Implementing New Phosphine Labeling Changes IAOM Pre-conference - - PowerPoint PPT Presentation

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Implementing New Phosphine Labeling Changes IAOM Pre-conference - - PowerPoint PPT Presentation

Implementing New Phosphine Labeling Changes IAOM Pre-conference Workshop May 12, 2004 Pamela Peckman - IFC Overview for this Talk 1. Implementing Major Label Changes State Requirements Written Notification to Receivers


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SLIDE 1

Implementing New Phosphine Labeling Changes

IAOM Pre-conference Workshop May 12, 2004

Pamela Peckman - IFC

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SLIDE 2

Overview for this Talk

  • 1. Implementing Major Label Changes

– State Requirements – Written Notification to Receivers – Fumigation Management Plans

  • 2. Safety Monitoring
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SLIDE 3

Background Information

  • Re-registration (RED) 12/1998
  • MOA 1/2002 - Major Provisions

– Fumigation Management Plans – Incident Reporting – Monitoring Studies – Worker Exposure Limits – Training and Certification – Other Label Modifications

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SLIDE 4

Timeline of Revisions

1. January 17, 2002 2. September 11, 2002 3. September 19, 2002 4. September 20, 2002 5. December 9, 2002 6. January 18, 2003 7. January 27, 2003 8. May 7, 2003 9. May 9, 2003

  • 10. May 15, 2003
  • 11. Final labels starting fall of 2003

Initial Acceptance based on MOA States stopped process

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SLIDE 5

Consult with Your State

“THIS PRODUCT MUST BE ACCOMPANIED BY AN APPROVED LABEL & APPLICATORS MANUAL. ALL PARTS OF THE LABELING AND APPLICATORS MANUAL ARE EQUALLY IMPORTANT FOR SAFE AND EFFECTIVE USE OF THESE PRODUCTS. CONSULT WITH YOUR STATE LEAD PESTICIDE REGULATORY AGENCY TO DETERMINE REGULATORY STATUS, REQUIREMENTS AND RESTRICTIONS FOR FUMIGATION USE IN THAT STATE. CALL (540) 234-9281 OR 1-800-330-2525 IF YOU HAVE ANY QUESTIONS OR DO NOT UNDERSTAND ANY PART OF THIS LABELING.”

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SLIDE 6

New Label Changes – Certified Applicator

PRESENT & RESPONSIBLE

  • A. During Application

“physically present, responsible for, and maintain visual and/or voice contact with all fumigation workers”

  • B. During Aeration

“Certified applicator present for initial opening” “once process is secured and monitoring has established that aeration can be completed safely, trained personnel can complete process”

  • C. Persons with documented training

“responsible for receiving, aerating and removal of placards from vehicles fumigated in transit”

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SLIDE 7

Written Notification to Receivers

  • Good Annual Notification Process

– Help ensure your receiver knows the new label

  • Some states require notification with each

car

“The Shipper and/or the fumigator must provide written notification to the receiver of …vehicles which have been fumigated in-transit”

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SLIDE 8

Fumigation Management Plans

  • Section 21

– 9 Items – Guidance Document

  • Maintain for 2 yrs minimum
  • Prior to each fumigation, review

– Existing FMP – MSDS – Applicators Manual

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SLIDE 9

Components of the Guidance Document

  • Section A -Preplanning
  • Section B -Personnel
  • Section C- Monitoring
  • Section D -Notification
  • Section E - Sealing
  • Section F - Application
  • Section G - Post Application Operations
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SLIDE 10

Aeration & Placards

  • Air space & Commodity < 0.3ppm
  • “Placards must be made of substantial material to

withstand adverse weather”

  • May only be removed by certified applicator or

person with documented training

“To determine whether aeration is complete, each fumigated structure or vehicle must be monitored and shown to contain 0.3 ppm or less of phosphine gas in the air space around and, if feasible, in the mass of the commodity.”

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SLIDE 11

Safety Monitoring

Industrial Hygiene Monitoring “Phosphine gas exposures must be documented in an

  • perations log or manual at each fumigation area and
  • peration where exposures may occur. Monitor

airborne phosphine concentrations in all indoor areas to which fumigators and other workers have had access during fumigation and aeration. Perform such monitoring in workers breathing zones.”

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SLIDE 12

Safety Monitoring

Industrial Hygiene Monitoring (cont.) “This monitoring is mandatory and is performed to determine when and where respiratory protection is

  • required. Once exposures have been adequately

characterized, spot checks must be made, especially if conditions change significantly or if an unexpected garlic odor is detected or a change in phosphine level is suspected.”

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SLIDE 13

Safety Monitoring

  • Exposure Limits in New Label

– 0.3 ppm TWA – 1.0 ppm STEL (15 min. TWA) – No MAC after application

  • Safety Monitoring Records

“Gas exposure must be documented in an

  • perations log or manual at each fumigation area &
  • peration where exposure may occur”
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SLIDE 14

Registrant Monitoring Study

  • Submitted to EPA Jan. 9, 2003
  • Data gathered by several companies at over

30 sites

  • In General

– Showed no evidence of unacceptable bystander exposure to phosphine, even if downwind. – Proper monitoring and use of PPE eliminated worker exposure concerns.

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SLIDE 15

Phosphine Safety Monitoring in Grain Elevators

The following slides provided by Carl Reed Kansas State University

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SLIDE 16
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Example of Fumigant Dilution as Phosphine Leaks to Open Air

  • Ca. 300 readings taken over a 10-hour period

Position 0 ppm 0 - 0.1 ppm 0.09 - 0.3 ppm >0.3 ppm Ave ppm 6 " from leak 0.1 15.5 84.4 4.44 5 ' from leak 39.5 60.5 0.016 10 ' from leak 60.9 39.1 0.006

Percent of all Readings

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SLIDE 18

Gallery

Fill Port

Discharge Spout

Headspace Wall Vents Intervents

Structures that contribute to fumigant movement from the fumigated grain

Exposures occur when fumigant gas moves into enclosed WORKER AREAS

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SLIDE 19
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SLIDE 20

Phosphine concentrations in worker breathing zones in the headhouse of a country elevator

0.5 1 9/15/1998 9/16/1998 9/17/1998 9/18/1998 9/19/1998

Date (1:00 p.m.) PPM Phosphine

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SLIDE 21

Likelihood of high phosphine concentration depend on location

Percent of All Phosphine Readings* Location 0 ppm Less than 0.3 ppm Greater than 0.3 ppm

Ground-level, inside

79.1 22.3 5.8

Bin-top level, inside

27.2 37.9

34.9

Ground-level,

  • utside

99 1

Bin-top level,

  • utside

90 9.9 0.1

* Readings taken in fall, winter, and spring

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SLIDE 22

Phosphine Levels in the Tunnel

when fumigant movement was downward

Fumigated Bin Vents

0.15 ppm 0.68 ppm 1.7 ppm 2.0 ppm 1.8 ppm 3.1 ppm 0.28 ppm 0.28 ppm

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SLIDE 23

Phosphine concentrations in the tunnel of a terminal elevator when tunnel fan was turned off

1 2 3 4 5 6 7 8

2/2/1999 2/3/1999 2/4/1999 2/5/1999 2/6/1999 2/7/1999

Date (1:00 p.m.) PPM Phosphine

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Phosphine Concentrations in the Gallery of a Terminal Elevator as Affected by Closed Windows

1 2 3 4

10/28/98 10/29/98 10/30/98 10/31/98 11/1/98 11/2/98

Date (1:00 p.m.) PPM Phosphine

8:30 p.m.

8:00 p.m. 8:00 p.m. Fri. 7:45 a.m. Mon. 7:00 p.m. 7:30 a.m. 9:00 a.m.

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SLIDE 25

The likelihood of fumigant exposure depends on the type of structure fumigated

Little likelihood of exposure here unless worker enters the fumigated bin or flat store. Danger is Here

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Minimizing Worker Exposure to Phosphine Fumigant

  • Fumigant exposures occur in enclosed worker

areas, i.e. tunnels, head houses, galleries

  • Fumigant exposures are most likely to occur at:

– bin-top areas in the fall and winter – tunnel areas in the summer

  • Exposures can be controlled

– Proper Sealing – Mechanical Controls – Worker Monitoring

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SLIDE 27

What are You Doing to Comply?

  • Review the new label
  • Develop an FMP
  • Develop Receiver Notification Programs
  • Develop Personnel

– Certification – Training Ex: In-house railcar fumigations, are there enough certified applicators to cover vacation time and all shifts.

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SLIDE 28

Any Questions??????

pam@indfumco.com 913-782-7600