Depok, 4 th December 2015 Subject : Invitation to join MCEE - - PDF document

Depok, 4th December 2015 Subject : Invitation to join MCEE workshop Attachment : 5 pages Dear Rodiansono, Dr. Eng At Lambung Mangkurat University Paper Title : Synthesis of Ni/Pd-M (M= Ag, Co, and Fe) alloy catalysts for hydrogenolysis/ hydrodeoxygenation of bio-oil and liquefied low rank coal into chemicals and fuels. On behalf of the Program Committee. I am delighted to inform that your abstract has been accepted as ORAL PRESENTATION at the Materials Chemistry for Energy and the Environment Workshop which will be held on January 26th – 29th, 2016 at Novotel Bogor,

• Indonesia. Please also have your poster ready for display. We appreciate your participation

and look forward to welcoming you to MCEE Workshop in Bogor, 26th -29th January 2016. Warm regards,

• Dr. Yuni K. Krisnandi

Co-Host MCEE Workshop

Attachment 1: List of Participants from Indonesia No Name Affiliation 1 Aldes Lesbani Sriwijaya University 2 Kusmiyati University Muhammadiyah Surakarta 3 Fitria Rahmawati Sebelas Maret University 4 Catherina M. Bijang Pattimura University 5 Elvina Dhiaul Iftitah Brawijaya University 6 Rodiansono Lambung Mangkurat University 7 Muhammad Zakir Hasanudin University 8 Suwardiyanto Jember University 9 Is Fatimah Univ Islam Negri Jogjakarta 10 Kun Harismah University Muhammadiyah Surakarta 11 Muliadi Ramli University of Syiah Kuala 12 Rahmat Wibowo University of Indonesia 13 Arie wibowo ITB 14 Indri Badria Adilina LIPI - Chemistry 15 Nazarudin University of Jambi 16 Siti Alaa’ Mataram University 17 Kartika Afriani AKA 18 Boy Fachri Jember University 19 Hedi Surachman Universitas Indonesia

Attachment 2: Time Table of MCEE Workshop 2nd Day : Tuesday, 27th January 2016 08.30-09.30 Atomic-ensemble effects and non- covalent interactions at the electrode- electrolyte interface Angel Cuesta, University of Aberdeen 09.30-10.00 Synthesis of Ni/Pd-M (M= Ag, Co, and Fe) alloy catalysts for Rodiansono, Lambung Mangkurat University 08.30-09.00 Opening remarks Yuni Krisnandi, Russell Howe 09.00-09.30 Catalytic Materials in Petroleum Fuel Processing Hery Haerudin, Pertamina 09.30-10.30 Introduction meetings (with coffee) 10.30-11.30 A Molecular Perspective of Heterogeneous Catalysis David Lennon, University of Glasgow 11.30-12.00 Catalytic Oxidative Desulfurisation of Benzothiphene using Supported Polyoxometallate Catalysts Aldes Lesbani, Sriwijaya University 12.00-12.30 Electric Field Assisted Chemical Vapour Deposition of Enhanced Photocatalytic Materials Russell Binions, Queen Mary University of London 12.30-13.00 Increasing the Concentration of Bioethanol Fuel by Dehydration Process Using Molecular Sieve Kusmiyati, University Muhammadiyah Surakarta 13.00 – 14.00 Lunch 14.00-15.00 Boron-doped Diamond Electrodes for Electrocatalysis Applications Ivan Tribidisari, University

• f Indonesia

15.00-15.30 Oxygen Reduction at Nanoscale Transition Metal Oxides Veronica Celorrio, University of Bristol 15.30-16.00 Tea/coffee 16.00-16.30 Photocatalytic hydrogen production with TiO2/Graphite as a catalyst Fitria Rahmawati, Sebelas Maret University 16.30-17.00 Rhodium and molybdenum based catalysts for the selective oxidation of

• rganic substrates: autoxidation and

structure-activity correlations Marco Conte, University of Sheffield 17.00-17.30 Study on cyclisation and hydrogenation of (r)-(+)-Citronelal based on ZnBr2/γ-Al2O3 and Ni/ γ- Al2O3 catalysts Elvina Dhiaul Iftitah, Brawijaya University 17.30-18.00 Hierarchically porous zeolites for energy and environment applications Volkan Degirmenci, University of Warwick 18.00-19.00 Poster session 19.00 Evening meal 1ST Day : Tuesday, 26th January 2016

hydrogenolysis/ hydrodeoxygenation

• f bio-oil and liquefied low rank coal

into chemicals and fuels. 10.00-10.30 Tea/coffee 10.30-11.00 Challenges in the in-situ structural characterisation of electrochemical interfaces Yvonne Gründer, University

• f Liverpool

11.00-11.30 Development of novel carbon nanoporous materials from biomass based resources Muhammad Zakir, University Hasanudin 11.30-12.00 Low-Dimensional Carbon and TiO2 Nanostructures for Applications in Heterogeneous Catalysis and CO2 Storage Robert Menzel, University

• f Leeds.

12.00-12.30 Highly Active Mo/ZSM-5 Catalysts for Methane Dehydroaromatization. Suwardiyanto, Jember University 12.30-13.00 Mechanochemical synthesis of advanced nanomaterials for catalytic applications. Manuel Ojeda, Heriot-Watt University 13.00-14.00 Lunch 14.00-15.00 Preparation and Characterization of Highly Ordered Titania Nanotubes for Development of Modified CdS Sensitized Solar Cell Having Catalytic Zone as Artificial Photosyntesis for Hyndrogen Production Jarnuzi Gunlazuardi, Universitas Indonesia 15.00-15.30 Preparation of Cu/TiO2-pillared clays and Sn/TiO2-pillared clays Photocatalyst for Dye Degradation Is Fatimah, University Islam Negri Jogjakarta 15.30-16.00 Tea/coffee 16.00-16.30 A new synthetic route for an effective preparation of metal alloy nanoparticles and its use as active electrocatalyst and photocatalyst Paramaconi Rodriguez, University of Birmingham 16.30-17.00 Synthesis of N-(2-hexyldecyl)-2,7- linked Carbazole Polymers by Suzuki Coupling Reaction for LED Applications Kun Harismah, University Muhammadiyah Surakarta 17.00-17.30 Designing supported bimetallic nanoalloy catalysts for a green and sustainable future. Sankar Meenakshisundaram, Cardiff University 17.30-18.00 Modification of Aceh Dolomite Mineral as Solid Inorganic Base Catalyst and Its Application on Transesterification Reaction for Biodesel Synthesis Muliadi Ramli, University

• f Syiah Kuala

18.00-19.00 Poster session 19.00 Evening meal

3rd Day : Tuesday, 28th January 2016 08.30-09.30 Metal-Oxide/ZSM-5 as Heterogeneous Catalysts in Biomass Conversion Yuni Krisnandi, University

• f Indonesia

09.30-10.00 Carbon Nitrides: New Electroactive Materials for Energy Applications Ana Jorge, University College London 10.00-10.30 Coffee/tea 10.30-11.00 Electrochemical reduction of CO2 using Cu based catalyst Rahmat Wibowo, University

• f Indonesia

11.00-11.30 Probing the Carbonaceous Fallout in MTG Catalysis by Magnetic Resonance Stephen Sproules, University of Glasgow, 11.30-12.00 Simple Preparation of Iron Oxide Nanoparticles at Cellulose and Their Photochemical Catalytic Behavior Arie Wibowo, Institute of Technology Bandung 12.00-12.30 Materials and devices for electrochemical water splitting: a fresh look at some old catalysts and some new catalysts for old applications Mark D. Symes, University

• f Glasgow

12.30-13.00 Design and modification of bentonite clays as efficient heterogeneous catalysts for environmentally friendly conversions of biomass to innovative chemicals Indri Badria Adilina, LIPI Chemistry 13.00-14.00 Lunch 14.00-15.00 Exploring Reaction Pathways in Catalysis through Spectroscopy Russell Howe, University of Aberdeen 15.00-15.30 Gold Catalysts for Sustainable Chemical Processing Xiao-Dong Wang, University of Aberdeen 15.30-16.00 Tea/coffee 16.00-16.30 Aplications of Porous Materials from Industrial Wastes Nazarudin, University of Jambi 16.30-17.00 Enantioselective Heterogeneous Catalysis David Watson, University of Surrey, 17.00-17.30 Design of Bentonite Acid Modified Electrodes in Cyanide Biosensors Catherina M. Bijang, University Pattimura 17.30-18.00 Material and reactor innovation for low carbon energy Jin Xuan, Heriot-Watt University 18.00-19.00 Poster session 19.00 Evening meal 4th Day : Tuesday, 29th January 2016 08.30-09.00 Royal Society of Chemistry and research collaborations Sarah Thomas, Royal Society of Chemistry 09.00-09.30 British Council and research collaborations Speaker from British Council to be advised 09.30-10.00 Indonesian funding for research collaborations Eko Prasetyo, LPDP

10-11.30 Break-out sessions 1 Three parallel sessions: catalysis, photocatalysis, electrochemistry (accompanied by coffee and tea) 11.30-13.30 Friday prayers and lunch 13.30-15.00 Break-out sessions 2 Three parallel sessions: catalysis, photocatalysis, electrochemistry 15.00-16.30 Reports from breakout sessions and wrap up (accompanied by coffee and tea)

Synthesis of Ni/Pd-M (M= Co, Ag, Fe) alloy catalysts for hydro-deoxygenation of bio-oil components

Rodiansonoa* , Maria Dewi Astutia, and Shogo Shimazub

aDepartment of Chemistry, Lambung Mangkurat University, Banjarbaru, South Kalimantan 70713. bGraduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522.

*corresponding author: rodiansono@ulm.ac.id or rodian114@gmail.com ABSTRACT Biomass feedstock valorisations are currently being explored for the production of bio-based platform chemicals, fuels, and various commodity products by using bimetallic-based heterogeneous catalysts. The use of bimetallic catalysts is a promising option for biomass feedstock upgrading, as the interaction between metals can modify the surface properties of the catalyst meet with the complex surface. A simple hydrothermal treatment was applied to produce Ni-Sn alloys both bulk and supported under mild conditions. This synthetic method offers easy process, cost-effective, and eco-friendly procedure.[1,2] Tabel 1. Results of hydrogenolysis of furfural (FFald) using the synthesised bimetallic Ni-M alloy catalysts

Reaction conditions: cat., 44 mg; substrate, 1.2 mmol; solvent, EtOH/H2O, H2 3.0 MPa 433 K, 12 h. aDetermined by GC using an internal standard

• technique. bDetermined by GC and GC-MS. cIt may be dimerization

product of FFald or FFalc according to GC and GC-MS data.

It can be observed that the catalysts demonstrated high activity in the hydrogenolysis of biomass-derived furfural, whereas the product distributions are strongly depended on the catalyst structure and the composition. In case of bimetallic Ni-Sn both bulk and supported, the main products were tetrahydrofurfuryl alcohol (THFalc), methyl furan (MeTF), and methyl tetrahydrofuran (MeTHF) (entries 1-3). On the other hand, bimetallic Ni-M (M= Co, Fe, Ag) catalyst provided high yield of MeTHF as hydrogenolysed product when the amount of M=Co, Fe, Ag metals was increased (entries 4-8). Tabel 2. Results of hydrogenolysis of phenol (PhOH) using the synthesised bimetallic Ni-M alloy catalysts

Reaction conditions: cat., 44 mg; substrate, 1.2 mmol; solvent, EtOH/H2O, H2 3.0 MPa 433 K, 12 h. aDetermined by GC using an internal standard

• technique. bDetermined by GC and GC-MS.

In the hydrogenolysis of phenol, the Ni-Ag(3.0), R-Ni/AlOH, and Pd/C catalysts are active for the hydrogenation

• f benzene ring to give cyclohexanol as the main products (entries 7, 9, and 10). While the conversion of phenol

was >99%, bimetallic Ni-M (Sn, Co, Ag) catalysts provided the hydrogenolysis of benzene then subsequently hydrogenated to cyclohexane (entries 1-6). As a conclusion inexpensive Ni/Pd-M (M= Co, Ag, Fe) based alloy catalysts exhibited high activity and selectivity in the hydro-deoxygenation of bio-oil components of furfural and phenol. The presence of second metal to form alloy may enhance the activity and selectivity of Ni metal catalyst toward methyl furan, methyl tetrahydrofuran, methyl benzene, and methyl cyclohexane products. References

[1] (a) Rodiansono, T. Hara, N. Ichikuni, S. Shimazu, Catal. Sci. T echnol., 2012, 2, 2139-2145. (b) Rodiansono, T.

Hara, N. Ichikuni, S. Shimazu, BCREC, 2014,9(1), 53-59.