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Optimal Timing of Preventive Maintenance for Addressing Environmental Aging Charles J. Glover Texas A&M University / TTI Artie McFerrin Department of Chemical Engineering MnROAD Test Facility July 23, 2008 OUTLINE Background Needs


  1. Optimal Timing of Preventive Maintenance for Addressing Environmental Aging Charles J. Glover Texas A&M University / TTI Artie McFerrin Department of Chemical Engineering MnROAD Test Facility July 23, 2008

  2. OUTLINE • Background • Needs • Needs being addressed • Needs - Not being addressed well enough • Combining efforts nationally • Suggested emphasis of this PFS

  3. THE PROBLEM • Binder oxidation and hardening DO occur extensively beyond one inch down into the pavement • Mixture performance declines significantly with binder oxidation • Effective maintenance programs will inhibit binder oxidation in pavement or rejuvenate in- place binder - Is this possible?

  4. BACKGROUND IN SERVICE: BINDERS OXIDIZE, BECOME STIFFER AND LESS DUCTILE…A RELENTLESS PROCESS! 40.0 35.0 30.0 25.0 Failure Stress Stress 20.0 Increasing Oxidation 15.0 10.0 5.0 0.0 Elongation 0 2 4 6 8 10

  5. BACKGROUND TxDOT 0-1872

  6. BACKGROUND TxDOT 0-4688 AS BINDERS OXIDIZED, MIXTURE FATIGUE RESISTANCE DECLINES…

  7. BACKGROUND TxDOT 0-4688 BINDER OXIDATION MODEL CAN BE USED TO ESTIMATE HARDENING RATE IN PAVEMENT

  8. BACKGROUND TxDOT 0-4688 THROUGHOUT SERVICE, BINDER HARDENING PROCEEDS IN A WAY THAT DEPENDS DEPENDS ON CLIMATE AND THE PHYSICAL STRUCTURE OF THE MIXTURE

  9. BACKGROUND TxDOT 0-4688 ACCESSIBLE AIR VOIDS IS ONE OF THE KEY MIXTURE PARAMETERS THAT SIGNIFICANTLY AFFECTS BINDER OXIDATION

  10. BACKGROUND TxDOT 0-5091

  11. TxDOT 0-5091 - SUMMARY - • Effects of fog seals on pavement durability appear to be minimal, with respect to sealing or rejuvenation • Fog seals did not appear to penetrate below the pavement surface • The aging rates of asphalt binders are decreased by very low accessible air voids

  12. BACKGROUND - SUMMARY - • Binder oxidation and hardening DO occur extensively beyond one inch down into the pavement • Mixture performance declines significantly with binder oxidation • Effective maintenance program would inhibit binder oxidation in pavement and/or rejuvenate in-place binder • Evidence suggests that sealants may affect binders…or may not

  13. RESEARCH NEEDS • Improved Understanding of binder oxidation and hardening rates in pavements (model) – Improved measurements of mixture air voids morphology: pore size, spacing, AAV – Improved understanding of air permeation through pavements • Improved understanding of the impact of binder hardening on mixture performance (e.g. fatigue) • Field measurements of binder oxidation in pavements and maintenance treatment effectiveness

  14. CURRENT EFFORTS • Improved Understanding of binder oxidation and hardening rates in pavements (model) – Thermal/Oxygen transport model - ARC, 0-6009 – Improved measurements of mixture air voids morphology: pore size, spacing, AAV - ARC – Improved understanding of air permeation through pavements - ?? • Improved understanding of the impact of binder hardening on mixture performance (e.g. fatigue) - 0-6009 (laboratory, field data, Texas mixtures); ARC (modeling, laboratory, field data, non-Texas) • Field measurements of binder oxidation in pavements and maintenance treatment effectiveness - 0-6009 (Texas)

  15. WORK PLAN – TxDOT 0-6009 Pavement Oxidation and Pavement and Mixture Lab Mixture Oxidation and Measurement Oxidation Modeling Measurement Develop Database of Binder Oxidation and Hardening Kinetics (Subtask 2a-1) Treatment Model 2: Model 1: Develop Pavement Temperature- Develop Database of Pavement Oxygen Transport Model Temperatures (Subtask 2a-4) (Subtask 2a-2) Model Estimates of Binder Oxidation and Hardening in Pavements over Time Compare/ as a Function of Depth Calibrate (Subtasks 2a-3 and 2a-5) Measure Binder Oxidation and Hardening in Pavements over Time Mixture Aging as a Function of Depth Parameter Evaluation (Subtask 2a-6 and Task 2b) (Task 2c) Develop Fatigue Analysis System Field Lab with Aging Aging Aging (Task 2d) Measure CMSE Measure CMSE Fatigue Resistance Fatigue Resistance Compare (Task 2c) (Task 2c)

  16. TxDOT 0-6009: Evaluate Maintenance Treatments to Reduce Aging Selected Pavements (5 Climate Zones) Treatment Field Aging •Temperature Cycle •Local Climate •Traffic Load •Coring Annually Mixture Test •CMSE (Mixture Properties) •X-ray CT (Air Void Content) •Corelok (Air Void Content) ER (Environmental Room) Extraction and Recovery DSR (Dynamic Shear Rheometer) FTIR (Fourier Transform Infrared) CMSE Binder Test (Calibrated Mechanistic Approach with Surface Energy) •DSR ( η 0 *, G’/( η ’/G’)) •FTIR (Carbonyl Area)

  17. NEEDS - NOT BEING MET • Improved Understanding of binder oxidation and hardening rates in pavements (model) – Improved understanding of air permeation through pavements - Pavement breathing? Permeation from below? Flow out the edges? – Do treatments restrict access to oxygen? Compete with moisture drainage? • Field measurements: binder oxidation; maintenance treatment effectiveness - more data are needed in many climates to give better confidence in models

  18. SUGGESTED EMPHASIS OF PFS • Additional measurements of field aging and maintenance treatment effectiveness - flow into and through pavements; ability to retard oxidation and/or rejuvenate binders – Hot-applied treatments – Emulsion Treatments • A better understanding of fundamentals will allow determining optimal timing - link to fundamentals of binder oxidation in 0-6009 and ARC

  19. …Discussion…

  20. …Backup Slides…

  21. TEST PLAN Model Development Approach

  22. Equation for Oxidation Model ∂ ⎛ ⎞ ∂ ∂ 2 ⎡ ∂ ∂ ⎤ ⎛ ⎞ ⎛ ⎞ ⎛ ⎞ D P P 1 P cRT ⎜ ⎟ = + − O ⎜ ⎟ ⎜ ⎟ ⎜ ⎟ D r r ⎢ ⎥ ⎜ 2 ⎟ ∂ ∂ ∂ ∂ ∂ O CA ⎝ ⎠ ⎝ ⎠ ⎝ ⎠ ⎣ ⎦ ⎝ ⎠ t P r r r r h 2 d CA α − = = E / RT r AP e CA dt Where P = Oxygen partial pressure in asphalt binder film α = Order of reaction E = Activation energy D O2 = Oxygen diffusivity in asphalt film = Experimental constant c R = Gas Constant T = Absolute temperature of asphalt film h = Henry’s law constant

  23. TEST PLAN Measure Field & Lab Binder Aging Rates to Calibrate the Transport Model Neat Binder Laboratory Mixtures Field Cores (Correspond to Field (Controlled Binder Content (5 Climate Zones) and Laboratory and Air Void Content) Mixture) Field Aging Laboratory Aging in ER •Temperature Cycle 1)0 month Follow procedure in •Local Climate 2)3 months Subtask 2a-1 for Neat •Traffic Load 3)6 months Binder aging and •Coring Annually 4)9 months Measurements Mixture Test •CMSE (Mixture Properties) •X-ray CT (Air Void Content) •Corelok (Air Void Content) ER (Environmental Room) Extraction and Recovery DSR (Dynamic Shear Rheometer) FTIR (Fourier Transform Infrared) CMSE Binder Test (Calibrated Mechanistic Approach with Surface Energy) •DSR ( η 0 *, G’/( η ’/G’)) •FTIR (Carbonyl Area)

  24. CMSE Test Procedures

  25. BACKUP SLIDE 2 Improvement over EICM and recent advanced models Improvements Over EICM and existing Models Our Model Δ ∂ ∂ x T T ρ = − α + ε σ − εσ − − + 4 4 s s C ( 1 ) q T T h ( T T ) k ∂ ∂ s a a s c s a t x 2 * q s [shortwave solar radiation] 4 [incoming longwave radiation] Surface B.C ε a σ T a 4 [outgoing longwave radiation] εσ T s h c (T a -T s ) [convection heat loss] Heat conduction ∂ ∂ 2 T k T = inside pavement ∂ ρ ∂ 2 t C x Bottom B.C * Depth independent heat flux * Input data * Ta Interpolated hourly air temperature with * max. and min. temperature recorded Qs Hourly solar radiation predicted using SUNY * * or METSTAT model (available at NSRDB) Wind speed Hourly wind speed Model Parameters Optimized model parameters (Based on * * temp. measured in the middle depth of Pav.) * Improvement over EICM * over recent advanced models

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