SERDP & ESTCP Webinar Series
New Tools for Improving the Management of Contaminated Sediment Sites
- Dr. Philip Gschwend, MIT
- Dr. Bart Chadwick, SPAWAR Systems Center Pacific
New Tools for Improving the Management of Contaminated Sediment - - PowerPoint PPT Presentation
SERDP & ESTCP Webinar Series New Tools for Improving the Management of Contaminated Sediment Sites Dr. Philip Gschwend, MIT Dr. Bart Chadwick, SPAWAR Systems Center Pacific SERDP & ESTCP Webinar Series Welcome and Introductions Rula
(5 minutes)
(5 minutes)
(30 minutes + Q&A)
Contaminated Sediment Sites
Center Pacific (30 minutes + Q&A)
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Small reaction vessels Columns, microcosms Tanks, large reactors Test cells, controlled field sites Field sites
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DATE WEBINARS AND PRESENTERS December 4, 2014 The Roles Efficient Tar Management and Rotary Kiln Gasification for Base Camps as Options for Waste to Energy
Engineering Center
Center, Construction Engineering Research Laboratory) December 18, 2014 Energy Audits: From Clipboard to Cloud
January 8, 2015 DNAPL Source Zone Management
January 22, 2015 Sustainable Materials
Systems Directorate)
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ESTCP Project Number: ER-0915 Phil Gschwend, Massachusetts Institute of Technology
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Cl Cl Cl Cl
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1 10 100 1,000 10,000 1996 1998 2000 2002 2004 2006 2008
Concentration (ug/kg) Year
Lauritzen Channel mussels
DDT Dieldrin
(Tamara Frank, E2 Consulting Engineers)
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Hawthorne et al., 2007
~1% PAH saturation in lipids
Expected to be toxic!!! 20
e.g., Mya arenaria (soft-shelled clam) OC sorbs and Black Carbon sorbs decrease fraction dissolved in pore water?
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Bioaccumulation predictions more accurate with OC and BC!
w/ Cwater = Csed/(focKoc)
w/ Cwater = Csed/(focKoc + fBCKBCCw
n-1)
0.001 0.01 0.1 1 10 100 DB, OC-rich sed DB, OC-poor sed SR
0.001 0.01 0.1 1 10 100
a biota (lip, prot) / a sed(OC, BC) Phen Pyr BaA BaP
DB, OC-rich sed DB, OC-poor sed SR
divided by predicted in clam 22
pollutants natural
matter black carbon porewater
Accumulate contaminants proportional to porewater concentrations
PE strips Metal Frame 25 cm
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PRCs Add surrogate stds & extract with DCM Choose (Mpe/Vwater)*Kpe-water > 20 CH2Cl2 CH3OH H2O Mount in frame and deploy from boat After 1 to 3 months, recover Clean exterior Evaporate solvent , add injection stds, run GCMS. No extract clean up!
LDPE cleaned loaded w/ stds mounted deployed GCMS extracted recovered 24
0% 20% 40% 60% 80% 100%
100 150 30 60 90 120 PRC Remaining (%)
PE Concentration (ng/g PE)
Time (days)
PCB 101
Target Corrected Target 0% 20% 40% 60% 80% 100%
20 30 40 30 60 90 120 PRC Remaining (%)
PE Concentration (ng/g PE)
Time (days)
PCB 52
Target Corrected Target
PE / Kpe-w = Cporewater
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Chemical activity measured in porewater (ppm)
Chemical activity measured in PE (ppm)
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1 2 3 4 5 6
water conc at equilib (ng/L)
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Activity in porewater (0-4 cm depth) (ppm) Activity in clams (ppm)
Pyrene
activity in porewater = Cporewater /Cwater
sat = (CPE / KPE-water )/ Cwater sat
activity in clam = (Clipid/flipidKlipid water)/Cwater
sat
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○ Main source = diffusion from bed
○ Passive samplers for biomonitors (mussels)
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H2O 0–5cm (ng/L) SED 0–5cm (ng/L)
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1.00 10.00 100.00 1000.00 10000.00 100000.00 200 400 600 800 1000 1200 1400 1600 1800 2000
Fluxes (ng /m2 / day)
Position in harbor
Bed-to-water fluxes
4,4-DDD 4,4’-DDE 4,4’-DDT Log scale! 31
Flux (ng/m2/day) = Dwater (m2/day)* (Cpore water – Cbottom water) (ng/m3) _______________________________________ boundary layer thickness (m)
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Too high Too low Need mid-channel input! 34
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PCB #52 in finfish & shellfish living near PCB-contaminated lake sediments Medium Conc’s Water non-detect Perch 16 μg/kg Bass 3 μg/kg Mussels 7 μg/kg Sediment 23 μg/kg
Can do better with passive sampler data! 36
PCB #52 BEFORE AFTER w/ PE SAMPLING
Conc’s eval’ using “equil’d water conc” Water no detect
10 pg/L (via LDPE) w/ Cbiota/flipKlipw
Perch 16 ug/kg
9 pg/L
Bass 2.5 ug/kg
60 pg/L
Mussels 7.2 ug/kg
30 pg/L
Sediment 23 ug/kg
w/ Kd = focKoc 5000 pg/Lporewater via LDPE 400 pg/Lporewater
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averages 20x higher than Cpe / Kpe-w
previously sampled!
Sediment Data vs PE data (ex situ) (Csed/focKoc) (Csed basis) (CPE/KPEw)
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CPE/Kpe-water Csediment/focKoc
Porewater Concentration (ng/L)
Analysis of isolated pore water
Csediment/focKoc CPE/Kpe-water
Analysis of isolated pore water Lower CPE/Kpew for in situ than ex situ
=> Suspect Flushing 39
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Cclam = (flipKlip-w) Cporewater with Cporewater from Csediment/focKoc
Ratios Measure in clam Divided by Predicted in clam Sampling stations
Lohmann et al., 2004
0.001 0.01 0.1 1 10 100 DB, OC-rich sed DB, OC-poor sed SR
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5 10 0.0 20.0 40.0 60.0 80.0
Depth (cm) PCB ng/gPE
PCB Depth Profile, Site 11
d19-52 d38-101 d54-153 d72-180
0.0 0.0 20.0 40.0 60.0 80.0
Relative Depth (cm) PCB ng/gPE
( ) PCB Depth Profile, Site 12
0.0 0.0 20.0 40.0 60.0 80.0
Relative Depth (cm) PCB ng/gPE
( ) PCB Depth Profile, Site 15
0.0 0.0 10.0 20.0 30.0 40.0 50.0
Relative Depth (cm) PCB ng/gPE
( ) PCB Depth Profile, Site 17
Subsurface max ~40 ng/g at 15 cm
Weak subsurface max
~40 ng/g at 25 cm ?max ~60 ng/g at ≥ 30 cm
Strong subsurface max of #52 at 30 cm
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Bottom water in cap Below cap Bottom water in cap Below cap Bottom water in cap Below cap
PE Passive Sampling for Assessing Contaminated Sediments 47
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g (SCCWRP & Navy, 2005)
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and analysis
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http://oceanexplorer.noaa.gov SERDP & ESTCP Webinar Series (#3)
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http://tisiri.org http://www.real-project.eu
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From Koomans, 2000
material
where R is the particle radius and L is the length of the groove
(Koomans, 2000)
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Software Interface
10 cm
Delrin Isolator Friction Sound Sensor Probe Physical Interface Sound Cable to Electronics Probe Interface Electronics Interface SERDP & ESTCP Webinar Series (#3)
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Pneumatic Drive Cylinder Landing Frame Isolation Bobbins Reaction Weight Canisters Collapsible Frame Control System
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10 20 30
0.0 1.0 2.0 3.0
Filtered RMS Friction Sound (rel) Sample Depth (cm)
Clay
10 20 30
100 200 300 400 500
Filtered RMS Friction Sound (rel) Sample Depth (cm)
Fine Sand
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y = 1.23x R2 = 0.99 200 400 600 800 1000 1200 1400 200 400 600 800 1000 1200
Sediment Size (µm, mid-range) Filtered RMS Sound Intensity (rel)
Vertical error bars are 1 SD of replicates Horizontal error bars are sieve range for standard
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10 20 30
100 200 300 400 500 600 700 800
SED-FSP Calibrated Mean Particle Size (um) Depth (cm)
Nominal SED-FSP
Very Fine Sand Medium Sand SERDP & ESTCP Webinar Series (#3)
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urban creek in San Diego Bay
and PAHs
distribution – physical effects
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creasing metal concentratio (SCCWRP & Navy, 2005).
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across site
calibration
historical (2001) data
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Outer Creek (fine grained) Mid Creek Mouth (sandy strata) Inner Creek Mouth (very fine) Depth (cm) FSP Signal (rel)
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Mean Particle Size (um)
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500 250 125 63
0-6” Strata 6-12” Strata 12-18” Strata 18-24” Strata Calibrated Mean Particle Size (um)
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1 Month Survey
Sand Cell AquaBlok Cell Apatite Cell Coke Breeze Cell
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Grain Size (um) Depth (cm)
Station 1 Station 8
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“… rapid, inexpensive, and standardized assessment tools to measure the rates and magnitude of the fundamental contaminant fate and transport processes in order to adequately develop and refine a conceptual site model.”
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Clay Silt
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http://www.serdp-estcp.org/Tools-and-Training/Webinar-Series/12-04-2014
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