Endocrine Disruptors and Persistent Organics in Ithaca NY . Susan - - PowerPoint PPT Presentation

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Endocrine Disruptors and Persistent Organics in Ithaca NY . Susan - - PowerPoint PPT Presentation

Feb 09, 2024 510 likes •745 views

Endocrine Disruptors and Persistent Organics in Ithaca NY . Susan Allen-Gil, Jose L. Lozano Ithaca College and Ithaca Area Wastewater Treatment Facility. 1 PAT PHILLIPS AND TIA-MARIA SCOTT (USGS ALBANY) NYS DEPARTMENT OF HEALTH

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Endocrine Disruptors and Persistent Organics in Ithaca NY .

Susan Allen-Gil, Jose L. Lozano Ithaca College and Ithaca Area Wastewater Treatment Facility.

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  • PAT PHILLIPS AND TIA-MARIA SCOTT (USGS

ALBANY)

  • NYS DEPARTMENT OF HEALTH
  • ITHACA COLLEGE (SUSAN ALLEN-GIL)
  • CORNELL (DAMIAN HELBLING AND AMY

POCHODYLO)

  • CORNELL COOPERATIVE EXTENSION
  • CAYUGA FLOATING CLASSROOM

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SLIDE 3

IAWWTF

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Antibiotic Anticonvulsant Antidepressant Antifungal Antihistamine Antiviral Benzodiazepine Diabetics (Metformin) Hypertensives Mescle Relaxants Opiates/Opiods Other (Non Pharmaceutical) Other Pharmaceuticals Stimulant

THE STARTING POINT: DRINKING WATER INTAKE

J u n e 2 1 4 J u l y 2 1 4 S e p t e m b e r 2 1 4 D e c e m b e r 2 1 4 M a y 2 1 5

ng/L

10 20 30 40 50

Atrazine Nicotine Metformin

J u n e 2 1 4 J u l y 2 1 4 S e p t e m b e r 2 1 4 D e c e m b e r 2 1 4 M a y 2 1 5 J u l y 2 1 5

ng/L

50 100 150 200 250

  • Six Mile Creek water is cleaner than Fall Creek Water (note scales differ)
  • Metformin, atrazine, nicotine, and acetaminophen found most often and at highest

concentrations

  • Detectable, reportable, but less than 1 pinch of salt on 10 tons of potato chips
  • Doesn’t mean that is what comes out of your sink! (just atrazine! 35 nanograms/L)

Six Mile Creek Fall Creek

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AFTER HUMAN USE: INFLUENT

J u n e 2 1 4 J u l y 2 1 4 S e p t e m b e r 2 1 4 D e c e m b e r 2 1 4 M a y 7 2 1 5 M a y 8 2 1 5 M a y 9 2 1 5 M a y 1 2 1 5 M a y 1 2 2 1 5 M a y 1 3 2 1 5 M a y 1 4 2 1 5

ng/L

50000 100000 150000 200000 250000 300000 350000

Antibiotic Anticonvulsant Antidepressant Antifungal Antihistamine Antiviral Benzodiazepine Diabetics (Metformin) Hypertensives Mescle Relaxants Opiates/Opiods Other (Non Pharmaceutical) Other Pharmaceuticals Stimulant

  • Much higher levels that

raw water

  • More compounds

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INFLUENT: MAY 9, 2015

ng/L

1 10 100 1000 10000 100000 1000000 Fluvoxamine Loratadine Methadone Norverapamil Chlorpheniramine Carisoprodol Atrazine 10-Hydroxy-amitriptyline Promethazine Sertraline Propranolol Amitriptyline Thiabendazole Desmethyldiltiazem Verapamil Nizatidine Ketoconazole Triamterene Nadalol Penciclovir Abacavir Pentoxifylline Metaxalone Fluoxetine Oxycodone Dextromethorphan Fluconazole Bupropion Codeine Piperonyl butoxide Famotidine Carbamazepine Lamivudine Quinine Metoprolol Cimetidine Diltiazem Meprobamate Citalopram Venlafaxine Tramadol Amphetamine Lidocaine Sulfamethoxazole Methocarbamol Sitagliptin Cotinine Trimethoprim Morphine Diphenhydramine Desvenlafaxine Ranitidine Atenolol Theophylline Nicotine Acyclovir Pseudoephedrine + ephedrine3 Fexofenadine 1,7-Dimethylxanthine Methyl-1H-benzotriazole Metformin Acetaminophen Caffeine

Antibiotic Anticonvulsant Antidepressant Antifungal Antihistamine Antiviral Benzodiazepine Diabetics (Metformin) Hypertensives Mescle Relaxants Opiates/Opiods Other (Non Pharmaceutical) Other Pharmaceuticals Stimulant

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JULY 2014 SH2440 INFLUENT VS. EFFLUENT

ng/L

1 10 100 1000 10000 100000 Glyburide Loratadine Hydroxyzine Chlorpheniramine Paroxetine Omeprazole + esomeprazole3 Norverapamil Methadone 10-Hydroxy-amitriptyline Erythromycin Sertraline Sulfadimethoxine Amitriptyline Carisoprodol Atrazine Thiabendazole Desmethyldiltiazem Verapamil Hydrocodone Propranolol Abacavir Dextromethorphan Hydrocortisone Nizatidine Nadalol Quinine Fluconazole Oxycodone Triamterene Codeine Pentoxifylline Carbamazepine Amphetamine Metaxalone Bupropion Metoprolol Meprobamate Citalopram Venlafaxine Lamivudine Penciclovir Lidocaine Diltiazem Sitagliptin Cimetidine Methocarbamol Tramadol Trimethoprim Morphine Famotidine Diphenhydramine Desvenlafaxine Sulfamethoxazole Atenolol Cotinine Ranitidine Pseudoephedrine + ephedrine3 Theophylline Nicotine Acyclovir Fexofenadine 1,7-Dimethylxanthine Methyl-1H-benzotriazole Metformin Acetaminophen Caffeine

ng/L

1 10 100 1000 10000 100000 Hydroxyzine Glyburide Loratadine Verapamil Norverapamil Omeprazole + esomeprazole3 Abacavir Albuterol 10-Hydroxy-amitriptyline Acetaminophen Erythromycin Temazepam Desmethyldiltiazem Hydrocodone Carisoprodol Thiabendazole Atrazine Dextromethorphan Propranolol Nadalol Oxycodone Lamivudine Pentoxifylline Citalopram Fluconazole Metaxalone Triamterene Quinine Cotinine Caffeine Codeine Carbamazepine Metoprolol Diltiazem Nicotine Phenytoin Penciclovir Morphine Meprobamate Sitagliptin Venlafaxine Bupropion Lidocaine Tramadol Trimethoprim Pseudoephedrine + ephedrine3 Methocarbamol Diphenhydramine Acyclovir Sulfamethoxazole Atenolol Desvenlafaxine Fexofenadine Methyl-1H-benzotriazole Metformin

Influent Effluent

Antibiotic Anticonvulsant Antidepressant Antifungal Antihistamine Antiviral Benzodiazepine Diabetics (Metformin) Hypertensives Muscle Relaxants Opiates/Opiods Other (Non Pharmaceutical) Other Pharmaceuticals Stimulant

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SLIDE 10

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Treatment trend: Polar escapes Lipophilic stays

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THE ENDING POINT: CAYUGA LAKE

J u n e 2 1 4 J u l y 2 1 4 S e p t e m b e r 2 1 4 M a y 2 1 5

ng/L

100 200 300 400

Lidocaine Atzrazine Metformin Caffeine

  • Much lower

concentrations than influent/effluent (100,000 to 300 ng/l)

  • But some

pharmaceuticals detectable

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SLIDE 12

ng/L

20 40 60 80 100 120 140 160 Cotinine Nicotine Caffeine Methyl-1H-benzotriazole Atrazine Metformin Lidocaine

CAYUGA LAKE PHARMACEUTICALS SEPTEMBER 2014

Deicing fluid additive

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Compounds Always Detected

  • Bis(2-ethylhexyl)phthalate

– Common plasticizer, classified as a High Production Volume Chemical

  • Caffeine
  • DEET
  • Prometon

– Herbicide used for landscaping; not used for food crops

  • Sucralose
  • Venlafaxine

– Antidepressant

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Alternatives:

Avoidance UV-O3 / Filtration Selective adsorption/desorption (cyclodextrins) EAG Technology

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Also of Concern: Microplastics

Crowbar Sample

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Near East Shore Sailing Dock, 2016,

appears to be in GI tract

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SLIDE 18

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All USGS data will be on the NWIS data base http://waterdata.usgs.gov/nwis

Phillips, Patrick < pjphilli@usgs.gov> Damian E Helbling < deh262@cornell.edu> Susan Allen-Gil < sallen@ithaca.edu> Jose Luis Lozano < jll13@cornell.edu>

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https://drive.google.com/file/d/0BwqAUDio7q27b2JpQjJVTDk 0R2c/view?usp= sharing

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THE ENDING POINT: CAYUGA LAKE HORMONES

June 2014 July 2014 September 2014 May 2015 July 2015

ng/L

200 400 600 800 1000

Cholesterol Androgens

  • 300 -1000 ng/l
  • Very low synthetic estrogens

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CAYUGA LAKE: WASTEWATER COMPOUNDS

J u n e 2 1 4 J u l y 2 1 4 S e p t e m b e r 2 1 4 M a y 2 1 5

µg/L

0.0 0.1 0.2 0.3 0.4

Personal Care/Domestic Use Polycyclic Aromatic Hydrocarbon Pesticide/Herbicide Plant/Animal Biochemical Plasticizer/Phosphorous Based Flame Retardant Other 21

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CAYUGA LAKE: WASTEWATER COMPOUNDS

µg/L

0.00 0.01 0.02 0.03 0.04 0.05 0.06 Isophorone Camphor Caffeine Metolachlor Tris(2-chloroethyl) phosphate (TCEP)

Personal Care/Domestic Use Polycyclic Aromatic Hydrocarbon Pesticide/Herbicide Plant/Animal Biochemical Plasticizer/Phosphorous Based Flame Retardant Other 22