Natural Gas DRA Drag Reducing Agent for Natural Gas Pipeline - - PowerPoint PPT Presentation

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Natural Gas DRA Drag Reducing Agent for Natural Gas Pipeline - - PowerPoint PPT Presentation

Natural Gas DRA Drag Reducing Agent for Natural Gas Pipeline Transportation Themark Corporation Competition Worldwide Country Available Lab Sample Commercialized? USA Yes No UK Yes No Russia No No Japan No No Norway No No


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Themark Corporation

Natural Gas DRA

Drag Reducing Agent for Natural Gas Pipeline Transportation

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Competition Worldwide

Themark Corporation

Country USA UK Russia Japan Norway Germany France Themark Corp Available Lab Sample Yes Yes No No No No No Yes Commercialized? No No No No No No No Yes

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USA/UK

Resilience of pipeline wall Corrosion inhibitor analogue Pipeline precleaning or shutdown is needed for DRA coating Hard to treat (1-10mm) Smelly and toxic chemicals 0.15 Performance stablizes within 1 month No performance remains at day 90 No commercial samples 10 - 70ºC

Our Advantage

Themark Corporation Item

Mechanism Molecules Injection Method Post-treatment Environmental Impact Efficiency and Duration (In-house) Efficiency and Duration (Field) Applicable Temperature

Themark Corp

Roughness and resilience of internal pipeline wall Proprietary all-new molecule No downtime - online spray, no interrupt for transportation No maintence (20µ) Environmentally friendly, light smell 14~15% Performance stablzes within 2 months 8% improvement remains at day 90 >10% within 2 months 6% at day 90

  • 50 -150ºC
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Compact Injection System

Themark Corporation

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DRA Molecule Filming Mechanism

Themark Corporation

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Dose Calculation

Themark Corporation

Quantity = 2 × π × r × L × d × ζ r = Pipeline radius r=0. 3m L = pipeline length L= 100,000m d = film thickness d=2×10-5m ζ = Times of injection ζ = 5 Example: Q = 2×3.14×0.3×100,000×(2×10-5) ×5 = 18.84m3

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Coverage Distance

Themark Corporation

Flow Rate (m/s) 2 2 2 3 3 3 5 5 5 8 8 8 Diameter (mm) 300 600 900 300 600 900 300 600 900 300 600 900 Distance Coverage (km) 100 90 80 120 110 100 150 130 110 200 180 160

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Technical Data Sheet

Themark Corporation

Density 1.10~1.12g/mL Viscosity 1mPa·s Applicable Temp -50°C~100°C Toxicity Nontoxic; Environmentally Friendly Breakdown 400ºC Acidity Neutral Odor Nearly Odorless Color Yellow Liquid

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Effect on Pipeline Operation

Themark Corporation

No corrosion on pipeline wall

  • 1. Weight loss after treatment ω=(W0-W)/(S×D) 0.00 m/d
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Effect on Pipeline Operation

Themark Corporation

No corrosion on pipeline wall

  • 2. Electro-chemical result:

No corrosion

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Effect on Pipeline Operation

Themark Corporation

No detrimental effect on natural gas quality The nonvolatility of the DRA prevents it from entering the natural gas. Its small-molecule hydrocarbon solvent is combustible (combusted product is the same to that of natural gas). No side effect for the natural gas quality.

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Effect on Pipeline Operation

Themark Corporation

No side effect to natural gas compressor Soaking the whole compressor into DRA solutions for 90 days leads to no change in all aspects, e.g. shape, me- chanical strength, resilience etc. Residual DRA (1.3×10-10 of the natural gas) can be readily separated and has no effect on the compressor.

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Effect on Pipeline Operation

Themark Corporation

No effects on internal wall of pipeline Soaking the filmed pipeline coupons into the DRA solution leads to no change in coupon weight, color, resilience and mechanical strength.

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Effect on Pipeline Operation

Themark Corporation

Third-party Toxicity Study The DRA is nontoxic and nonvolatile. It does not enter the natural gas, and leads no side effects on the natural gas.

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Effect on Pipeline Operation

Themark Corporation

No effects on post-transport treatment Adding DRA into to carbon and sulphur removing solution leads no change.

Methyldiethanolamine diethanolamine: H2O 40: 5: 55 (Carbon and sulphur removing agent)

Before After

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Effect on Pipeline Operation

Themark Corporation Triglycol (dehydrating agent)

No effects on post-transport treatment Adding DRA to natural gas dehydrating agent leads no change to the dehydrating agent.

Before After

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Field Test

Themark Corporation No detrimental effects of DRA were found for transpiration, storage, post-treatment and refinery.

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Field Test Design

Themark Corporation

Air Flow Pigging Process Normal Process Nozzle Air Flow Processing On-site with Specifications

  • f Flange

Ball Valve High Pressure Hose Connected to Injection Site

Injector

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Field Test

Themark Corporation Average friction resis- tance reduced by 19.5%. Increased transportation capacity: 11.5%.

Friction Resistance

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Long-Distance Field Test

Themark Corporation

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Simple Application

Themark Corporation

Assembly of Injector

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Long-Distance Field Test

Themark Corporation

Field Results FRR:10% FRR:11% FRR:10% FRR:15%

FRR: Friction Resistance Reduction

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Long-Distance Field Test

Themark Corporation Using an existing water-injector for DRA application (July to Oct 2011)

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Themark Corporation

Long-Distance Field Test

Field Results

Pipeline No. 1 2 3 4 5 Distance (km) 18.1 18.95 54.25 13.65 18.05 Yes Friction Reduction 15.6% 10.2% 15.1% 5.0% 4.1% Duration 75 days 75 days 75 days 75 days 75 days

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SLIDE 25

Themark Corporation

Thank You