hazardous

substances TPQs found in Section 302 column

  • TPQs for common extremely hazardous

substances in R7

  • Ammonia (anhydrous) ‐ 500 pounds
  • Chlorine ‐ 100 pounds

www.epa.gov/epcra/consolidated‐list‐lists

July 2018 Kansas LEPC Conference 6

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Kansas Tier II Reports

Kansas LEPC Conference July 2018

Facility Contact Chemical Information Storage Location Facility Info

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Accessing Kansas Tier II Reports

http://kansas.tier2online.com/index.php

July 2018 Kansas LEPC Conference 8

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Four Methods of Searching Kansas Tier II Reports

  • Facility Name
  • Location
  • City
  • County
  • Chemical
  • Business Code
  • Standard Industrial Classification Code (SIC)
  • North American Industry Classification System (NAICS)

July 2018 Kansas LEPC Conference 9

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Searching Kansas Tier II Reports

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Searching Kansas Tier II Reports (cont.)

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Issues with Chemical Names On Kansas Tier II Reports

  • Abbreviations and trade‐names used
  • 2,4‐D LV6

(2,4‐Dichlorophenoxyacetic Acid, 2‐Ethylhexyl Ester)

  • SALVO (2,4‐Dichlorophenoxyacetic

Acid, 2‐Ethylhexyl Ester)

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  • No standardization
  • 7 versions of Anhydrous

Ammonia

  • Anhydrous Ammonia vs

Ammonia Anhydrous

  • Sulfur vs Sulphur
  • Misspellings
  • Example: Anhydrouse

Ammonia

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Issues with Chemical Names On Kansas Tier II Reports (cont.)

  • No chemical abstracts service (CAS) number provided
  • Incorrect chemical reported
  • Chlorine vs sodium hypochlorite
  • Solutions report incorrect strength
  • 37% hydrochloric acid regulated under the Risk Management

Program

  • 36% hydrochloric acid is not

July 2018 Kansas LEPC Conference 13

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Example Kansas Tier II Reports

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Example Kansas Tier II Reports

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Example Kansas Tier II Reports (cont.)

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Example Kansas Tier II Reports (cont.)

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Example Kansas Tier II Reports (cont.)

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Topeka Tier II Facilities

  • 111 Tier II’s for Topeka
  • Simple – Lead/Acid Batteries
  • Complicated – 48 Entries
  • Harmless – Sand
  • Higher potential risks
  • Chlorine used for water

treatment

  • Anhydrous ammonia

used for refrigeration and fertilizer

July 2018 Kansas LEPC Conference 19

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July 2018 Kansas LEPC Conference

Identifying Facilities that Submit Risk Management Plans (RMPs)

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July 2018 Kansas LEPC Conference 21

Green = Agriculture RMP Red = Refrigeration RMP Blue = Chemical Manufacturing RMP White = Water Treatment RMP Yellow= Submitted Tier II Report

Topeka Facilities

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Emergency Planners and Responders Can Request

  • Current copy of Risk Management Plan
  • Off‐site consequence analysis
  • Names and quantities of regulated substances
  • Accidents in past 5 years
  • Emergency contacts
  • Copy of incident investigation reports
  • May include information on near misses
  • Discusses what happened and follow‐up taken
  • Copy of Emergency Response Plan or Emergency Action Plan

These are all Risk Management Program items facilities are required to have

July 2018 Kansas LEPC Conference 22

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Resources for Chemical Information

July 2018 Kansas LEPC Conference 23

  • Safety Data Sheets (SDS)
  • CAMEO / ALOHA / MARPLOT www.epa.gov/cameo
  • WISER wiser.nlm.nih.gov or webwiser.nlm.nih.gov
  • NIOSH www.cdc.gov/niosh/npg
  • ERG www.phmsa.dot.gov/hazmat/erg/emergency‐response‐guidebook‐erg
  • RMP Comp cdxnodengn.epa.gov/cdx‐rmp‐maintain/action/rmp‐comp
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Safety Data Sheets (SDSs)

  • Search reputable company websites
  • Examples: Aldrich, Sigma‐Aldrich, Fisher Chemical, Air Gas, PraxAir*
  • 16 Sections

1: Identification 2: Hazard(s) Identification 3: Composition/Ingredient Information 4: First Aid Measures 5: Firefighting Measures 6: Accidental Release Measures 7: Handling and Storage 8: Exposure Controls/Personal Protection 9: Physical and Chemical Properties 10: Stability and Reactivity 11: Toxicological Information 12: Ecological Information 13: Disposal Considerations 14: Transport Information 15: Regulatory Information 16: Other Information

July 2018 Kansas LEPC Conference 24

*Sample SDS from following slides found at www.praxair.com/‐ /media/documents/sds/ammonia‐nh3‐safety‐data‐sheet‐sds‐p4562.pdf?la=en

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I added for response planning

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Physical and Chemical Properties Continued

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I added for response planning

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CAMEO Software Suite

www.epa.gov/cameo

July 2018 Kansas LEPC Conference 39

  • Computer‐Aided Management of Emergency Operations software
  • Integrates
  • CAMEOfm – Database to manage facility and chemical information
  • CAMEO Chemicals – Extensive chemical database
  • MARPLOT – Mapping application including census information
  • ALOHA – Atmospheric dispersion model used for evaluating

hazardous chemical vapors

  • Download to your computer and mobile devices
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CAMEO Chemicals

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  • Chemical and UN/NA

datasheets

  • Physical and health

hazards

  • Spill response

recommendations

  • As found in Emergency

Response Guidebook cameochemicals.noaa.gov/

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CAMEO Chemicals (cont.)

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WISER

webwiser.nlm.nih.gov

July 2018 Kansas LEPC Conference 42

  • Focuses on

information useful during emergency responses

  • Includes

treatment during exposure

  • Helps identify an

unknown

  • Free to download
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SLIDE 43

NIOSH Pocket Guide

  • Concise
  • Essential physical and chemical

properties

  • Exposure levels
  • Incompatibilities
  • Lots of abbreviations
  • Not explicit in actions to be taken

Website: www.cdc.gov/niosh/npg/search.html Mobile ap: www.cdc.gov/niosh/npg/mobilepocketguide.html

July 2018 Kansas LEPC Conference 43

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Emergency Response Guide

  • Initial actions to be taken by

first responders

  • Used for the first 30 minutes of

response or until more advanced help arrives

  • Easy to use

www.phmsa.dot.gov/sites/phmsa.dot.gov/files/docs/ERG2016.pdf

July 2018 Kansas LEPC Conference 45

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Orange Colored Guide Pages

  • Potential hazards
  • Health, fire, explosion
  • Public safety measures
  • Secure, isolate, notify (SIN)
  • Protective clothing
  • Evacuation distances
  • Emergency response
  • Fire extinguishing agents
  • Spill or leak control measures
  • First aid

July 2018 Kansas LEPC Conference 48

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Game to practice ERG skills: hazmatsolutions.net/2016‐erg‐game/ You tube video: www.youtube.com/watch?v=WCpr4Xmhrss PHMSA Website: www.phmsa.dot.gov/hazmat/erg/erg2016‐english

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RMP Comp and MARPLOT

www.epa.gov/rmp/rmpcomp

Kansas LEPC Conference July 2018

Determine area potentially impacted by a chemical release Use MARPLOT to map and view census data

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Websites with Chemical Incompatibility Information

  • www.epa.gov/sites/production/files/2016‐03/documents/compat‐

haz‐waste.pdf

  • ehs.princeton.edu/sites/ehs/files/Chemical%20Incompatibility%20C

hart.pdf

  • pub.extranet.fsu.edu/sites/safety/safetywiki/Wiki%20Pages/Incomp

atible%20Chemical%20Storage%20Chart.aspx

  • rms.unlv.edu/environmental‐and‐lab/labinspect/IncChem.pdf

July 2018 Kansas LEPC Conference 52

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Chemical Incompatibilities (cont.)

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(From Manufacturing Chemists' Association, Guide for Safety in the Chemical Laboratory, pp. 215–217, Van Nostrand )

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Chemical Incompatibilities (cont.)

July 2018 Kansas LEPC Conference 54

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  • Facility produces: Distilled

spirits, specialty wheat proteins, starches

  • October 21, 2016
  • 4,000 gallons sulfuric

acid incorrected loaded into tank with 6,000 gallons of bleach

  • Large cloud of chlorine

released into the air

Incompatible Chemicals Mixing Leads to Accidents MGPI in Atchison, Kansas

July 2018 Kansas LEPC Conference 55

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Sodium Hypochlorite Sulfuric Acid Reaction Results

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July 2018 Kansas LEPC Conference 58

Chemical Safety Board Investigation

  • Video: www.youtube.com/watch?v=Tflm9mttAAI
  • Report and Pictures: www.csb.gov/mgpi‐processing‐inc‐toxic‐

chemical‐release‐/ Facilities may accidentally release chemicals not found on Tier II Reports

  • Chemicals stored below threshold
  • Unintended mixing forming a new chemical

Take time to download WISER free at wiser.nlm.nih.gov/register.html

MGPI Lessons Learned

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SLIDE 59

What You Can Do With This Information?

  • Talk with Tier II Facilities
  • Request site visits
  • Request copy of emergency action or report plan
  • Ask facility to join the Local Emergency Planning Committee
  • Share information with emergency management/fire/hazmat
  • Put information in community plan

July 2018 Kansas LEPC Conference 59

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SLIDE 60

Who To Call With Questions on Chemicals?

  • Local college chemistry department
  • Consultant
  • Kansas Department of Health and Environment
  • EPA (Your Presenters)
  • Dr. Steve Greenwald; 913‐551‐7408, greenwald.steven@epa.gov
  • Doug Ferguson; 913‐551‐7221, ferguson.doug@epa.gov

Questions?

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