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Review of Water and Effluent Management Alunorte Environmental Consultancy and Engineering Barcarena/PA +55 11 3217 6300 | www.sgwservices.com Investigation | Remediation | Audits | Permitting | Consultancy Scope and Objectives Independent


  1. Review of Water and Effluent Management Alunorte Environmental Consultancy and Engineering Barcarena/PA +55 11 3217 6300 | www.sgwservices.com Investigation | Remediation | Audits | Permitting | Consultancy

  2. Scope and Objectives ✓ Independent Assessment of the Refinery Water and Effluent treatment management system. ✓ Focus on the intense rain event occurred on February 16 th and 17 th that caused flood at Barcarena region. ✓ This review is preliminary and the works are ongoing. ✓ The objective is to verify if the intense rain event resulted in environment contamination related to Alunorte leakages or operational and procedural failures.

  3. Rain events on Feb 16 th and 17 th 224mm rain in 10 hours ✓ There was no overflow at the solid waste basins - DRSs ✓ There was a Flood in Area 45 - The rainwater leakage occurred by a cracked deactivated pipe. Visual inspections and soil pH measurements results did not identify environmental alterations. There was no overflow towards the Murucupi River. There are no evidences of environmental impacts in the river due to the deactivated pipe leakage. ✓ Untreated rainwater was discharged into the Pará River by the Canal Velho in order to avoid WWTP basins overflowing. The discharge also received alkaline effluents from the process and there was a pH control and neutralization during this discharge.

  4. Water Balance Simulation performed by SGW SGW performed a Water Balance simulation of the days16 and 17 ✓ WWTP basins volumes did not have capacity to handle the unusual rainfall event; ✓ DRSs capacities sufficient WWTP Basins Capacity DRS1 Basins Capacity DRS2 Basins Capacity 80 000 1 000 000 600 000 900 000 60 000 500 000 800 000 Basins capacity DRS2 (m3) Basins capacity DRS1 (m3) Basins capacity WWTP (m3) 40 000 700 000 400 000 20 000 600 000 0 300 000 500 000 1 2 3 4 5 6 7 8 9 1011121314151617181920212223242526 (20 000) 400 000 200 000 300 000 (40 000) Area 45 Discharge to 200 000 100 000 (60 000) pumps Canal Velho 100 000 stopped (80 000) 0 0 1 3 5 7 9 11 13 15 17 19 21 23 25 (100 000) 1 2 3 4 5 6 7 8 9 1011121314151617181920212223242526 Hours Hours Hours

  5. Sampling As the existing data was not enough for a precise analysis of the Alunorte’s contamination potential, SGW carried out a sampling in the environmental: Surface water (Para and Murucupi rivers), effluents and mining pipeline; Soil, Bauxite, Coal, Ashes, Red Mud. Well water from the Bom Futuro, Burajuba and Vila Nova communities Preliminary results indicate impact absence on water bodies and point to region’s natural anomalies (Al and Fe)* The metals results are n/d or below the legal levels in the community wells - except 1 spot (Al = 220 ppb - Standard 200 ppb). *Master thesis – Multielementary Regional Geochemistry applied to the Human and Environmental Health Fields in the Continental Portion of the Leaf AS.22-X-D – Belém – Northeast Region of Pará – Volume I; Author: Eduardo Paim Viglio, Belém – 2008; Pará University – Geosciences Institute

  6. Conclusions ✓ Leakage from Sump 45 is not sufficient to cause significant environmental contamination. ✓ Emergencial discharge into Canal Velho – mainly stormwater – no significant impact in the Pará river ✓ Volumes discharge x river flow ✓ There was no overflow at the solid waste basins - DRSs ✓ Environment Diagnostic and monitoring expansion. ✓ The metals results are n/d or below the legal levels in the community wells - except 1 spot (Al = 220 ppb - Standard 200 ppb) – source not clear ✓ Preliminary results yet, so far not indicating any significant impacts

  7. Environmental Consultancy and Engineering contatos@sgw.com.br | www.sgwservices.com Investigation | Remediation | Audits | Permitting | Consultancy

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