SLIDE 19 The most stable distribution function against fluctuations of 𝑟′:
𝜖2 𝜖𝑟′2 = 0
This corresponds to an extremum of 𝜖
𝜖𝑟′
This is a minimum, as far as 𝐾 ≈ 0 at least. In the latter case, indeed: 𝑒𝑇𝑟′ = 𝑒𝑢 𝑒 = 𝑒𝑢𝑒𝑟′
𝑒 𝑒𝑟′ is the amount of produced in the time
𝑒𝑢 by the fluctuation 𝑒𝑟′; it is ≥ 0 for 𝑟′ = 1 (Gibbs’ case!) as fluctuations involve irreversible physics and achieves its minimum value 0 at equilibrium (where 𝑒S = 0) of an isolated system (where 𝐾 = 0). But GEC describes relaxation the same way regardless of 𝑟′ and the structure of the relaxed state is modified only slightly for 𝐾 ≈ 0 , hence
𝑒 𝑒𝑟′
is still a minimum (even if non-zero), not a maximum! Allowable range for 𝑨 = 𝑟′ − 1 = 1 − 𝑟: 0 ≤ 𝑨 < 1 (𝑨 = 0 is Gibbs) Borland 1998