SLIDE 1 Innovative Solutions for Water and the Environment
Membrane Bioreactor vs. Extended Aeration Treatment Pilot Study – Effluent and Groundwater Quality
Presenter
Leslie Dumas September 15, 2009
SLIDE 2
Acknowledgements
Thanks to: Colin Moy, REA., East Bay Municipal Utility District [EBMUD] – Project Manager Eileen Fanelli, P.G., East Bay Municipal Utility District/Presidio Trust – Project Manager David W. Smith, Ph.D., Merritt Smith Consulting – Principal Investigator
SLIDE 3 Background
- WateReuse Foundation Project WRF-04-016
- Project Title: Development of Regulatory
Protocol for Incidental Environmental Reuse of Title 22 Recycled Water
- Issued August 2005 to EBMUD with RMC Water &
Environment
- EBMUD’s ‘upcountry’ wastewater systems needs:
- Upgrading systems to meet evolving regulatory requirements
- Beneficial reuse of treated effluent
- Use of small MBR treatment systems
SLIDE 4
The Pardee Site
SLIDE 5 Key Challenges to Recycling in California
- Regulatory Compliance - Resolution #68-16
Antidegradation Policy
- Cost-Benefit for Small Systems
- Higher capital cost to implement MBR treatment
- Little to no reduction in longer-term operating costs
- Permitting costs increase overall capital costs
SLIDE 6 Study Goals
- Recognize baseline assumptions on meeting
CCR Title 22 standards for unrestricted use
- Provide a standardized process (Framework) for
evaluating recycled water projects
- Utilize established and industry-accepted tools
and practices for assessment
SLIDE 7 A Two-Part Study Approach was Used
- Develop a Framework (standardized process)
- Conduct a Pilot Test
SLIDE 8 Pilot Study Design
- Conducted over 12 month period
- Sampled and analyze influent, effluent and
groundwater quality from both existing and pilot systems
- Apply data to Framework analysis
- Identify key operating differences between the
extended aeration and MBR treatment plants
SLIDE 9
Treatment Trains
Pilot MBR Plant Schematic PACT Extended Aeration Plant Schematic
SLIDE 10
Conventional Plant
SLIDE 11
Pilot Plant
SLIDE 12
Pilot Plant
SLIDE 13
Pilot Plant
SLIDE 14
Pilot Plant
SLIDE 15
Pilot Plant
SLIDE 16 Pilot Program Analytical Plan
Parameter Influent Effluent Groundwater Settleable Solids (SS) Total Suspended Solids (TSS) pH Dissolved Oxygen Total Dissolved Solids (TDS) Turbidity Biological Oxygen Demand (BOD5) Chemical Oxygen Demand (COD) Total Organic Carbon (TOC) Total Kjeldahl Nitrogen (TKN) Ammonia (NH3 - N) Nitrate (NO3 – N) Total Coliform Bacteria (after disinfection) Viruses (after disinfection) General Minerals Metals Trihalomethanes (THMs) Halogenic Acetic Acids (HAAs) n-Nitrosodimethylamine (NDMA)
SLIDE 17 Influent W ater Quality Analysis
- Influent quality was consistent throughout the
pilot study
- Influent from PACT is found to be consistent with
a low-strength municipal wastewater
- Constituent concentrations appear to be on the
same order of magnitude for both pre- and pilot- period influent data based on a trend analysis.
SLIDE 18 Effluent W ater Quality Analysis
- 1. Confirm the assumption that the MBR effluent
met disinfected tertiary-treatment criteria
- 2. Identify the main differences in effluent quality
produced by the extended aeration and the MBR pilot systems
- 3. Compare to groundwater quality over the pilot
study period
SLIDE 19 Comparison of Expected and Actual MBR Effluent Quality
Parameter Units Published Expected Effluent Value Pilot MBR Effluent Quality Average Range BOD5 mg/L < 5 1.2 ND (< 2) - 2.2 TSS mg/L < 1 Not Sampled Not Sampled Ammonia mg/L as N < 1 0.63 ND (<0.3) - 6.72 Nitrate mg/L as N NA 30.03 0.19 – 53 Total Kjeldahl Nitrogen (TKN) mg/L as N NA 1.58 ND (< 1) – 11 Nitrite mg/L as N NA 0.16 ND (<0.0035) – 0.44 Total Nitrogen mg/L as N < 3 32.40* 0.19 – 71.16* Total Phosphorous (measured as Orthophosphate as P) mg/L < 0.2 6.8 1.7 - 9.9 Turbidity NTU < 0.2 0.34 0.13 – 1 Bacteria (measures as Total Coliform) Log removal Up to 6 log (99.9999%) 23.3 ND (< 2) – 230 Viruses Log removal Up to 3 log (99.9%) ND ND
SLIDE 20 MBR Effluent W ater Quality Analysis
- Results
- Improved for clarity, aluminum removal
and BOD degradation
- No difference for nitrogen, phosphates,
total dissolved solids and most metals
- Reduction in lead, manganese, and
- rthophosphate
- Poor denitrification (no change in TKN,
ammonia and nitrate concentrations)
SLIDE 21 Groundwater W ater Quality Analysis
- Water quality analyzed to:
- characterize groundwater quality for both the pre- and
MBR pilot periods
- Identify statistical differences that could be
attributable to the MBR pilot system
- The aquifer underlying the effluent pond is
composed fractured bedrock
- Used major ionic species to ‘fingerprint’ the
water quality
SLIDE 22
Piper Diagram shows no difference between pilot and pre-pilot groundwater quality
SLIDE 23
Similar shaped Stiff Diagrams support the same conclusion
Pre-Pilot Data Pilot Data
SLIDE 24 Groundwater Quality Results did not Reflect Change in Effluent Quality
- Few anomalies observed, but longer
monitoring required to determine cause
- Pre- and pilot effluent qualities are
significantly different from groundwater
- No changes in groundwater quality may
be result of:
- slight change in effluent chemistry
- low volumes of effluent discharged to
pond
SLIDE 25 Study Conclusions
- MBR system produced generally better effluent
- MBR system was efficient in biodegradable and
- rganic compounds removal
- MBR was not efficient in phosphorus removal or
denitrification
- Groundwater does not appear to be impacted by
either pre-pilot or pilot data over the monitoring period Based on testing, not reasonable to upgrade plant to achieve improved environmental results
SLIDE 26 The Framework was Tested with Pilot Data
thorough data collection
flexibility needed in developing the reuse scenario
SLIDE 27 The Full Report
- A Protocol for Estimating Potential Water Quality
Impacts of Recycled Water Projects: Final Report and Pilot Test Results; WateReuse Foundation: Alexandria, VA. 2009.
- A Protocol for Estimating Potential Water Quality
Impacts of Recycled Water Projects: Framework and User Guidance; WateReuse Foundation: Alexandria ,VA. 2009.
SLIDE 28
QUESTIONS?
SLIDE 29 Framework Design
- Internally consistent process
- Early disclosure of potential impact
- Allow project refinement to address possible
impacts
- Rely on established analytical tools and
accepted industry practices
- Apply on a constituent basis
- Broadly applicable
- Scalable relative to both project size and
number of constituents of potential concern
SLIDE 30 Framework Analysis Process
Consists of two main elements
- Preliminary Screening
- Detailed Site Evaluation
Figure 1 – Framework Analysis Process Figure 1 – Framework Analysis Process
SLIDE 31 Preliminary Screening
Process
Step 1 –Water Quantity Analysis Step 2 –General Water Quality Analysis Step 3 – Screen Applicable Guidelines and Regulations
Assumptions
Meets criteria for disinfected tertiary recycled water Beneficial reuse for irrigation at agronomic rates Storage not in a water of the United States
Outcomes
Identification of constituents of potential concern Identification of applicable water quality goals and objectives Identification of site-specific parameters for detailed analysis
SLIDE 32
Detailed Site Analysis
Process
Step 4 –Prepare site assessment focused on vegetation,
soil geochemistry and soil hydraulics
Step 5 –Complete the constituent analysis
Assumptions
Rely on site-specific data or literature values ,as
appropriate
Outcomes
Refine list of potential constituents of concern Estimate short and long term magnitude of potential impact Identify options for mitigating potential impacts
SLIDE 33
Framework Tools
Nutrients (nitrogen and phosphate)
Nutrient budget
Salts (measured by water and soil salinity & sodicity)
Determination of leaching fraction relative to assimilative
capacity
Metals (aluminum, copper, lead, nickel & zinc)
Metals inventory and attenuation
Organic carbon (as precursor for disinfection by-
products and HAA formation)
Effluent organic matter (EfOM)