Building on 35 Years of Progress The Next 10 Years of Photovoltaic - - PowerPoint PPT Presentation

building on 35 years of progress the next 10 years of
SMART_READER_LITE
LIVE PREVIEW

Building on 35 Years of Progress The Next 10 Years of Photovoltaic - - PowerPoint PPT Presentation

Building on 35 Years of Progress The Next 10 Years of Photovoltaic Research at NREL Pioneers in Energy Lecture Purdue University Dr. Gregory M. Wilson Director, National Center for Photovoltaics National Renewable Energy Laboratory


slide-1
SLIDE 1

NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, operated by the Alliance for Sustainable Energy, LLC.

Pioneers in Energy Lecture Purdue University

  • Dr. Gregory M. Wilson

Director, National Center for Photovoltaics National Renewable Energy Laboratory Golden, Colorado - USA 17 July, 2013

Building on 35 Years of Progress – The Next 10 Years of Photovoltaic Research at NREL

slide-2
SLIDE 2

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

The National Center for Photovoltaics (NCPV) is the nation’s largest PV research institute focused on the scientific research and technology developments needed by industry to rapidly move PV forward as a mainstream source of low cost, reliable energy.

“That’s one small step for man,

  • ne giant leap for mankind.”

Neil Armstrong, July 20, 1969

  • Grid Parity by 2020.
  • $1/Watt installed PV (5MW scale),

50¢/Watt module price.

  • Equivalent to 5-6 cents per kilowatt hour.
  • Competitive with fossil energy.
  • Rapid growth without incentives.

Our Mission:

2

slide-3
SLIDE 3

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

1996 - National Center for Photo- voltaics (NCPV) is established. 1991 - SERI becomes the National Renewable Energy Laboratory (NREL).

  • 1974 - Solar Energy

Research Institute (SERI) is chartered.

  • 1977 - SERI begins
  • peration.
  • 1980 – President

Reagan cuts SERI budget by 90%.

National Renewable Energy Laboratory

3

slide-4
SLIDE 4

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

NREL - Part of DOE’s National Lab Complex

4

slide-5
SLIDE 5

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

NREL ¡Snapshot ¡

  • 35+ ¡years ¡of ¡accomplishments ¡

and ¡market ¡impact ¡in ¡energy ¡ efficiency ¡and ¡renewable ¡ energy ¡technology ¡R&D ¡

  • 2,419 ¡staff ¡(as ¡of ¡12/2012) ¡

‒ 1,634 ¡employees ¡ ‒ 785 ¡non-­‑payroll ¡

  • $329.5M ¡total ¡funding ¡in ¡FY12 ¡
  • $309M ¡projected ¡for ¡FY13 ¡
  • More ¡ ¡than ¡350 ¡partnerships ¡
  • InternaSonal ¡benchmark ¡for ¡

sustainability ¡ ¡

5

slide-6
SLIDE 6

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

Scope of Mission

Energy Efficiency Renewable Energy Systems Integration Market Focus

Residential Buildings Commercial Buildings Personal and Commercial Vehicles Solar Wind and Water Biomass Hydrogen Geothermal Grid Infrastructure Distributed Energy Interconnection Battery and Thermal Storage Transportation Private Industry Federal Agencies Defense Dept. State/Local Govt. International

6

slide-7
SLIDE 7

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY 7

NCPV: Helping seed the PV technologies of tomorrow

CIGS/CdTe ¡ Silicon ¡

SERI begins

  • peration

1977

Record Cell Efficiencies

SERI becomes the National Renewable Energy Laboratory

III-­‑V ¡ CIGS/CdTe ¡ Silicon ¡

SERI begins

  • peration

1991

NCPV: Helping seed the PV technologies of tomorrow

Record Cell Efficiencies

SERI becomes the National Renewable Energy Laboratory SERI begins

  • peration

National Center for Photovoltaics (NCPV) is established

NCPV

III-­‑V ¡ CIGS/CdTe ¡ Silicon ¡

1996

NCPV: Helping seed the PV technologies of tomorrow

Record Cell Efficiencies

III-­‑V ¡ OPV ¡ CIGS/CdTe ¡ Silicon ¡

SERI becomes the National Renewable Energy Laboratory SERI begins

  • peration

National Center for Photovoltaics (NCPV) is established

NCPV Today

NCPV: Helping Seed the PV Technologies of Tomorrow

Record Cell Efficiencies

2013

7

slide-8
SLIDE 8

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

The NCPV Today

8

slide-9
SLIDE 9

NCPV Competencies

Measurements ¡& ¡ Characteriza8on ¡ Silicon ¡ ¡ III-­‑V ¡

¡

Module ¡Reliability ¡& ¡ Systems ¡Engineering ¡

PV ¡Technologies ¡ PV ¡Cross-­‑CuCng ¡R&D ¡

Thin ¡Film ¡PV ¡ CIGS ¡/ ¡CdTe ¡/CZTS ¡ OPV/TCO ¡ ¡ Na8onal ¡Center ¡for ¡Photovoltaics ¡ (NCPV) ¡

Extensive Capabilities and PV Experience Under One Roof

Material Synthesis • Device Processing • Device Design • Device Modeling • Measurements & Characterization • A Highly Trained Technical Staff

1 µm

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY 9

slide-10
SLIDE 10

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

Organization Structure – Directorate Level

10 Last Updated: June 20, 2013

National Center for Photovoltaics

Greg Wilson, Center Director

(Paula Robinson, Senior Administrative Specialist)

Materials and Chemical Science & Technology – 5F00

William Tumas

Associate Laboratory Director

(Katarina Nelson, Acting Executive Assistant)

M&C Core Support and Partnering

Pete Sheldon, Deputy Director

(Audrey Carapella, Senior Administrative Specialist)

NCPV Business Manager – Kaitlyn VanSant

(Paula Robinson, Sr. Administrative Specialist)

NCPV Business Data – Morgan Curley

(Audrey Carapella, Sr. Administrative Specialist)

Core Support Manager – Brian Keyes

(Sandy Padilla, Administrative Professional)

Analytical Microscopy

Mowafak Al-Jassim, Group Manager

(Paula Robinson, Sr. Administrative Specialist)

Cell & Module Performance

Keith Emery, Group Manager

(Sandy Padilla, Administrative Professional)

Electro-Optical Characterization

Dean Levi, Group Manager

(Audrey Carapella, Sr. Administrative Specialist)

Engineering and Informatics

Brent Nelson, Group Manager

(Audrey Carapella, Sr. Administrative Specialist)

Surface Analysis

Glenn Teeter, Group Manager

(Audrey Carapella, Sr. Administrative Specialist)

PV Technologies and Reliability

Greg Wilson, Center Director

(Paula Robinson, Senior Administrative Specialist)

III-V Multijunction Photovoltaics

Daniel Friedman, Group Manager

(Kristen Kennedy, Administrative Professional)

Module Reliability & Systems Engineering

Sarah Kurtz, Group Manager

(Sandy Padilla, Administrative Professional)

CdTe Photovoltaics

Wyatt Metzger, Group Manager

(Shirley Contreras, Administrative Professional)

CIGS/CZTS

Kannan Ramanathan, Section Supervisor

CIGS/CZTS

Rommel Noufi, Group Manager

(Shirley Contreras, Administrative Professional)

Solar Resources and Forecasting

Tom Stoffel, Group Manager

(Sandy Padilla, Administrative Professional)

Silicon

Pauls Stradins, Group Manager

(Shirley Contreras, Administrative Professional)

Program Integration

Larry Kazmerski Marisa Howe

Chemical and Materials Science Center

Jao van de Lagemaat, Acting Center Director

(Katarina Nelson, Administrative Specialist)

Hydrogen Technology and Fuel Cells

Bryan Pivovar, Group Manager

(Consuelo Montaño, Administrative Professional)

Chemical & Nanoscale Sciences

Nathan Neale, Acting Group Manager

(Nicole Campos, Administrative Professional)

Materials Science

Angelo Mascarenhas, Group Manager

(Nicole Campos, Administrative Professional)

Theoretical Materials Science

Suhuai Wei, Group Manager

(Consuelo Montaño, Administrative Professional)

Process Technology and Advanced Concepts

Phil Parilla, Acting Group Manager

(Kristen Kennedy, Administrative Professional)

Research Fellows Council

David Ginley, Strategic Science Advisor

CMS Associated Research Fellows

Garry Rumbles John Turner Arthur Nozik, Emeritus

NCPV Associated Research Fellows

Howard Branz, Assn in DC Tim Coutts, Emeritus

National Center for Photovoltaics

  • Broad TRL span, mostly focused on

applied science.

  • EERE is primary sponsor

Chemical and Materials Science Center

  • Narrow TRL span,

mostly focused on basic science.

  • Office of Science is

primary sponsor

slide-11
SLIDE 11

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

World Energy Consumption

The earth’s population currently consumes ~21 trillion kWhrs of electricity, with ~2/3 generated using fossil fuels.

Source: 2010 DOE-EIA International Energy Outlook

Trillion Kilowatt-hours Trillion Kilowatt-hours

11

slide-12
SLIDE 12

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

Energy & CO2 - 21st Century Grand Challenges

  • The CO2 emissions from

fossil fuel combustion have resulted in unprecedented new problems:

− Global climate change with associated changes in rainfall patterns, average surface temperatures and polar ice cover. − Increased ocean CO2 content with a corresponding increase in acidity.

  • Photovoltaic energy

production is a rapidly scalable, non-nuclear alternative that is large enough to address the problems we are facing.

Source: NASA-GISS

12

slide-13
SLIDE 13

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

PV Energy for Planet Earth in 2020

2020 “new policy” scenario: PV farm in the U.S. SW 425 mi on a side supplies all of the world’s energy needs.

13

slide-14
SLIDE 14

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

NCPV Conversion Technology R&D Portfolio

System Development & Manufacturing

Market Transformation Component Prototype & Pilot Scale Production Device & Process Proof of Concept Manufacturing-Oriented Design & Pilot Production Commercial Production Demonstration Commercial Replication

Market Transformation Component Prototype & Pilot Scale Production Device & Process Proof of Concept

Material & Device Concepts

Material & Device Concepts

System Development & Manufacturing

Prototype System Development Manufacturing- Oriented Design & Pilot Prod. Commercial Production Demonstration Commercial Replication

PV TECHNOLOGY PIPELINE

NCPV Conversion Technology R&D Overview:

Ü III-V Multijunction Ü Wafer Si Ü Thin Si Ü CdTe Ü CIGS Ü Organic PV (OPV)

Highest potential η, > 50% Most common technology, ~25% 1-J η today ** Potential for low cost and > 20% η Lowest cost in HVM today, potential for > 20% η Can be flexible, potential for > 20% η Flexible, potentially very low cost

14

slide-15
SLIDE 15

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

NCPV Research Portfolio

System Development & Manufacturing

Market Transformation Component Prototype & Pilot Scale Production Device & Process Proof of Concept Manufacturing-Oriented Design & Pilot Production Commercial Production Demonstration Commercial Replication

Market Transformation Component Prototype & Pilot Scale Production Device & Process Proof of Concept

Material & Device Concepts

Material & Device Concepts

System Development & Manufacturing

Prototype System Development Manufacturing- Oriented Design & Pilot Prod. Commercial Production Demonstration Commercial Replication

PV TECHNOLOGY PIPELINE

Other NCPV Research Areas:

Ü CZTS Ü III-V 1J via HVPE Ü Novel PV Absorbers Ü Novel TCO

Earth abundant replacement for CIGS Potential path to low-cost, 1-sun III-V cells Search via Inverse Design Search for better TCO materials

15

slide-16
SLIDE 16

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

Best Research Cell Efficiencies

16

16

slide-17
SLIDE 17

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

PV Market: cSi now with 91%

17 17

Source: PHOTON Consulting, Solar Annual 2013

slide-18
SLIDE 18

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

The cSi PV Business Problem

  • Prices at or below cost

across the entire cSi PV value chain. Situation not predicted to improve in meaningful timeframe.

  • Required capital investment

is high but returns too low to attract investment from capital markets.

  • Once strong cSi cell and

module companies in China are beginning to experience problems.

18

slide-19
SLIDE 19

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

The cSi PV Business Problem

  • Prices at or below cost

across the entire cSi PV value chain. Situation not predicted to improve in meaningful timeframe.

  • Required capital investment

is high but returns too low to attract investment from capital markets.

  • Once strong cSi cell and

module companies in China are beginning to experience problems.

19

è Prices across the cSi PV supply chain will eventually rise to reflect real manufacturing costs.

slide-20
SLIDE 20

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

PV Workhorse – 1J Silicon

Source: Stefan Glunz presentation, NREL Si Workshop in Vail, CO, July, 2012 20

  • Typical Chinese cSi

cells today are p-type CZ Si diffused junction cells with Al BSF with η ≈ 18% resulting in roughly 16% modules.

  • SunPower’s best

production IBC cell has η > 24%.

  • Panasonic recently

announced a new record cSi 24.7% cell based on their heterojunction technology.

é é

slide-21
SLIDE 21

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

Cost Potential - Silicon PV

Source: Stefan Glunz presentation, NREL Si Workshop in Vail, CO, July, 2012 21

Path to SunShot Goal

  • Wafer cSi – May not be possible with single junction cells
  • n Si wafers cut from ingots. Higher efficiency tandem

cells with low incremental cost are emerging as a new research focus.

  • Wafer mcSi – Further reductions in costs possible through

improvements in poly cost structure (UMG), crystal growth (DSS) and wafering. Still, most believe best that can be achieved with cut wafers is ~60¢/W.

  • Thin Absorber Si – Goal could be achieved if current high

efficiency wafer cell performance can be duplicated on lower cost “kerfless” Si absorber layers.

slide-22
SLIDE 22

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

Limitation of Conventional Solar Cells

Conventional (single-junction) Cell, e.g. silicon… … has unavoidable losses which put a fundamental ceiling on cell efficiency… … when applied to the sun’s broad spectrum

Photon energy (eV) 1 4 0.5 Photon Energy Conversion Efficiency photon not absorbed excess energy lost as heat Eg

the sun is not a laser!

22

slide-23
SLIDE 23

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

Capturing More Photons - Multijunctions

Photon energy (eV) 1 4 0.5

Multijunctions provide much higher efficiencies than conventional cells

3 2 1 Junction bandgaps (eV) 5 4 3 2 1 number of junctions 60 55 50 45 40 35 cell efficiency (%) Efficiency Band gaps series 4J series+1J

AM1.5D, 1000x, 300K

23

slide-24
SLIDE 24

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

Next Gen Si PV - Tandem Cells

Source: Stefan Glunz presentation, NREL Si Workshop in Vail, CO, July, 2012 24

Top Cell - TBD >1.6 eV Bottom Cell - Si 1.1 eV

? ¡

  • Path to > 30% efficiency for

Si wafer based cells.

  • Top cell requirements:
  • Lattice match to Si
  • CTE match to Si
  • Target band gap
  • Top cell optical properties
slide-25
SLIDE 25

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

dNphdλ (a.u.) 1 1.5 2 3 4 0.7 0.8 0.9 photon energy (eV)

G173 global spectrum

InP ¡substrate ¡ Ga0.47In0.53As ¡juncSon ¡(0.74 ¡eV) ¡ GaInAsP ¡juncSon ¡(1.05 ¡eV) ¡ GaAs ¡juncSon ¡(1.42 ¡eV) ¡ Ga0.5In0.5P ¡juncSon ¡(1.85 ¡eV) ¡ p-­‑GaN ¡ InGaN/GaN ¡MQW ¡(2.65 ¡eV) ¡ n-­‑GaN ¡ Ga.5In.5P 1.85 eV GaAs 1.42 eV grade Ga.7In.3As 1.0 eV grade handle Ga.45In.55As 0.7 eV

48% in 2014 52% in 2016

25

III-V Multijunctions – Future Plans

Path to SunShot Goal

  • III-V multijunctions cells will continue to be expensive

given the very sophisticated process and expensive materials required.

  • Still, system cost potential for CPV probably $1.25/W in

high DNI areas.

  • Cost will be low enough to grow CPV market in spite of

missing $1/W target.

slide-26
SLIDE 26

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

What About Thin Films?

System Development & Manufacturing

Market Transformation Component Prototype & Pilot Scale Production Device & Process Proof of Concept Manufacturing-Oriented Design & Pilot Production Commercial Production Demonstration Commercial Replication

Market Transformation Component Prototype & Pilot Scale Production Device & Process Proof of Concept

Material & Device Concepts

Material & Device Concepts

System Development & Manufacturing

Prototype System Development Manufacturing- Oriented Design & Pilot Prod. Commercial Production Demonstration Commercial Replication

PV TECHNOLOGY PIPELINE

26

slide-27
SLIDE 27

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

CdTe PV Research: GBs, Defects & Doping

27

Objective: Identify the path to a 20% production cell. To get there we need to significantly increase CdTe carrier concentration (1014 cm-3) and lifetime (1-2 ns). Approach:

  • Learn how to dope >1x1016 with single crystals – MBE and novel

post-deposition treatments.

  • Improve lifetime to >10 ns - Deconvolute surface, bulk, and grain-

boundary recombination. Work backwards from high lifetime material.

  • Understand GBs - Deposit films with large grain size. Characterize

how potential, lifetime, chemistry changes at GB.

  • Answer fundamental questions – Does CdCl2 create a Voc limit?
slide-28
SLIDE 28

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

CdTe: GBs and Recombination

  • Currently working to catalog hundreds of GBs in EBSD, then collecting CL

spectra from each of these GBs to statistically evaluate the role of GBs on recombination.

  • ∑3 GBs are preferable to other GBs.
  • Statistics will be required to distinguish differences between ∑5, ∑7, ∑9, and

∑11 GBs.

  • Work on non CSL GBs is in progress.

Intensity (Counts)

∑11 GB spectra

1.2 1.4 1.6 1.8 50 100 150 200 250 300

Photon Energy (eV) 10 GBs Range=71-290

28

slide-29
SLIDE 29

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

CdTe: GBs and Recombination

  • Currently working to catalog hundreds of GBs in EBSD, then collecting CL

spectra from each of these GBs to statistically evaluate the role of GBs on recombination.

  • ∑3 GBs are preferable to other GBs.
  • Statistics will be required to distinguish differences between ∑5, ∑7, ∑9, and

∑11 GBs.

  • Work on non CSL GBs is in progress.

Intensity (Counts)

∑11 GB spectra

1.2 1.4 1.6 1.8 50 100 150 200 250 300

Photon Energy (eV) 10 GBs Range=71-290

Path to SunShot Goal

  • Current CdTe HVM production costs probably around

75¢/W with average panel efficiencies around 12%.

  • Increasing panel efficiency to 18% with minimal increase

in unit manufacturing cost is possible and would move panel cost to <40¢/W.

29

slide-30
SLIDE 30

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

CdTe: Recent Progress

Major progress in champion cell efficiencies at both First Solar and GE

  • ver the last 2 years provides strong evidence that CdTe production

module efficiencies have the potential to reach 18%.

30

June, 2013 - GE, 19.6% February, 2013 - FSLR, 18.7% October, 2012 - GE, 18.3% June, 2011 - FSLR, 17.3%

slide-31
SLIDE 31

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

CIGS PV Research: Enable Low Cost HVM

Absorber band gap (eV)

Theoretical limit

Efficiency (%)

Increase η across CIGS band-gap range Fast Zn(S,O) buffer layer processes Fast, 2-step selenization process (10X faster than state of the art)

31

Approach

  • Demonstrate higher η device (23%)

and larger process window (higher evap process T, reduced Ga content).

  • Optimize layer stack enabling much

faster selenization process (Se vapor).

  • Optimize emitter layer and process

(CBD vs. sputter ZnS:O).

  • Continue to investigate impact of

CIGS defects on Voc and FF. I

slide-32
SLIDE 32

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

CIGS PV Research: Enable Low Cost HVM

Absorber band gap (eV)

Theoretical limit

Efficiency (%)

Increase η across CIGS band-gap range Fast Zn(S,O) buffer layer processes Fast, 2-step selenization process (10X faster than state of the art)

32

Approach

  • Demonstrate higher η device (23%)

and larger process window (higher evap process T, reduced Ga content).

  • Optimize layer stack enabling much

faster selenization process (Se vapor).

  • Optimize emitter layer and process

(CBD vs. sputter ZnS:O).

  • Continue to investigate impact of

CIGS defects on Voc and FF. I

Path to SunShot Goal

  • Optimization of NREL CIGS process leads to ~50¢/W

with 13% - 14% module efficiencies.

  • Improvements in production cell efficiency with low to

zero incremental cost is likely and should drive panel cost to 40¢ - 50¢ per Watt.

slide-33
SLIDE 33

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

NCPV Conversion Technology R&D Portfolio

System Development & Manufacturing

Market Transformation Component Prototype & Pilot Scale Production Device & Process Proof of Concept Manufacturing-Oriented Design & Pilot Production Commercial Production Demonstration Commercial Replication

Market Transformation Component Prototype & Pilot Scale Production Device & Process Proof of Concept

Material & Device Concepts

Material & Device Concepts

System Development & Manufacturing

Prototype System Development Manufacturing- Oriented Design & Pilot Prod. Commercial Production Demonstration Commercial Replication

PV TECHNOLOGY PIPELINE

NCPV Conversion Technology R&D Overview:

Ü III-V Multijunction Ü Wafer Si Ü Thin Si Ü CdTe Ü CIGS Ü Organic PV (OPV)

Highest potential η, > 50% Most common technology, potential for > 25% η Potential for low cost and > 20% η Lowest cost in HVM today, potential for > 18% η Can be flexible, potential for > 20% η Flexible, potentially very low cost

CZTS ¡

33

slide-34
SLIDE 34

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

CZTS Thin Film Solar Cells

100’s meV potential barrier at grain boundaries, like CIGS.

  • Some grains show

high collection and flat response.

  • Some grains nearly

inactive.

  • TEM studies in

literature also indicate some grain- to-grain nonuniformity. 1 µm Large grains, Compact film, like CIGS.

Achieved ¡9.2% ¡cell ¡efficiency ¡

Project ¡started ¡in ¡FY11 ¡made ¡rapid ¡progress ¡in ¡less ¡than ¡two ¡years ¡

34

slide-35
SLIDE 35

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

NCPV Conversion Technology R&D Portfolio

System Development & Manufacturing

Market Transformation Component Prototype & Pilot Scale Production Device & Process Proof of Concept Manufacturing-Oriented Design & Pilot Production Commercial Production Demonstration Commercial Replication

Market Transformation Component Prototype & Pilot Scale Production Device & Process Proof of Concept

Material & Device Concepts

Material & Device Concepts

System Development & Manufacturing

Prototype System Development Manufacturing- Oriented Design & Pilot Prod. Commercial Production Demonstration Commercial Replication

PV TECHNOLOGY PIPELINE

NCPV Conversion Technology R&D Overview:

Ü III-V Multijunction Ü Wafer Si Ü Thin Si Ü CdTe Ü CIGS Ü Organic PV (OPV)

Highest potential η, > 50% Most common technology, potential for > 25% η Potential for low cost and > 20% η Lowest cost in HVM today, potential for > 18% η Can be flexible, potential for > 20% η

35

Flexible, potentially very low cost

slide-36
SLIDE 36

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

OPV Materials Design and Characterization

Theory - DFT

  • W. Braunecker, Chem. Mater. DOI:10.1021/cm2038427
  • Planar structure of BDT-TPD leads to ordered films and longer photocarrier lifetimes
  • BDT-CID shows an amorphous structure consistent with calculations

Structure - XRD

Amorphous Crystalline

Charge Generation

Time Resolved Microwave Conductivity (TRMC)

S N O O R S S OR RO n

TPD$BDT

S N O O R S S OR RO n

TID$BDT

Combinatorial Computation & Theory à Synthesis à Characterization à Device optimization

36

slide-37
SLIDE 37

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

  • Grid Parity by 2020.
  • $1/Watt installed PV (5MW scale),

50¢/Watt module price.

  • Equivalent to 5-6 cents per kilowatt hour.
  • Competitive with fossil energy.
  • Rapid growth without incentives.

37

Review - SunShot Goal

slide-38
SLIDE 38

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

Towards SunShot

38

slide-39
SLIDE 39

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

Cost Forecast – First Solar

FSLR plans to cut their costs nearly in half over the next 4 years, again.

39

slide-40
SLIDE 40

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

Cost Forecast - SunEdison

SunEdison has a cost roadmap similar to FSLR’s.

40

slide-41
SLIDE 41

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

Beyond SunShot

So what will be the impact of 1 or more PV conversion technologies achieving the SunShot goal?

  • Utilities can and will continue to limit PV penetration around

the world until the PV business model works for them…

è PV market growth will continue to be constrained without breakthroughs related to cost effective energy storage.

  • PV system reliability will continue to be closely watched by

the project finance investment community…

è Module failures above some critical threshold could severely limit willingness to raise capital for new projects.

  • If the above problems are managed then PV terawatt

scalability will become the next major challenge…

è Earth abundant materials and energy payback time will determine which PV conversion technologies win market share.

41

slide-42
SLIDE 42

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

Summary

  • Great world-wide progress over the last 10 years in

demonstrating multiple PV conversion technologies.

  • Crystalline Si PV based on both cSi and mcSi wafers will

continue to dominate the industry for a number of years but more efficient use of high purity Si must be part of Si PV’s terawatt scale future.

  • In spite of current headwinds, polycrystalline thin film

technologies continue to have the potential to compete effectively with mcSi PV technology over the longer term.

  • Module efficiency, energy payback and earth abundance
  • f materials will become increasingly important as PV

moves “beyond SunShot” towards the terawatt scale.

42

slide-43
SLIDE 43

Innova&on ¡for ¡Our ¡Energy ¡Future ¡

NATIONAL RENEWABLE ENERGY LABORATORY

NREL PDIL Collaboration Methodology

43

Projects that are selected and considered will have the following high- level expectations:

  • Leadership in scientific discovery and innovation
  • Linkage of discovery/innovation to product development
  • Impact on PV manufacturing-industry needs
  • Impact on DOE programmatic goals, e.g. Price Parity and other
  • Strategic value to the Lab
  • Reasonable time frame for impact (with some sense of urgency)

Thank You