Research @ Elettra - Sincrotrone Trieste Elett ettra ra Labora - - PowerPoint PPT Presentation

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015

Research @ Elettra - Sincrotrone Trieste

Elett ettra ra Labora rato tory ry Mission: n: Using ng Sync nchrotron hrotron and d FEL L radiat diation ion to

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duct t experi riments ments con

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sidered red impossi ssibl ble a decade cade ago

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ELETT ELETTRA RA

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015

Multid idisci ciplin plinary ary intern rnational ational labor

• ratory

atory of excelle llence ce, special cialized ized in synchro rotro tron and free-electron electron laser er radi diatio ations ns and their ir appl plicati ication

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Elettra-Sincrotrone Trieste: http://www.elettra.eu

Alf lfons

• nso
• Franc

ancios iosi President and Chief Executive Officer

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015

Solaris Synchrotron – Krakow (PL) to be operated 550-1.5 GeV

Elettra:

• Provides consulting in design,

installation, test and commissioning tasks;

• Design, manufacturing, and delivery with

installation and site acceptance test of the complete UARPES Beamline € 3.070.000 (to be completed by April-May 2015);

• Training scientists.

Elettra involved in:

• Producing 4 improved RF cavities ~

1.4 mln

• Train SESAME personnel

Industrial Liaison Office (ILO):

activities using the skills and know-how of the beamline and machine scientists who are consulting ILO and also execute service when requested

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015

High quality insertion device for light sources:

http://www.kyma-undulators.eu Fabrication of insertion devices for light sources combining more than twenty years experience in design, assembling, characterization and

• peration of insertion devices at Elettra- Sincrotrone Trieste and Fermi, with

the manufacturing capabilities of the industrial partners and shareholders.

Scientific backup by Elettra Sincrotrone Trieste

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015

Kyma and Cornell University are cooperating under an exclusive license agreement for the design, realization and commercialization of low cost high-performance compact undulators, based on new concepts

Fixed-gap, variable-phase, compact LPUs

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015

ELETTRA Storage Ring

Operating at 2.0 and 2.4 GeV 23 operating BLs, 2 under commissioning

October 6, 2014: INAUGURATION IAEA-Elettra XRF beamline

Nature 520, 205 (2015), DOI:10.1038/nature14341

Transient gratings, generated by the interference of coherent extreme-ultraviolet pulses delivered by the FERMI free-electron laser

n = c/l

% coherent polarised tunable

Fermi -FEL

3 operating beamlines, 3 under construction

FEL1: 20–70 nm FEL2: 4-20 nm

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015 User support lab

Workshop and sample preparation tools incl. chemical laboratory.

MUST

Micro and Nano Carbon Lab:

• ff-line laboratory for samples

preparation and analysis focused on C materials and sensor related research,

NanoInnovation Laboratory

Atomic Force Microscopy for complementary studies in support of all beamlines.

Tomolab

Complementary to the SYRMEP beamline setup for micro-CT with microfocus lab source

Powder Diffraction

Support laboratory for MCX, XRD and XAFS beamlines

Collaboration with University Trieste for training students in Synchrotron environment.

Complementary research to PES and XAS beamlines (SuperESCA, NanoSpec, VUV etc)

Structural Biology lab

Molecular and structural biology tools to complement research using SAXS and XRD beamlines.

Scientific Computing

Beamline Controls, Data acquisition, management and processing MUST

Laboratories backing the scientific and training activity of the Elettra and Fermi beamlines

CITIUS and T-ReX Laser labs complementing Fermi and slicing source experiments.

CITIUS is located in the near-by University of Nova Goriza in Slovenija

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015

Beamtime at ELETTRA and FERMI@Elettra: via

proposals judged for scientific merits by independent PRPs

443 got beamtime Average overbooking ≈ 2 – some beamlines > 3!

Italy 39%

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015

BL 10. 1 X Ray Fluorescence beamline

The XRF beamline can host two stations. The first is the IAEA multi-purposes station (UHVC-PTB Berlin) combining different XRF techniques: total reflection XRF, grazing incidence XRF, XANES.

Partly operational for users in 2015 with 40% beamtime for IAEA users and training activities.

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015 Zn distribution and speciation Air Particulate Matter collected in Bangladesh

(420- 400 b.C.)

Black Glaze Fe-based decorations of Ancient ceramics: pre-edge XANES

• P. Romano et al, INFN, Catania

First results obtained by users at BL 10. 1 X Ray Fluorescence

Localization and speciation of Hg in edible mushrooms

• K. Vogel-Mikuš et al, Uni Ljubliana, Slo

These first results were obtained in the frame IAEA Coordinated Research Project (CRP) program for scientists from associated countries and during the first training course for Asia-Pacific Countries in November 2014.

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015

The quality of a new class of ultraporous luminescent materials probed with (SAXS): the diffraction results confirm the crystalline order of the framework matrix surrounding the QDs. Characterization crystal structure (GIXRD) and morphology (GISAXS and XRR) of the magnetron sputtered W films as a function of Ar pressure and sputter power

Structural Characterization of MOF-5 crystals allowing for dynamic positioning in a magnetic field

Austrian SAXS beamline: one of the most

productive beamlines

Metal organic frameworks (MOF) - very promising ultra-porous materials for a variety of applications, such as sensing, detecting, gas storage and separation catalysis and drug delivery.

New Detector and upgrade program ongoing .

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015

SYRMEP

Mammography with Synchrotron Radiation: First Clinical Experience with Phase-Detection Technique,

• Radiology. 2011 Jun;259(3):684-94

Bones Ba

Sample: acute asthma mouse treated with macrophages labeled with Ba

asthmatic mouse Healthy Ba treated Healthy untreated

Application of Phase Retrieval

Reducing noise and artefacts around the tissue edges; Enhancing the phases separation; Lungs imaging @ SYRMEP complements optical fluorescence microscopy visualizing Ba- labeled macrophages trafficking to inflammation sites Since December 2014 under discussion new project with in the field of Tomography and XRF using white light as well. Ongoing ERIC project application for bio-imaging (Mancini-Tromba)

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015

FZJ, Peter Grünberg Institute– Prof. C. Schneider Max-Planck-Institut für Mikrostrukturphysik, Halle – Prof. J. Kirschner

• aberration corrected energy filter;
• spin filtering by reflection at

W(100) mirror

• C. Tusche et al., Ultramicroscopy

130, 70 (2013)

Adding spin filtered momentum detection in XPEEM microscope @ NanoESCA

Photon energy 50 eV

spin integrated intensity Spin polarization map

Spin resolved Fermi surface of Co (10ML Co/Cu(100)

The set-up allows for mapping the intensity distribution of the photoelectrons emitted into the complete solid angle as a function of the momentum component parallel to the surface, within a single image acquisition and spin resolution. Upgrade to energy resolution < 50 meV.

To be open for users second semester of 2015.

• C. Tusche et al. Ultramicroscopy 130, 70-76 (2013)

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015

Users’ docking ports Load-lock Sample preparation

MO Kerr effect; LEED/Auger Sample growth and prep.

STM APE-LE APE-HE Distribution center

Variable polarization photons 8-120 eV Variable polarization photons 150-1600 eV

APE beamline: combining sample fabrication and

characterization with conventional and synchrotron-based methods

VG-Scienta DA30 Omicron EA125

Fe(100) Fermi surface S segregation

• n Fe(100)
• Growth facilities (oxide MBE + new preparation chamber);
• In-operando XAS/XMCD/XLMD/XPS;
• Integration of spin-polarization measurements with ARPES;
• Ultrafast spectroscopy;
• Information management and data repository;

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015

Publications 2014: increasing trend in number and % with high impact factor publications

2014 2013 2012

2014: 47% IF > 7

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015

APE Beamline: Electrical and reversible on/off switching of

the interfacial FeOx magnetization in the Fe/BTO heterostructure

By performing XMCD experiment while applying an electric bias it was possible to discover a ferromagnetic-antiferromagnetic phase transition in the Fe oxide layer at the Fe/BTO interface as a function of the BTO electrical state.

The yellow stripe indicates the energy region, corresponding to the Fe oxide where XMCD changes (dichroic effect) can be supp a function of the BTO electrical poling.

5, 3404 (2014)

• G. Radaelli et al.

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015

XAFS: one of the most requested and prodictive

beamlines

Ru4-polyoxometalate: evidence for unique Ru oxide species catalysing solar to fuel energy conversion .

The electrochemical Na extraction/insertion mechanism together with the V oxidation state has been determined in

• perando using XAS

XANES identified two phases in the biomineralization process.

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015

TwinMic beamline at short undulator: asbestos in lung tissue:

fibre core @ shell of complex content result of tissue reaction Synchrotron soft X-ray imaging and fluorescence microscopy combined with Fe m-XANES at ESRF reveal novel features of asbestos body morphology and composition in human lung tissues

• L. Pascolo et al, Particle and Fibre

Toxicology, 6-7, 2011: Scietific Reports, 2013. The evidenced Mg participation in tissue reaction has opened a route to further in-depth investigations on the molecular mechanism of asbestos toxicity considering important role of Mg in many cell and tissue mechanisms, particularly oxidative stress defence and inflammatory conditions.

Relevant also to CNT - similar effects!

• What is the effect on the organic matter content

– proteins, lipids, polysahharides - IRSM.

Lipids – CH stretching Proteins– Amide I area Protein NH stretching

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015

Bio-matter and synchrotron radiation

Refraction and absorption properties of soft X-rays provide distinct advantages for ‘fast’ imaging of matter consisting of light elements, as biological samples, with sensitivity better than conventional light microscopy. Lipid droplets and NPs clearly seen

• A. Gianoncelli, Lisa Vaccari et al, Soft X-Ray Microscopy Radiation Damage On Fixed Cells Investigated With Synchrotron

Radiation FTIR Microscopy, Accepted in Scietific Reports

Radiation Damage with increasing exposure to X-rays

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015

Dissemination of SR and FEL-based science generated @ Elettra beamlines 2014 2013

The First Focus Topic on "Novel Trends in Synchrotron and FEL-Based Analysis” in the frame of AVS’61, Baltimore in November 2014 (MK Chair) Results obtained at Elettra lab were reported by five invited speakers:

(B. Bozzini (Uni Lecce), A. Goldoni (Elettra), A. Kolmakov (NIST-USA), P. Rudolf (Uni Gronningen) and C. Schneider (FZJ)

19-21/05, 2014 | Melbourne, Photon and Neutron Applications to the Study of Biological and Nanoscale Systems

Trieste: 22-26/06, 2014, International Workshop on Radiation Imaging Detectors

Trieste-ICTP, International Workshop on Advances in X-ray Imaging

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015

7 out 30 Chapters are Authored or co- authoted by Elettra scientists

16 Beamline scientist were

• rganizers and lectureres @

Specialized Schools (Two ICTP/IAEA

schools, HERCULES-Grenoble, SAXS / SANS data analysis, Melbourne Dissemination of SR and FEL-based methodology and science In 2014 14 staff scientists were teaching University and PhD courses in Trieste University and other Universities in Italy, Austria and Australia.

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7th ILSF Users’ Meeting, Tehran 20-21 April 2015

Conclusive remarks

 Elettra had its 21st Birthday October 2014 – in these 20 years Elettra has been vital and efficient and has attracted user communities in natural, material and life sciences.  Elettra has world-class beamline scientists that have been the driving force to make Elettra an attractive research and training center. For remaining competitive and respond the growing science and technology demands Elettra needs more revolutionary upgrades

• f the existing beamlines and experimental stations, replacing

some and biulding new beamlines. Ongoing upgrades at SAXS and APE. Under consideration APPES, pink beam tomography, another XAFS, micro-XRF, RIXS. Long-term vision: Elettra-2 conceptual design project started. The new machine lattice most probably 6 M-Bend Achromats structure, reducing the present emittance about 30 times.