Development of Nanostructured Materials Technologies for Structural - - PDF document

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21C Frontier R&D Program

CNMT

Development of Nanostructured Materials Technologies for Structural Applications by CNMT Sang-Hee Suh

Center for Nanostructured Materials Technology http:/cnmt.kist.re.kr/

Center for Nanostructured Materials Technology

21C Frontier R&D Program

CNMT 2

Outlines

R&D investment for NT by Korean Government R&D programs for NT in Korea R&D program by the CNMT

R&D program for structural applications by the CNMT

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Center for Nanostructured Materials Technology

21C Frontier R&D Program

CNMT 3

Investment for NT by Korean Government

Research & Development

137.7 M$

Education for NT

9.4 M$

R&D I nfrastructures

Nano Fabrication Centers 60.9 M$

NT

Total Investment in 2003: 208 M USD Center for Nanostructured Materials Technology

21C Frontier R&D Program

CNMT 4

R&D Programs for Nanotechnologies in Korea

R&D Programs for Nanotechnologies by the Ministry of Science and Technology of Korea

Basic NT Core NT

Industrial Impact

Time scale for Industrialization of the developed technologies

2007 2012 2017 10 5

Frontier Research Program Fundamental NT

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Center for Nanostructured Materials Technology

21C Frontier R&D Program

CNMT 5

Frontier Research Programs for Nanotechnologies

Frontier Research Centers for Nanotechnology

Center for Nanostructured Materials Technology Center for Nanoscale Mechatronics & Manufacturing Tera-level Nanodevice Program

Budget

About 10 M US Dollars every year for 10 years for each Center

Nano- technology

Nano- materials Nano- systems

Nano- devices

Center for Nanostructured Materials Technology

21C Frontier R&D Program

CNMT 6

Overview of the R&D Program by the CNMT

Three Areas with 30 Projects

High strength nanostructured materials Environmental and energy storage materials Optical materials for information technology

• 2002. 7. – 2012. 3.

55 Institutions

550 Researchers

CNMT 10 Research Institutes 24 Companies 4 Foreign Institutes 19 Universities

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Center for Nanostructured Materials Technology

21C Frontier R&D Program

CNMT 7

Nanostructured Materials under Development by the CNMT

High strength nanostructured materials

Nanostructuredbulk materials Nanostructuredcomposite materials Hard coating materials

Environmental and energy storage materials

Catalysts for environment applications Active materials for rechargeable batteries

Optical materials for information technology

Nanostructuredmaterials and devices for broad band

• ptical communication

Nanostructuredmaterials and devices for display applications

Center for Nanostructured Materials Technology

21C Frontier R&D Program

CNMT 8 High strength nanocomposite bumper facia High performance tire

Structural Applications of Nanostructured Materials

Nanostructured Structural Materials for Car Industries

Ultra light and high strength steel, Al Hard coating on plastic windshield Aging resistant paint

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Center for Nanostructured Materials Technology

21C Frontier R&D Program

CNMT 9

Nanocrystalline Materials by Severe Plastic Deformation by

J.W. Park of KIST, D.H. Shin of Hanyang Univ. and C.Y. Lim of KIMM To increase the strength of Al and Cu alloys 2 to 3 times and obtain superplastic behavior at the processing temperatures by reducing the crystal grain size down to 100-200 nm.

ECAR (Equal Channel Angular Rolling) : Al alloys ECAP (Equal Channel Angular Pressing), ARB (Accumulative Roll Bonding): Cu

plunger

ECAP N=1 N=1 N=8 N=8 ECAR Nanocrystalline materials

conventional engineering materials reducing scale

toughness toughness strength strength

Theoretical strength

Center for Nanostructured Materials Technology

21C Frontier R&D Program

CNMT 10

Amorphous Composite Materials by J.C. Lee of KIST, S.Y.

Shin of KITECH and S.H. Lee of POSTECH

To develop amorphous composite materials and their processes with UTS of 2-3 Gpa and elongation of 4-6%.

Formation of soft crystals in bulk metallic glass during rapid solidification or heat treatment Powder sintering to form a composite structure of soft crystals in bulk metallic glass

17 17 1 2 3 4 5 6 7 8 9 10 10 11 11 12 12 13 13 14 14 15 15 16 16 500 1000 1500 2000 2500 3000

Pure amorphous ( Cu60Zr30Ti10 )

Stress (MPa) Strain (%) Strain (%)

Amorphous composite (Cu60Zr30Ti10) 95Ta5

UniaxialCompression Strain Rate = 1 x 10

• 4/s

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Center for Nanostructured Materials Technology

21C Frontier R&D Program

CNMT 11

Polymeric Nanocomposite by T.W. Kim of KIMM and J.R. Lee

• f KRICT

Polymer matix composite reinforced with both micron- and nano- carbon fibers

Carbon nanofibers made by electrospinning

Center for Nanostructured Materials Technology

21C Frontier R&D Program

CNMT 12

Metallic Nanocomposite by S.K. Lee of KIMM and S.H. Hong of

KAIST Cu matrix composite reinforced with CNF or CNT Target strength: 1 Gpa

CNTs Cu Grain boundaries

Cu powder embedded with CNTs

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Center for Nanostructured Materials Technology

21C Frontier R&D Program

CNMT 13

Ceramic Nanocomposite by S.H. Park of KIST

Laminated Ceramics

Ti3SiC2, Ti3AlC2 Machinable and low friction coefficient (< 0.1) High oxidation resistance Low fracture strength < 600 Mpa

Reinforced with nanophases

1.5 Gpa, 1500oC Ti3SiC2

100µm 50µm

Ti3AlC2

Center for Nanostructured Materials Technology

21C Frontier R&D Program

CNMT 14

20-30 GPa 40-60 GPa

TiN, TiAlN, CrN nano-multilayer (TiN/AlN)

Toughness Hardness

Si3N

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Cemented Carbides High Speed Steel CBN PCD Ideal Cutting Tool Material Coated Carbides

target

Nano-multilayer Coated Carbide

Nanostructured Multilayer Hard Coating by K.R. Lee

and Y.J. Paik of KIST

Carbon based nanoscale multilayers and nano- composite films for precision dies

Tetrahedral amorphic carbon coating

Nanomultilayersuperlattice materials for cutting tools

TiN/VN multilayers

50nm 50nm

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Center for Nanostructured Materials Technology

21C Frontier R&D Program

CNMT 15

Nanostructured Thermal spray coating by S.H. Hwang of

RIST and H.K. Suk of KIST Development of Feedstock Materials

Powder feedstock from nanoparticles by spray drying or liquid condensation Hard metallic wire by spray forming and downstream mechanical processing

Development of Thermal Spray Processes

Plasma spraying, High velocity

• xyfuel spraying, Cold spraying,

Electric arc spraying

WC/Co cermet coating for high wear resistance and durability Multi-component coating for low friction coefficient Hard metallic coating for corrosion and erosion resistance

Homogeneous Feedstock Constant Volume Dr ying Liquid Condensation Homogeneous Feedstock Constant Volume Dr ying Liquid Condensation Core/Shell Feedstock Spray D rying Controlled Bleeding Core/Shell Feedstock Spray D rying Controlled Bleeding

Multi-component solid lubricant coating WC/Co cermet coating

Plasma spraying

Center for Nanostructured Materials Technology

21C Frontier R&D Program

CNMT 16

Organic / Inorganic Hybrid Nanocomposite Coating for Plastic Materials by Kilwon Cho of Postech

Organic / organic nanocomposite coating through the control of crystallization of inorganic materials on the various organic templates

s u b s t r a t e

C a

2 +

C O

3 2

• C

a C O

3

i n t e r a c t i

• n

substrate

O O Si O CH3 Si CH 3 Si O CH 3 O O O

Multilayered organic/inorganic nanocomposite thin film by using dip

• coating
• r spin coating with polyelectrolyte and nano-

particles.

200 300 400 500 600 0.0 0.2 0.4 0.6 0.8 1.0 1.2 DR/PSS coated ZrO

2

2 4 6 8 10

Absorbance(A.U.) Wavelength(nm)

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Center for Nanostructured Materials Technology

21C Frontier R&D Program

CNMT 17

Vision of the Frontier Research Program for Nanostructured Materials Technology

Development of world top level technologies for nanostructured materials by the year 2012

21C Frontier R&D Program

CNMT

BIO.INFO.NANO The Convergence of 21st-Century Technologies

Monday October 20, 2003 The Westin Chosun, Seoul, 2F, Orchid Room Presented by the University of California. Berkeley and the UC Berkeley Korea Alumni Association

No Admission Fee! Lunch is served! On-line or off-line Pre-registration is required! www.berkeley.or.kr/symposium, Fax: 02-3443-3787, Tel: 02-3443-1315

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Center for Nanostructured Materials Technology

21C Frontier R&D Program

CNMT 19

Topics and Speakers

The Convergence of 21st-Century Technologies Thomas Kalil, Special Assistant to the Chancellor for Science and Technology Bio-Info-Nano in Service of Society

• S. Shankar Sastry, Chairman of the Department of EECS

Bridging the Nano-Bio Interface Paul Alivisatos, Chancellor’s Professor of Chemistry and Materials Science Integration of Novel Nanostructures with CMOS Jeffrey Bokor, Professor of EECS Integrated BioPOEMS with Nanophotonic Probes Luke P. Lee, Assistant Professor of Bioengineering