Open new market opportunities with BioPBS TM /PLA InnoBioPlast 2016 - - PowerPoint PPT Presentation

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Open new market opportunities with BioPBS TM /PLA InnoBioPlast 2016 - - PowerPoint PPT Presentation

Oct 29, 2023 36 likes •417 views

Open new market opportunities with BioPBS TM /PLA InnoBioPlast 2016 September 15, 2016 Agenda Introduction to BioPBS TM BioPBS TM /PLA compound Takeaway Points Acknowledgement More People, More Plastics We produce more

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SLIDE 1

Open new market opportunities with BioPBSTM/PLA

InnoBioPlast 2016 September 15, 2016

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SLIDE 2

Agenda

  • Introduction to BioPBSTM
  • BioPBSTM/PLA compound
  • Takeaway Points
  • Acknowledgement
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SLIDE 3

More People, More Plastics

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SLIDE 4

We produce more waste, and most of it isn’t disposed in the most environmentally-friendly method.

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SLIDE 5

Bio-based Petro-based Biodegradable Non-biodegradable

PLA BioPBS PHA PBAT, PCL Bio-PE Bio-PP Bio-PA PTT Conventional Plastics: PE, PP, PS, PET, ABS, PC, PMMA, Nylon, etc. Starch blends with PE

Bioplastics

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SLIDE 6

Who are we?

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SLIDE 7
  • Renewable content
  • Continuous process
  • More efficient purification
  • Higher drying capability
  • More uniform products
  • Very low moisture
  • Very low impurity
  • Longer shelf-life
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SLIDE 8

Introduction to BioPBS

Bio-Succinic Acid 1,4-butanediol Polybutylene Succinate, PBS

O O O O

m n p

X

Petro-Succinic Acid 1,4-butanediol Polybutylene Succinate, PBS

O O O O

m n p

X

produced by batch process in Japan produced by continuous process in Thailand

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SLIDE 9

Note: These values are typical and not to be construed as specifications.

Properties Unit FZ71 FZ91 FD92 Melt Flow Rate (190ºC/2.16kgf) g/10min 22 5 4 Density g/cm3 1.26 1.26 1.24 Glass Transition Temperature ºC

  • 33
  • 33
  • 47

Melting Point ºC 115 115 84 Yield Stress MPa 40 40 17 Tensile Strength at Break MPa 30 36 24 Tensile Strain at Break % 170 210 380 Flexural Modulus MPa 630 650 250 Flexural Strength MPa 40 40 18 Izod Impact Strength (23ºC) kJ/m2 7 10 47 Heat Deflection Temperature (0.45 MPa) ºC 95 95 63 Vicat Softening Point ºC 109 109 75 Rockwell Hardness (R-scale) kJ/mm 107 107 56

Injection Molding Properties

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SLIDE 10

Note: These values are typical and not to be construed as specifications.

Film Properties

Properties Unit FZ91 (20 µm) FD92 (20 µm) Melt Flow Rate (190ºC/2.16kgf) g/10min 5 4 Density g/cm3 1.26 1.24 Tensile Modulus MD MPa 575 280 TD MPa 590 320 Yield Stress MD MPa 39 18 TD MPa 38 17 Stress at break MD MPa 42 32 TD MPa 30 27 Strain at break MD % 350 600 TD % 180 580 Elmendorf Tear Strength MD N/mm 2 2 TD N/mm 4 5 WVTR 20 / 50 µm g/m2•d 510 / 210 1,050 / 510 OTR 20 / 50 µm cm3/m2•d•bar 490 / 140 2,040 / 760 Puncture Impact Strength kJ/mm 4 6 Haze (25 µm) 45 22

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SLIDE 11

CEDAR GROVE

Certified Compostable

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SLIDE 12

10 20 30 40 50 60 70 80 90 100 100 200 300 400 500 600 700 % biodegradation Days Cellulose BioPBS FZ71PB BioPBS FZ91PB BioPBS FD92PB

Biodegradation in SOIL

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SLIDE 13

Excellent heat seal strength even at low temp.

Heat Seal Condition:

  • Pressure 0.2 MPa
  • Time 1 sec
  • Seal width 5 mm

Strength Measurement Condition:

  • Specimen:

Film 15 mm width with 20µm thickness

  • Chuck Interval:

60 mm

  • Test Speed:

300 mm/min

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SLIDE 14

BioPBS Heat Seal Property

Paper Film 1 2 3 4 5 6 7 8 9 10 100 120 140 160 180 Heat seal strength（N/15mm） Heat seal temperature (deg.C) GS Pla LDPE LDPE+corona PBS

* MFR 8.2 g/10min Density 0.919 g/cm3

  • Coating conditions :

Structure: Kraft/resin (20 μm) Processing temperature: PBS 270ºC LDPE* 320ºC Corona treatment

  • Heat seal conditions :

Seal surface: Resin/paper Seal bar width : 5 mm Pressure / time : 0.2 MPa/1.0sec

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SLIDE 15

Complies with EU directives 10/2011

  • All raw materials
  • n positive list
  • Migration test

passed OM-6 (100C, 4 hours) FCN No. 1574 and 1643

  • FZ-grade: Condition of Use B-H
  • FD-grade: Condition of Use C-G
  • All food types except alcoholic

foods Listed in JHOSPA Positive List

Food Contact Safety

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SLIDE 16

 Excellent process as fast as LDPE  Stable and narrow neck-in  Excellent adhesion and seal strength  Compostable at room temperature  Recyclable in paper mill

BioPBS for Paper Coating

Source: MCC’s internal laboratory

BioPBS BioPBS BioPBS

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SLIDE 17

BioPBS as Sealing Layer

in Flexible Packaging

 Excellent process in existing LDPE extrusion coating machine  Excellent seal strength

seal strength

 Compostable without composting facility  Excellent printability without pre-treatment  Good to retai

retain aroma aroma such as limonene

 Suitable for food packaging

Cellulose Cellulose Metallized Metallized Cellulose Cellulose BioPB BioPBSTM

TM

Example of a Example of a film film structure structure Utilizing BioPB Utilizing BioPBS as a sealing layer as a sealing layer

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SLIDE 18

Agenda

  • PTTMCC and BioPBSTM
  • BioPBSTM/PLA Compound
  • Take Away Points
  • Acknowledgement
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SLIDE 19

Properties comparison of BioPBS vs PLA

* in soil at 30C (86F), 50%RH

Flexibility Flexibility Process temp. Process temp. Heat resistance Heat resistance Biodegradability* Biodegradability*

Flexible Flexible Rigid Rigid Lower Lower Higher Higher Translucent Translucent Higher Higher Lower Lower Transparent Transparent

Transparency Transparency

Faster Faster Slower Slower

Impact strength Impact strength

Higher Higher Lower Lower

Heat-seal temp. Heat-seal temp.

Lower Lower Higher Higher

BioPBS PLA

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SLIDE 20

Potential of PBS/PLA Compound

BioPBS

PBS Compound Potential PBS-PLA Compound

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SLIDE 21

Compatible to PLA

PBS / PLA 75 / 25 50 / 50 25 / 75

1μm

Compound resin of PBS with PLA showed good dispersion

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SLIDE 22

Improve thermal stability

50 100 150 200 250 300 350 400 450

10 20 40 60 80 100

%BioPBS FZ71 %crystallinity HDT Degradation Temperature

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SLIDE 23

BioPBS can improve service temperature

PLA 0% PLA 30% PLA 60% PLA ７５% PLA 90% PLA 100%

60ºC for 1 hour 70ºC for 1 hour 80ºC for 1 hour

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SLIDE 24

Tensile Properties

500 1000 1500 2000 2500 3000 3500 50 100 150 200 250 300 10 20 40 60 80 100 Tensile Modulus, MPa Tensile Strength, MPa Elongation, % %BioPBS FZ71 Tensile Strength Elongation Tensile Modulus

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SLIDE 25

Flexural Properties

20 40 60 80 100 120 500 1000 1500 2000 2500 3000 3500 4000 10 20 40 60 80 100 Yield Stress, MPa Flexural Modulus, MPa %BioPBS FZ71 Flexural Modulus Yield Stress

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SLIDE 26

Izod Impact Strength

5 10 15 20 25 10 20 40 60 80 100 Izod Impact Strength, ft·lb/ft %BioPBS FZ71 Notched

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SLIDE 27

Opportunities are endless

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SLIDE 28

How can you use BioPBS?

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SLIDE 29

Takeaway Points

  • Properties alike LDPE plus biodegradable at ambient
  • Food contact safety in USA and EU
  • Improve flexibility, impact, and thermal properties of PLA
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SLIDE 30

Acknowledgement

PTT Research Institute of Technology

  • Dr. Narin Kaabbuathong and his team
  • Dr. Jirawut Junkasem

Mitsubishi Chemical Corporation

  • Dr. Uyeda Tadashi
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SLIDE 31
  • Mr. Chinnawat Srirojpinyo

Marketing Technical Service Manager

+66-9-2260-7226 Email: chinnawat.s@pttmcc.com

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SLIDE 32

Test Condition

Material: PLA Ingeo 4032D PBS BioPBS FZ71PM Sample Preparation:

  • 1. Compounded by twin-screw extruder at 320°F
  • 2. Injected specimen at 375°F
  • 3. Conditioned at 73.4±3.6°F, 50±5%RH for 40 hours before evaluation
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SLIDE 33

Bio-based Certificates

Certificates FZ71 FZ91 FD92

Din Certco 50-85% (51%) 50-85% (51%) 20-50% (35%) BiomassPla 48.5% 48.5% 33.5%

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SLIDE 34

Compostable Certificates

Certificates Standard FZ71 FZ91 FD92 BPI (USA) ASTM D6400 74µm 68µm On process (Q2/2016) OK Compost (EU) EN13432 74µm 69µm 87µm OK Compost HOME (EU) EN13432 at 28±2°C

  • 85µm

OK Biodegradable Soil (EU) EN13432 at 25°C 2-year test Up to Feb 2018 2-year test Up to Feb 2018 2-year test Up to Feb 2018 GreenPla (JBPA) JBPA On process (Q3/2016) On process (Q3/2016) On process (Q3/2016) ABA (Australia) AS 4736 On process (Q3/2016) On process (Q3/2016) On process (Q3/2016)

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SLIDE 35

EU 10/2011

BioPBS FZ-grade (PBS) 50µm: OM-6 condition, simulant A, B, D1, D2 BioPBS FD-grade (PBSA) 50µm: OM-3 condition, simulant A, B, D1, D2  Raw materials including chain extenders are in positive list  Overall migration limit < 10 mg/dm

2

 Specific migration limit are met

  • 1,4-BDO < 5 mg/kg SML(T)

Grade Condition 1,4-BDO FZ71PM 50 µm OM-6 <0.1 - 0.2 mg/kg FZ91PM 50 µm OM-6 <0.1 mg/kg FD92PM 50 µm OM-3 <0.1 - 0.2 mg/kg

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SLIDE 36

MFR 190°C, 2.16 kgf

5 10 15 20 25 20 40 60 80 100 MFR, g/10min %BioPBS FZ71 in PLA

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SLIDE 37

Viscosity 190°C

10 100 1,000 10,000 10 100 1,000 10,000 Viscosity, Pa-s Shear Rate, s-1

0:100 10:90 20:80 40:60 60:40 80:20 100:0

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SLIDE 38

Summary

FZ71PM Ingeo 4032D MFR Crystallinity HDT Thermal Degradation Temperature g/10min Tc, °C % °C °C 100 3.2

  • 52.2

360 10 90 3.8

  • 52.2

360 20 80 4.2

  • 50.8

360 40 60 7.1 81.2 50.3 52.0 360 60 40 10.9 80.7 53.4 55.6 395 80 20 14.4 82.1 59.7 81.0 400 100 21.4 64.7 55.5 93.3 401 FZ71PM Ingeo 4032D Tensile Flexural Izod Impact Modulus, MPa Strength, MPa Elongation, % Modulus, MPa Stress, MPa Notched, ft•lb/ft 100 2,860 75 4 3,610 110 8.7 10 90 2,390 62 8 2,970 85 9.2 20 80 2,240 58 13 2,880 80 10.3 40 60 1,890 50 42 2,710 80 17.1 60 40 1,280 38 66 1,510 60 23.1 80 20 900 39 41 1,010 50 20.0 100 660 40 16 690 40 23.8