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Groundwater, its treatment and protection Harri Mattila, 2019 1 - - PowerPoint PPT Presentation
Groundwater, its treatment and protection Harri Mattila, 2019 1 - - PowerPoint PPT Presentation
Groundwater, its treatment and protection Harri Mattila, 2019 1 7.10.2019 General l Groundwater forms only 0,53 % of all water resources (worldwide). l In Finland, more than 2/3 of all raw water is groundwater or artificial groundwater l
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General
l Groundwater forms only 0,53 % of all water
resources (worldwide).
l In Finland, more than 2/3 of all raw water is
groundwater or artificial groundwater
l Advantages of groundwater when compared
to surface water:
- No need for disinfection (in normal situations)
- Temperature is rather constant (and low)
- Little or no chemicals involved in treatment
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The hydrological cycle
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Various groundwater formations
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Observation tube (well)
l Usually PVC pipe l DN > 50 mm l Screen in the depth
- f the groundwater
layer
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An example of groundwater depth variations (Tuusula, Finland)
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The need for groundwater treatment
l optimum situation: no treatment l most common reason is prevention of corrosion l Fe or Mn l organic material l fluoride l salts l radon l arsenic
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pH -value
l Depends on soil around the
groundwater well
l Sometimes rain water can be acidic l pH of groundwater in Finland is
normally between 5 - 7
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Nitrate compounds
l ammonium, nitrate, nitrite, nitrogen l Very rarely in Finnish groundwaters l Usually means pollution by agriculture
- r industry
l Sometimes also because of wastewater in
groundwater!
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Sulfate
l Can be diluted in groundwater for
example from minerals rich of sulphur beacause of high pH.
l Important factor in corrosion l limit 50 mg/l
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Iron and manganese
l Most common problems in groundwater
(in Finland)
l No health hazard – technical and/or
aesthetical problems
l Fe < 0,2 mg/, Mn < 0,05 mg/l l Causing also sedimentation in networks
and that’s why harmful
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Chloride
l Normally because of nearby sea but also
because of deicing in winter
l In nature < 10 mg/l, taste limit 200 – 300
mg/l, recommended maximum 250 mg/l, target 25 mg/l
l Very important factor in corrosion
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Hardnes
l Ca- ja Mg –salts l 1 mmol/l = 5,6 º dH l Should be 3 – 5 º dH l The most interesting parameter to
customers due to washing machines
l sometimes high also in Finland, even >10
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Aluminium
l Can be diluted from from the soil (like
Fe and Mn), specially when the soil in acidic
l The maximum limit allowed 0,2 mg/l
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Arsenic
l carcinogenic, max allowed 0,01 mg/l l Mainly in deep boreholes l In Finland about 7% of all the deep
wells are contaminated
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Boron
l Max allowed 1,0 mg/l l Is indicating pollution by wastewater l Appears very seldom
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Fluoride
l WHO: max allowed 1,5 mg/l (note,
drinking water should have 0,5 mg/l)
l Defluoridation is considered as an
expensive task => 1. change the source if possible, 2. dilute water with another
- ne with little flouride, 3. treatment
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Copper
l Max allowed 2,0 mg/l ( an average /
week)
l Rather seldom in groundwater l Mainly because of corrosion in pipelines
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Bacteria
l E.coli is the most important indicator
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Viruses
l Very difficult to analyze => difficult to
separate/destroy from water
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Dilutants
l Altogether about 70 compounds l Hydrogarbons, alcohols, aethers, esters,
aldehydes, ketones
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MTBE, TAME
l Additives in petrol l Are diluted very easily in water => the
first compounds found in case of pollution
l Easy to detect by smell and taste (0,03
mg/l)
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Pesticides
l Hundreds of compounds l Max allowed 0,0005 mg/l (total) l The smallest amounts which can be
detected are normally 0,00001 – 0,00002 mg/l
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Radioactivity
l Mostly in deep wells (in the rock) l No smell, no colour, no taste ! l Radon is the most common one in
groundwater
l Max allowed 1000 Bq/l)
=> 1. new water source, 2. treatment (aeration, active carbon filtration)
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Uranium
l Lack of knowledege concerning health
effects
l Earlier max by WHO 0,15 mg/l, today
0,002 mg/l
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Corrosion
l pH > 7,5 l alkalinity > 0,6 mmol/l l calsium > 10 mg/l l oxygen > 2 mg/l
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Maps and aerial photographs
l Swamps, springs,
ditches, etc.
l Humidity changes out
- f photgraphs
l Old maps might give
valuable information
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Geophysical methods
l Seismic sounding l Electrical probing (resistance)
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Drillings
l Manually l Machinery
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Iron and manganese
l Most common quality problem with
ground waters
l Coagulation happens immediately with
- zygen
l Iron can be removed also biologically
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Removal of Fe and Mg
l In small scales
– aeration – sand filtration – ion exchange processes
l Lime stone filtration l Slow sand filtration
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Slow sand filtration
l Water is filtered slowly through a sand
layer
l Surface load 0,05 – 0,2 m/h l Water per one 1 m2: 50 – 200 l/h l Iron content max 1mg/l l Pretreatment could be done by a filter
containing crushed stone
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Sand filtration
l Aeration needed almost always l Dissolved iron is oxidized => can be
filtered out of water
l Surface load normally 4 – 5 m/h l Small filters require backwashing more
- ften
l Might be expensive ?
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UV desinfection
l Generally, ground water is
microbiologically clean
l Sometimes we have experienced pollution l UV-desinfiction is applicable method for
ground waters (no turbidity nor colour)
l UV-desinfection is not affecting the taste
- f water unlike chlorination
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Ground water protection !
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Raato