BIOREMA project Annarita Baldan Chair of BIOREMA BIOREMA workshop, - - PowerPoint PPT Presentation

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BIOREMA project Annarita Baldan Chair of BIOREMA BIOREMA workshop, - - PowerPoint PPT Presentation

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BIOREMA project Annarita Baldan Chair of BIOREMA BIOREMA workshop, 27 October 2010, Brussels, Belgium Page 1 Outline Project overview Conclusions Project activities BIOREMA project Role of Metrology BIOREMA ILCs & CRMs Page 2

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BIOREMA project

Annarita Baldan Chair of BIOREMA

BIOREMA workshop, 27 October 2010, Brussels, Belgium

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Outline

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BIOREMA project

Project overview Project activities Role of Metrology & CRMs BIOREMA ILCs Conclusions

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Project details

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REference MAterials for BIOfuel specifications Call:

  • FP7 Cooperation Work Programme:

Theme 5 / Energy

  • Coordination and Support Action
  • Grant agreement 219081

Duration: 24 months Start date: 27 November 2008

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Project objectives

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 Development of (Certified) Reference Materials: homogeneus and stable biofuel test materials (sugar cane bioethanol – E100 and rape seed FAME – B100) with well characterized reference values  Information on current quality of measurement results by carrying out interlaboratory comparisons with these

  • materials. The ILCs are organized for field

laboratories specialized in the analysis of biofuels

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Project background

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 Lack of (Certified) Reference Materials for biofuels  Outcome of Tripartite Task Force (BR, EU, USA)

Proposal for compatible international documentary standards, “White Paper on International compatible Biofuel Standards”, December 2007  Classification of biofuels specifications (A,B and C)

 Come into force of EU RED (2009/28/EC) and EU FQD (2009/30/EC)

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BIOREMA project partners

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Role of National Metrology Institutes (NMIs)

Providing SI traceability to measurement results

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NL UK US CN

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Why CRMs

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Traceability Method validation QA Traceability

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BIOREMA activities

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Production of (Certified) Reference Materials Homogeneity

  • f batch

Characterizati

  • n with

reference methods Short and long term stability Reference value assignment

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Parameters under investigation

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Bioethanol FAME FAME 1 Sulphur 1 Water 13 Triolein 2 Copper 2 Methanol 14 Ester content 3 Iron 3 Sodium 15 Linolenic acid methylester 4 Sodium 4 Potassium 16 Palmitic acid methylester 5 Sulphate 5 Sulphur 17 Stearic acid methylester 6 Chloride 6 Density 18 Sum of isomers C18:1, C18:2, C18:3 7 Ethanol 7 Viscosity 19 FAME with ≥ 4 double bonds 8 Water 8 Total glycerol 20 Oxidative stability 9 Density 9 MAG, DAG, TAG 21 Flash point 10 Electrolytic conductivity 10 Free glycerol 22 Acid value 11 Acidity 11 Monolein 23 Iodine value 12 pHe 12 Diolein

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BIOREMA activities

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Interlaboratory Comparisons Production of (Certified) Reference Materials Inventory “measurement

  • f biofuels”

Homogeneity

  • f batch

Characterizati

  • n with

reference methods Short and long term stability Characterized batch available for 30 labs Call for participation worldwide Reference value assignment Measurement and reporting

  • f the results

Measurement methods for traditional / advanced biofuels Evaluation of the measurement results Dissemination/ discussion of results Workshop October 2010 Reference materials for traditional / advanced biofuels

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ILCs fact-sheet

Call for participation

 Maximum 30 participants per biomaterial  More than 100 labs were contacted  call closed: end of April 2010

Interaboratory comparison

 Sample dispatch: 2nd half of May 2010

(one participant did not receive the samples)

 Submission results: 2 July 2010

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Bioethanol Biodiesel Remarks Applications 15 25 10 applied for both ILCs Submitted results 13 23 1 lab did not receive the samples 2 did not report results

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ILCs participants

Geographical distribution:  Europe: Austria, Belgium, Estonia, France, Germany, Greece, Italy, Spain, Sweden, The Netherlands, Turkey, United Kingdom  America: Brazil, Canada,  Asia: India, Singapore, Thailand  Africa: -  Oceania: -

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Europe 69% America 19% Asia 12%

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Follow up of BIOREMA

 Parallel worldwide “ Pilot Comparison” on determination of ethanol and water content in bioethanol fuel (May - Sep 2010)

 Use of BIOREMA Bioethanol material  Comparison of NMIs measurement capabilities  Participants: Germany, France, The Netherlands, Turkey, Singapore, Thailand, China, Japan, United States, Brazil, Argentina, Kenya and South Africa

 Begin (June 2010) of a 3 years research project “Metrology for liquid biofuels” under the European Metrology Research Program (EURAMET)

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Conclusions

 Positive example of collaboration among metrology institutes and useful exercise for establishing a common approach to the production of biofuels materials  Production of biofuels (Certified) Reference Materials has been demonstrated. However, for several specifications, the assignment of an SI traceable value still need further research due to the complexity of the material.  Conclusions on the quality of the measurement results

  • btained by biofuel testing laboratories in the

interlaboratory comparison (ILC) will be drawn (together) at the end of this workshop

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Thank you for your attention! I look forward to a fruitful discussion of the ILC results!!

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