Chemistry in the Community Mid Term Review Sections 0 through 1.D - - PowerPoint PPT Presentation

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Chemistry in the Community Mid Term Review Sections 0 through 1.D - - PowerPoint PPT Presentation

Chemistry in the Community Mid Term Review Sections 0 through 1.D (p. 142 in the text book) Section 0.C 0.3 Density of Solids and Liquids M D V Density is a physical property D = ,


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SLIDE 1

Chemistry in the Community Mid Term Review Sections 0 through 1.D (p. 142 in the text book)

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SLIDE 2

Section 0.C

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SLIDE 3

0.3 Density of Solids and Liquids

  • Density is a physical property

D = , density of water = = 1 g/cm3

  • Calculate volume of a regular solid: Measure length x

width x height (units: cm3, m3, ft3 etc.)

  • Measure Volume of a liquid: Use a graduated

cylinder: mL or L

  • Measure volume of an irregular solid by displacement

with a graduated cylinder

  • Density of water = 1.00 g/mL 1 mL = 1 cm3

mass

volume

1 g

1 cm3

¡ ¡M ¡ D ¡ ¡ ¡V ¡

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SLIDE 4

Unit 1 Section A: Building Blocks of Chemistry

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SLIDE 5

1.A.5 Molecular View of Matter

  • Matter

– Anything that has mass and takes up space – All solids, liquids and gases are matter

  • Molecules are made of atoms held together by

chemical bonds; eg. N2 , H2O

  • Compounds are molecules with 2 or more different

atoms; eg. H2O

  • Elements contain only one type of atom; eg. N2

– there are ~115 elements; 88 naturally occurring – most occur as atoms, some as molecules – Diatomic elements: HONClBrIF

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SLIDE 6

Unit 1 A.2 Physical and Chemical Properties

  • Physical properties- Properties that can

be determined without altering the chemical makeup of the material.

  • Color, ductility, malleability, conductivity,

density, odor, boiling point, melting point, Freezing point, and shape

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SLIDE 7

Unit 1 A.2 Physical and Chemical Properties

  • Physical change in a substance does not

involve a change in the identity of the substance (grinding, cutting, melting, and boiling)

  • These changes can usually be reversed

(because the identity of the substance was not changed)

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SLIDE 8

Unit 1 A.2 Physical and Chemical Properties

  • Chemical property relates to a

substance’s ability to undergo changes that transform it into different substances.

  • Chemical change or Chemical reaction

is a change in which one or more substances are converted into different substances.

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SLIDE 9

Unit 1 A.2 Physical and Chemical Properties

  • A chemical change probably occurred if you
  • bserve one or more of the following:
  • Gas produced
  • Evolution of heat and light (Burning)
  • Formation of a precipitate
  • Change on the surface of a solid
  • Color Change to a new color that is not a result
  • f the mixing of colors; Such as two clear

substances yielding a red color.

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SLIDE 10

Classify as chemical or physical change

1. You make scrambled eggs. 2. You step on a piece of chalk and it becomes powdered. 3. You light a match when the electricity goes out. 4. Steam from your hot shower condenses on a cold mirror. 5. Milk turns sour. 6. Wax melts. 7. Wax burns.

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SLIDE 11

1.A.5 – Particles of Matter

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SLIDE 12

Modeling Matter

1. Is an element or compound shown in a? 2. Two kinds of atoms are shown in b; is this a compound? 3. Which diagrams show only molecules? Compare them. 4. Which diagrams show mixtures? Compare them.

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SLIDE 13

Symbols, Formulas, and Equations 1.A.6

  • Chemical Symbols represent elements

– First letter is capitalized; second letter is lower case

  • Chemical Formula represent different chemical

substances, e.g. H2O

– Subscript tells how many atoms of an element

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SLIDE 14

Symbols, Formulas, and Equations 1.A.6

  • Chemical Formulas are the “words” in the

language of chemistry.

  • Chemical equations are the sentences.
  • Each chemical equation summarizes the details
  • f a particular chemical reaction.
  • Chemical reactions entail the breaking and

forming of chemical bonds. – Atoms are rearranged to from new

  • substances. The properties of the new

substances are different from those of the

  • riginal material(s)
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SLIDE 15

Chemical Equation for formation of water 2 H2 + O2 à 2 H2O

Hydrogen Oxygen Water

Reactants Product

(Left side of the arrow) (Right side of the arrow)

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SLIDE 16

Unit 1.A.9 The Chemical Elements Metals

  • Include such elements as iron, tin, zinc, and

copper

  • At room temperature they are solids
  • A good conductor of heat and electricity
  • Malleability- hammered or rolled into sheets
  • Ductile- can be drawn in to a fine wire (high

strength)

  • Luster- most metals have a grayish or silvery

luster

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SLIDE 17

Unit 1.A.9 The Chemical Elements

Non Metals

  • Most are gases at room temperature

(except bromine which is a liquid)

  • The solid nonmetals tend to be brittle
  • A poor conductor of heat or electricity
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SLIDE 18

Unit 1.A.9 The Chemical Elements

Metalloids- Such as Silicon and Germanium

  • Elements on the stair-step line that separate the

metals from the nonmetals

  • Has some of the characteristics of metals and

nonmetals

  • Are solids at room temperature
  • Less malleable than metals
  • Not as brittle as non-metals
  • Some have a metallic luster
  • Semiconductors of electricity (their ability to conduct

electricity falls between that of metals and nonmetals)

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SLIDE 19

Metals, Nonmetals, Metalloids

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SLIDE 20

Unit 2 A.3 Lab: Metal or Non Metal?

Mg (s) + HCl→ MgCl2(aq) + H2(g) Zn (s) + HCl (aq) → ZnCl2 (aq) + H2 (g) Fe (s) + HCl (aq) → FeCl3 (aq) + H2 (g) Sn (s) + HCl (aq) → SnCl2 (aq) + H2 (g)

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SLIDE 21

How do you select a material for a specific use?

  • Need suitable physical and chemical properties
  • Need suitable cost

Examples:

  • during WWII (1943), pennies were made of

steel, but they corroded

  • Post 1982 pennies have a zinc core (cheaper)

– 97.5% Zinc

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SLIDE 22

Unit 1 Section B: Periodic Trends

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SLIDE 23

Periodic Table Origins 1.B.2

  • By mid-1800s, about 60 elements known;

mostly solids.

  • 1869 Dmitri Mendeleev published a periodic

table with elements in a regular pattern

– Elements arranged horizontally in order of increasing atomic weight (relative mass of individual atoms) – Elements with similar “combining capacity” for

  • xygen and chlorine placed in vertical groups

(columns)

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SLIDE 24

1.B.3 Electrical Nature of Matter

  • Demonstrate charged balloon
  • Like charges repel
  • Unlike charges attract

+ +

  • +
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SLIDE 25

1.B.3 Electrical nature of Matter

  • These Positive and negative charges in an

atom are:

  • Protons --positive charge
  • Electrons --negative charge
  • Neutrons -- neutral charge
  • The attraction between these particles are

the “glue” that hold the atom together

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SLIDE 26

The Pattern of Atomic Numbers 1.B.4

  • Properties of elements depend mostly on

the elements’ electronic structures.

  • Electronic structure- The arrangement of

electrons in the atom of an element.

  • Number of electrons is the same as the

number of protons for an electrically neutral atom. (not for ions)

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SLIDE 27

The Pattern of Atomic Numbers 1.B.4

  • The atomic number (# of protons) identifies an

element

– Every atom of carbon contains 6 protons in the nucleus

  • The nucleus also contains neutrons, which have

about the same mass as protons

– The mass # of an atom = #protons+#neutrons – Electrons have 1/2000 the mass of a proton, don’t contribute to mass # – Carbon atoms can have 6, 7, or 8 neutrons

  • Isotopes = atoms with same # protons, different #

neutrons

  • Mass Number
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SLIDE 28

Average Atomic Mass 1.B.4

Why is the atomic mass of chlorine (35.5 g) not a whole number?

Chlorine has two isotopes

76% of Cl = 35Cl (17 protons + 18 neutrons) = 35 g/mol 24% of Cl = 37Cl (17 protons + 20 neutrons) = 37 g/mol weighted average = closer to 35 g/mol = (0.76 x 35 g/mol) + (0.24 x 37 g/mol) = 35.5 g/mol

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SLIDE 29

The Periodic Table

Group

1 2 3 4 5 6 7

Periods ¡ ¡ Groups ¡ ¡

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SLIDE 30

Unit 1.B.7 Organization of the Periodic Table

Groups or Families

  • Vertical columns of the periodic table
  • Each group contains elements with similar

properties

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SLIDE 31

Unit 1.B.7 The Periodic Table

Periods

  • Horizontal rows
  • Elements close to each other have more

similar properties than those further apart

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SLIDE 32

Unit 1.B.7 The Periodic Table

Noble Gases

  • Unreactive or Inert elements
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SLIDE 33

Unit 1.B.7 The Periodic Table

Halogens

  • Elements of group 17
  • F, Cl are gases at room temperature
  • Br is a reddish liquid
  • I is a dark purple solid
  • At is a solid
  • Most reactive of the nonmetals
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SLIDE 34

Unit 1.B.7 The Periodic Table

Alkali Metals

  • The elements of group 1 on the periodic

table

  • Silvery appearance
  • Soft enough to cut with a knife
  • Very reactive (usually stored in kerosene

because of their reactivity with air or moisture)

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SLIDE 35

Unit 1.B.7 The Periodic Table

Alkaline Earth Metals

  • Elements in group two
  • Harder denser stronger than alkali metals
  • Less reactive than alkali metals
  • Too reactive to be found in nature as free

elements

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SLIDE 36

Unit 1.B.7 The Periodic Table

Exceptions to the rule:

  • Hydrogen(H) even though it’s part of

group 1, does not share the same properties of group 1

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SLIDE 37

Unit 1.B.7 The Periodic Table

Transition elements

  • Metals with metallic properties
  • Good conductors of electricity and have

high luster

  • Less reactive than alkali and alkaline earth

metals

  • Do not easily form compounds
  • Exist in nature as free elements
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SLIDE 38

Unit 1.B.7 The Periodic Table

Inner Transition Elements

  • All metals
  • Lanthanides

– Shiny metals

  • Actinides

– All radioactive – All beyond uranium are synthetic

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SLIDE 39

Unit 1.B.7 The Periodic Table

Main Group Elements

  • Groups 1-2
  • Groups 13-18
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SLIDE 40

Building Skills 1.B.8 Predicting Properties

  • Mendeleev laid out a Periodic Table in 1869 when
  • nly 60 elements were known

– Elements arranged in rows with increasing atomic weight – Elements in each column had similar chemical properties – He was so sure of his PT that he left blanks for undiscovered elements Si b.p. = 3267°C b.p. = (3267+2603)/2 = 2935°C predicted Sn b.p. = 2603°C Germanium discovered in 1886, b.p. = 2834°C

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SLIDE 41

Here are formulas for several known compounds: NaI, MgCl2, CaO, Al2O3, CCl4 Knowing that elements in the same group (column) react the same ways, predict the formulas for a compound formed from: a) C and F d) Ca and Br b) Al and S e) Sr and O c) Li and Cl

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SLIDE 42

1.B.10 Ions and Ionic Compounds

  • Ionic compounds are made of ions (charged

particles)

– Ionic compounds are neutral; they have no net charge because the positive and negative charges

  • ffset each other

– The ions are held together in crystals by attractions between the positive and negative ions

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SLIDE 43

1.B.10 Formation of Ions

  • Cation: an atom loses one or more electrons and

becomes positively charged

Na – 1 electron à Na+

  • Anion: an atom gains one or more electrons and

becomes negatively charged

Cl + 1 electron à Cl-

+ +

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SLIDE 44
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SLIDE 45

1.B.11 Writing Formulas for Ionic Compounds

  • 1. Write the cation first, then the anion
  • 2. The correct formula contains the fewest

positive and negative ions needed to make the total electrical charge zero Give the formula for a compound containing

  • a. Na+ and Cl-
  • b. Mg2+ and Cl-
  • c. Li+ and N3-
  • d. Al3+ and O2-
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SLIDE 46

Lab 1.B.12 Relative Reactivates of Metals

  • Cu Mg Ag Zn
  • Examples:
  • Cu(s) + Mg(NO3)2 à NR
  • Cu(s) + AgNO3 (aq) à Cu(NO3)2 + Ag (s)
  • Order of reactants doesn’t matter.
  • Order of products doesn’t matter
  • Look at the 2 metals; the one in the elemental

form must be higher on the activity series than the one which is combined (in an ionic compound) for a reaction to occur.

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SLIDE 47

1.B.13 Metal Reactivity

  • When finely divided copper metal is heated, it

gradually reacts with oxygen in the air to produce a black copper(II) oxide:

2 Cu(s) + O2(g) à 2 CuO(s)

  • Magnesium metal burns in oxygen with a blinding

light: 2 Mg(s) + O2(g) à 2 MgO(s)

  • Gold does not react with oxygen
  • An activity series ranks elements in order of relative

chemical reactivity. What is the relative reactivity of Cu, Mg, Au?

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SLIDE 48
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SLIDE 49

1.B.14 Trends in Metal Reactivity

  • In general , a more reactive element

(higher on the activity series) will cause ions of a less reactive metallic element (lower in the activity series) to change to their corresponding metal.

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SLIDE 50

Unit 1 Section C: Materials and Moles

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SLIDE 51

Metals with highest production world- wide: 1) Iron 2) Aluminum 3) Copper U.S. used to lead production in all of

  • these. This is not the

case anymore.

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SLIDE 52

Unit 1.C.2 Sources and Uses of Metals

  • In this section you will explore the

properties and uses of minerals and metals.

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SLIDE 53
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SLIDE 54

Unit 1.C.2 Sources and Uses of Metals

  • Ore- a naturally occurring rock or mineral

that can be mined and from which it is profitable to extract a metal or other

  • material. (Rocks with economic value)
  • Rocks- Mixtures of different minerals.
  • Minerals (simple definition) - compounds

which occur naturally and from which pure metals are obtained

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SLIDE 55

Unit 1.C.2 Sources and Uses of Metals

  • Lithosphere contains ores and minerals, which can be

mined for metals

  • Many metals are not uniformly distributed on Earth
  • Factors affecting whether or not to mine a metallic ore

at a specific site – Amount of useful ore at site – Percent of metal in ore – Type of mining and processing needed to extract metal – Distance of mine from refining facility and markets – Metal’s supply and demand status

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SLIDE 56

Unit 2.B.1 Sources and Uses of Metals

  • Copper is one of the most familiar and

widely used metal in modern society.

  • Second only to silver for conductivity
  • Low-cost, corrosion resistant, and ductile.
  • Most common metal for electrical wiring.
  • Used to produce brass, bronze, and
  • ther alloys.
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SLIDE 57

1.C.6 Moles: We need to count atoms

Airbags are inflated by a chemical reaction: 2 NaN3(s) 3 N2(g) + 2 Na(s)

Each airbag needs the right amount of NaN3 (sodium azide) to fill the bag with nitrogen gas

electrical

decomposition

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SLIDE 58

1.C.6 Grouping items for counting

  • The size of the group depends on how many items

we use at a time 1 dozen=12 gross = 12x12

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SLIDE 59

1.C.6 Counting by weighing

Mass of 1 dozen objects depends on the object

1 doz jelly beans = 14 g 1 doz eggs = 680 g 1 doz grapefruit = 5400 g

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SLIDE 60

1.C.6 A mole is the counting unit for atoms

1 mole = “chemists dozen”

1 pair = 2 items 1 dozen = 12 items 1 gross = 144 items 1 mole = 6.02 x 1023 items 6.02 x 1023 is “Avogadro’s number” 1 mole eggs = 6.02 x 1023 eggs 1 mole H atoms = 6.02 x 1023 H atoms 1 mole S atoms = 6.02 x 1023 S atoms

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SLIDE 61

1.C.6 How big is a mole?

6.02 x 1023 grains of sand would cover New Jersey to a depth of 20 miles

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SLIDE 62

1.C.6 How much does 1 mole of atoms weigh?

Since individual atoms weigh so little, chemists deal with moles of atoms. Avogadro’s number was conveniently chosen so that 1 C atom weighs 12 amu 1 mole of C atoms weighs 12 g

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SLIDE 63

1.C.7 Molar mass of an element

  • The periodic table gives average atomic masses of

elements; e.g. the average mass of an Fe atom is 55.8 atomic mass units (amu)

  • The mass of 1 mol of Fe is 55.8 g
  • The molar mass is the mass in grams of the average

atomic mass

molar mass of Fe =

55.8 g Fe mol Fe

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SLIDE 64

1.C.7 Compare 1 mole samples of elements

Element # atoms in 1 mole Mass of 1 mole, grams H 6.02 x 1023 1.0 C 6.02 x 1023 12.0 O 6.02 x 1023 16.0 Fe 6.02 x 1023 55.9 Au 6.02 x 1023 197.0

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SLIDE 65

1.C.9 – Composition of Minerals

l PERCENT COMPOSITION – percent by mass of

each material found in a substance.

l Ex: A penny with a mass of 2.500 grams is composed

  • f 2.4375 grams of zinc and 0.0625 grams of copper.

What is the percent mass of each metal in the penny?

l % Zn = 2.4375 g Zn x 100 = 97.50% Zinc

2.500g total

  • % Cu = 0.0625 g Cu x 100 = 2.50% Copper

2.500g total

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SLIDE 66

l Percent composition helps geologists to describe

how much metal or mineral is present in a particular ore.

l Ex: the mineral chalcocite = source of copper metal

§ Chemical formula = Cu2S § To calculate % comp. of Copper in chalcocite:

% comp = number of moles of Cu in Cu2S x molar mass of element (Cu) molar mass of compound (Cu2S) ¡ ¡ ¡ ¡ ¡ ¡

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SLIDE 67

FORMULA: ¡ ¡ ¡ ¡ ¡ ¡ ¡

% ¡comp ¡= ¡( ¡# ¡moles ¡of ¡element ¡in ¡compound ¡x ¡molar ¡mass ¡of ¡element ¡) ¡ ¡X ¡ ¡100 ¡

¡ ¡ ¡ ¡ ¡ ¡ ¡ ¡ ¡ ¡ ¡ ¡ ¡ ¡molar ¡mass ¡of ¡compound ¡ ¡

molar ¡mass ¡of ¡Cu2S ¡= ¡(2 ¡x ¡63.55 ¡g/mol) ¡+ ¡32.07g/mol ¡ ¡ ¡ ¡ ¡ ¡ ¡= ¡127.10 ¡g/mol ¡+ ¡32.07g/mol ¡ ¡ ¡ ¡ ¡ ¡ ¡= ¡159.17 ¡g/mol ¡ % ¡Cu ¡= ¡molar ¡mass ¡of ¡Cu ¡x ¡100 ¡= ¡127.10 ¡g/mol ¡x ¡100 ¡ ¡ ¡ ¡ ¡ ¡ ¡ ¡ ¡ ¡ ¡ ¡molar ¡mass ¡of ¡Cu2S ¡ ¡ ¡ ¡ ¡ ¡ ¡ ¡ ¡ ¡ ¡ ¡159.17 ¡g/mol ¡ ¡ % ¡Cu ¡= ¡0.7985 ¡x ¡100 ¡= ¡79.85 ¡% ¡Copper ¡

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SLIDE 68

Mining and Refining 1.C.10 p.101

  • Converting a combined metal (usually a metal

ion) in a mineral to a free metal involves a particular kind of chemical change.

  • Reduction- One or more electrons are added to

an atom of an element.

  • Oxidation- An electron (or more than one) is

removed from the atom of an element.

  • The atom may be by itself or part of a molecule
  • f a compound.
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SLIDE 69
  • Oxidation- An electron (or more than one)

is removed from the atom of an element.

  • Example of a half-reaction representing
  • xidation:
  • Fe à Fe 2+ + 2e-

26 protons 26 protons 26 electrons 24 electrons (“atom”) (“ion”)

Mining and Refining 1.C.10 p.101

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SLIDE 70
  • Reduction- One or more electrons are

added to an atom of an element.

  • Examples of a half-reactions representing

reduction:

  • Cl + 1e- à Cl-
  • Co2+ + 2e- à Co

Mining and Refining 1.C.10 p.101

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SLIDE 71

Mining and Refining 1.C.10 p.101

  • Historically “oxidation” referred to the chemical

combination of a substance with oxygen, as the term itself suggests.

  • Chemists now know that in nearly all cases in

which oxygen combines with another element or compound, oxygen removes one or more electrons from the other species.

  • By today's definition any reactant that causes a

species to lose one or more electrons is said to cause that species to be oxidized.

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SLIDE 72

Mining and Refining 1.C.10 p.101

  • Lab activity 1.B.12 p.74
  • Cu(s) + AgNO3(aq) à Cu(NO3)2(aq) + Ag(s)
  • Cu(s) + 2 Ag+ (aq) à Cu2+ (aq) + 2Ag(s)
  • Copper Silver ion Copper (II) ion Silver metal

metal Copper atom oxidized Silver ion reduced

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SLIDE 73

Mining and Refining 1.C.10 p.101

  • Cu(s) + 2 Ag+ (aq) à Cu2+ (aq) + 2Ag(s)

Copper Silver ion Copper(II) ion Silver metal metal

  • Also in that same lab:
  • Cu 2+ (aq) + Mg(s) à Cu(s) + Mg 2+ (aq)
  • Which is oxidized which is reduced?
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SLIDE 74

Mining and Refining 1.C.10 p.101

  • Cu 2+ (aq) + Mg(s) à Cu(s) + Mg 2+ (aq)
  • Which is oxidized which is reduced?
  • OIL RIG or LEO GER
  • Called Oxidation-Reduction reactions or redox

reactions

  • Total electrical charge on both sides of the

equation is the same.

  • Charges AND atoms must balance correctly.
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SLIDE 75

Mining and Refining 1.C.10

  • Cu 2+ (aq) + Mg(s) à Cu(s) + Mg 2+ (aq)
  • This isn’t a useful way to get copper metal

because you are “using up” another highly desirable metal…magnesium metal

  • Reducing Agent- A reacting chemical

species that serves as the source of electrons.

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SLIDE 76

Mining and Refining 1.C.10

Chart p. 75 (1.B.13)

  • Electrometallurgy- electric current is used to

supply electrons to metal ions-reducing them.

  • Pyrometallurgy- Heat is used—such as a blast

furnace---Coke(Carbon) and CO are common reducing agents

  • Hydrometallurgy- Treatment of ores and other

metal containing materials by reactants in water solution.

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SLIDE 77

Unit 1 Section D: Conservation and Chemical Equations

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SLIDE 78

1.D Conservation

Burning coal: + à C + O2 CO2

1 carbon atom 1 oxygen 1 carbon dioxide molecule molecule

Equation with chemical formulas: C(s) + O2(g) à CO2(g) Words: One carbon atom reacts with one oxygen molecule to produce one carbon dioxide molecule

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SLIDE 79

1.D.3 Example - Converting Copper

2 copper atoms + 1 oxygen à 2 copper(II) oxide molecule formula units Equation with chemical formulas: 2 Cu(s) + O2(g) à 2 CuO(s) Word equation: “2 copper atoms + 1 oxygen molecule react to produce (yields) 2 copper(II) oxide formula units”

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SLIDE 80

Accounting for Atoms

C3H8 + O2 à CO2 + H2O

1 propane 1 oxygen 1 carbon dioxide 1 water molecule molecule molecule molecule

Reactant side Product side 3 C atoms 1 C atom 8 H atoms 2 H atoms 2 O atoms 3 O atoms

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SLIDE 81

Polyatomic Ions

  • Sodium “salts”: Na+Cl-, Na+OH- = Na+(OH)-
  • Potassium salts: KCl, KOH
  • Magnesium salts: MgCl2, Mg(OH)2

Mg(OH)2 = Mg2+ OH- OH- atom inventory = 1 Mg atom 2 O atoms 2 H atoms

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SLIDE 82

Atom Inventory Practice

  • 1. AgNO3
  • 2. Sr(OH)2
  • 3. Al2(CO3)3
  • 4. (NH4)2S
  • 5. (NH4)3PO4
  • 6. Ca(HCO3)2
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SLIDE 83

1.D.5 Balancing Chemical Equations

  • Balancing equations is making the number
  • f atoms of each element the same on the

left and right sides of the equation. (Before and after the reaction occurs)

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SLIDE 84

1.D.5 Balancing Chemical Equations

  • Step ¡1-­‑ ¡Determine ¡the ¡correct ¡formulas ¡of ¡the ¡

reactants ¡and ¡products ¡FIRST. ¡These ¡formulas ¡ and ¡subscripts ¡can ¡not ¡be ¡changed ¡in ¡ balancing ¡the ¡equaRon. ¡

  • Example: ¡Hydrogen ¡gas ¡and ¡oxygen ¡gas ¡react ¡

to ¡produce ¡water: ¡

  • H2(g) ¡+ ¡O2(g) ¡à ¡H2O ¡(g) ¡
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SLIDE 85

1.D.5 Balancing Chemical Equations

  • Why ¡do ¡we ¡add ¡subscripts ¡to ¡H ¡and ¡O? ¡
  • H2(g) ¡+ ¡O2(g) ¡à ¡H2O ¡(g) ¡
  • Diatomic ¡Elements: ¡HONClBrIF ¡
  • Step ¡2-­‑ ¡Use ¡whole ¡numbers ¡(coefficients ¡in ¡

front ¡of ¡reactants ¡or ¡products) ¡to ¡balance ¡

  • elements. ¡
  • ¡ ¡2 ¡ ¡H2 ¡(g) ¡ ¡+ ¡__O2 ¡(g) ¡ ¡ ¡ ¡ ¡ ¡à ¡ ¡ ¡ ¡ ¡2 ¡H2O ¡(g) ¡
  • Balances ¡ ¡ ¡ ¡ ¡ ¡Stays ¡1 ¡ ¡ ¡ ¡ ¡ ¡ ¡ ¡ ¡ ¡Balances ¡Oxygen ¡ ¡ ¡ ¡ ¡
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SLIDE 86

1.D.5 Balancing Chemical Equations

  • Balance ¡1 ¡element ¡at ¡a ¡Rme, ¡going ¡back ¡and ¡

forth ¡between ¡sides ¡beginning ¡with ¡the ¡ element ¡furthest ¡to ¡the ¡lea. ¡

  • Step ¡3-­‑ ¡Check ¡the ¡number ¡of ¡atoms ¡of ¡

elements ¡on ¡both ¡sides. ¡ ¡

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SLIDE 87

1.D.5 Balancing Chemical Equations

Helpful information:

  • For elements occurring more than once on

either the left or the right --leave those elements to last.

  • Balance uncombined elements last.
  • If a polyatomic ion (example: NO3
  • ) is on

both sides, balance the whole ion, not each element in it.

2 Al (s) + 3 Pb(NO3)2 (aq) à 2 Al(NO3)3 (aq) + 3 Pb (s)

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SLIDE 88

1.D.5 Balancing Chemical Equations

  • If there are 2 of an atom (or ion) on one

side and 3 of the same atom or ion on the

  • ther side, make them both 6 by using a

coefficient of 3 in front of the first and 2 in front of the second.

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SLIDE 89

1.D.5 Balancing Chemical Equations

  • If ¡H2O ¡is ¡on ¡one ¡side ¡and ¡OH-­‑ ¡is ¡on ¡the ¡other ¡

side ¡(by ¡itself ¡or ¡as ¡part ¡of ¡an ¡ionic ¡ compound), ¡Rewrite ¡H2O ¡as ¡HOH ¡

  • Example: ¡ ¡

Na(s) ¡+ ¡H2O(l)à ¡NaOH(aq) ¡+ ¡H2(g) ¡

  • 2Na(s) ¡+ ¡2 ¡HOH(l) ¡ ¡à ¡2 ¡NaOH(aq) ¡+ ¡H2(g) ¡

¡

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SLIDE 90

1.D.5 Balancing Chemical Equations

  • A balanced chemical equation represents

the law of__________ ___ _____

  • Conservation of Matter
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SLIDE 91

Calculations with molar mass

moles to grams

  • A Si chip contains 0.05 mole Si. How many g Si are

in the chip?

  • molar mass of Si =

Set up the question: 0.05 mole Si = ? g Si

0.05 mole Si x 28.1 g Si = 1.41 g Si mole Si

28.1 g Si mole Si

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SLIDE 92

Calculations with molar mass

grams to moles

  • An iron bar is 16.8 g. How many moles Fe are in the

sample?

  • molar mass of Fe =

Set up the question: 16.8 g Fe = ? atoms Fe

16.8 g Fe x 1 mole Fe = 0.30 moles Fe 55.8 g Fe

55.8 g Fe mole Fe

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SLIDE 93

l If ¡you ¡need ¡to ¡make ¡25 ¡grams ¡of ¡H2O, ¡how ¡many ¡

grams ¡of ¡PbO ¡do ¡you ¡need ¡to ¡start ¡with? ¡

l This ¡can ¡be ¡determined ¡by ¡using ¡a ¡conversion ¡

factor… ¡

l Conversion ¡Factor ¡– ¡Relates ¡the ¡amount ¡of ¡one ¡

substance ¡in ¡a ¡chemical ¡reacRon ¡to ¡another ¡ substance ¡in ¡the ¡equaRon ¡

l Allows ¡us ¡to ¡convert ¡from ¡one ¡unit ¡to ¡another, ¡or ¡one ¡

substance ¡in ¡the ¡reacRon ¡into ¡another. ¡

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SLIDE 94

Conversion with a familiar concept...

How many minutes are in a year?

What information do you need to solve this? Write out the conversions that you will do.

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SLIDE 95

Grams ¡A ¡à ¡Moles ¡A ¡à ¡Moles ¡B ¡à ¡Grams ¡B ¡

Mole ¡Map ¡

A ¡“map” ¡for ¡sejng ¡up ¡conversion ¡factors ¡from ¡ ¡ chemical ¡reacRons ¡

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SLIDE 96

1.D.9 Conservation in the Community

  • The Earth is like a spaceship: the resources

“on board” are all that are available

– Renewable resources can be replenished by natural processes

  • water, air, fertile soil, plants, animals
  • as long as natural cycles are not disturbed

– Nonrenewable resources cannot be readily replenished

  • metals, natural gas, coal, petroleum
  • we are using petroleum faster than nature is making it
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SLIDE 97

1.D.9 How can we avoid depleting nonrenewable resources?

  • 1. Use less (“source reduction”)
  • 2. Find substitute materials with similar

properties; refurbish or reuse (e.g. used car parts, printer cartridges)

  • 3. Recycle