Development of New Chemical Products and Processes March 21, 2011 - - PowerPoint PPT Presentation

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Development of New Chemical Products and Processes March 21, 2011 - - PowerPoint PPT Presentation

Life-Changing Innovation Development of New Chemical Products and Processes March 21, 2011 Keith Pauley Keith.Pauley@matricresearch.com 800-611-2296 x881 Chemical and Environmental Technologies Advanced Engineering Health and Life Sciences


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Life-Changing Innovation

Chemical and Environmental Technologies Health and Life Sciences Advanced Engineering Systems

Keith Pauley

Keith.Pauley@matricresearch.com

800-611-2296 x881

Development of New Chemical Products and Processes

March 21, 2011

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Agenda

MATRIC Description Development Process Examples

– Chemical Technologies – Energy Technologies – Environmental Technologies

Summary

www.matricresearch.com 2

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MATRIC DESCRIPTION

www.matricresearch.com 3

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MATRIC 4

About MATRIC

MATRIC is a non-profit research and development corporation formed in 2004

– Reinvest earnings in new research – Offices in Charleston (WV), Morgantown (WV) and Oak Ridge (TN) and Milan, Italy

Research and engineering staff of nearly 150

– 33 PhD-level researchers – 9 professional engineers + access to Dow downsized staff – 25+ average years of experience – 2 members of US National Academy of Engineering

MATRIC has a focus on developing intellectual properties and adding value throughout the R&D, engineering and commercialization processes

MATRIC was formed from the downsizing of over 2000 research scientists and engineers located at the Union Carbide Tech Center, South Charleston, WV from 2001-2008

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South Charleston Technology Park Facilities

World-Renowned Research and Development Campus

– 651 acres – Two major chemistry laboratory buildings – Three major pilot plant complexes – Major engineering building – Major computer data warehouse

MATRIC currently occupies Building 740

– Over 35 wet chemistry labs – Engineering space – Access to over 32 multi-story high pressure pilot plant cells

West Virginia university system in investing over $40M in new training facilities at the Tech Park

MATRIC 5

Significant history of R&D at this site Over 30,000 international patents 286 of the largest 500 chemicals in the world first produced here

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Professional Engineering to Implement Innovation

(detailed design, construction management, operations training)

Commercialization to Access Markets (license or

start-up companies)

Laboratory and Pilot-Scale Research and Development to Create New Innovation

(intellectual property development)

Full Innovation Life-Cycle Service

6

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MATRIC 7

MATRIC Business Areas

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Environmental Technologies

Carbon dioxide capture Water purification Natural gas purification Selenium and metals removal Nuclear remediation Soil restoration

Pharma and Fine Chemicals

API process development Microreactor systems

Member of NETL Contractor team for Energy R&D Fossil Fuels and Products

Ethane derivatives from Natural Gas Coal to Liquids/Chemicals Coal Gasification Integrated Gasification Combined Cycle Mine safety equipment

Biomass Fuels and Products

Biodiesel development Corn ethanol development Cellulosic ethanol development Biomass gasification Anaerobic digestion Bio-polymers and chemicals

Chemical, Energy and Environmental Technologies: Product Areas

MATRIC 8

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9

Chemical, Energy and Environmental Technologies: Capabilities

Process and Product Development

Economic-directed research Radical process innovation & synthesis Process and plant improvement Product and prototype development Materials development & testing Modeling using Aspen and Chemcad Scale-up, pilot plant development & demonstration Product manufacture for market development & testing

Separations Technologies

Membranes Distillation Crystallization Reactive media, Simulated moving bed Other advanced techniques

Catalysis

Catalyst design & scale-up Testing & modeling Substrate design Reaction engineering

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MATE Capabilities and Skills

Detailed Engineering

– Chemical process engineering – Control system engineering – Electrical system engineering – Mechanical engineering – Civil engineering, Drafting

Procurement

– Major and Minor equipment – Bulk material

Construction Management

– Construction oversight – Process Representation

Operations Training and Start-up

– OSHA training – Process operations training – Plant process start-up support

Project Management

MATE 10

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Overall Research and Engineering Enterprise

Laboratory Research Conceptual Process Design Detailed Process Design Procurement Construction Management Operations Training and Start-up Continuous Improvement

MATRIC 11

MATRIC Capabilities MATE Capabilities

Supporting Processes

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DEVELOPMENT PROCESS

www.matricresearch.com 12

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Iterative Development Process

Identify highest risks Create technical model Laboratory research Conceptual design Economics www.matricresearch.com 13

Integrated Technical Team

Tackle the hardest problems first Develop framework for scientific investigation Utilize disciplined work processes to maximize lab activity Create early designs for products or processes Create early economic models Integrated Technical Team includes representatives from all phases of development, through manufacture

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CHEMICAL TECHNOLOGIES

Examples

www.matricresearch.com 14

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Ethane Derived Chemicals

MATRIC has developed a process to produce ethylene and down- stream integrated chemicals using a catalytic cracking technology

– Lower capital costs (<40%) – Lower operating costs (exothermic) – Fewer down-stream products

MATRIC 15

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Coal to Chemicals

Syngas-derive chemicals portfolio

– Ammonia – Methanol – Olefins – Glycols

Advanced catalysts Market development and pilot demonstration World-scale plant engineering and design

MATRIC 16

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MATRIC 17

Coal Freeze Conditioning

AKJ Industries supplies the coal industry with solutions that prevent coal from freezing to the sides of rail cars MATRIC developed a new formulation for AKJ having 10X better performance The new formulation has been successfully commercialized MATRIC is continuing to support AKJ in expanding the market for this product

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Integrated Biorefinery

Technology development, design and engineering of an integrated biorefinery for a major Mid-West USA military facility Plant includes:

– Flexible feed ethanol production – Flexible feed biodiesel production – Flexible feed anaerobic digestion for methane production – Gas turbine electricity production

MATRIC 18

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Algae Development

MATRIC is working with a number of academic and industrial partners to utilize microbial algae to:

– Capture and sequester carbon dioxide – Develop algal oil-based biofuels – Create new food additives – Produce bio-derived polymers

MATRIC is working in the areas of extraction and

  • verall reaction system design

MATRIC 19

Courtesy: Greenfuelworks.com

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MATRIC 20

Bio-Derived Polymer Intermediate

MATRIC has developed and scaled a process for converting corn sugar to isosorbide, a valuable polymer intermediate Pilot plant production of several 100s

  • f pounds per month have allowed for

testing in larger scale manufacturing systems

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Fermentation Derivatives

MATRIC has created processes to produce airport de-icer products from biological fermentation MATE has engineered the full- scale fermentation process design A large-scale pilot plant has been developed and operated for market introduction

MATRIC 21

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MATRIC 22

Biodegradable Plastic Process

Large international bio- polymers company worked with MATRIC to dramatically increase their production through-put

– Approaching 2x improvement

Implemented process design improvements to all “bottle- necked” process steps

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MATRIC 23

Cellulosic Ethanol Development

MATRIC is currently researching advanced cellulosic pre-treatment technologies which will economically liberate the C5 and C6 sugars MATRIC and MATE participated in the design and engineering of several cellulosic demonstration facilities for a variety of government and private- sector funded projects

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ENERGY TECHNOLOGY

Examples

www.matricresearch.com 24

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Oxy-Fuel Combustion

MATRIC is developing oxygen membranes for use in traditional combustion processes

– Allows for more efficient combustion and overall cycle efficiency – Creates a nearly pure stream of CO2, which aids in GHG capture and sequestration

www.matricresearch.com 25

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MATRIC 26

Pyrolysis Systems

Pyrolysis heats biomass in the absence of oxygen

– Products: Methane, Bio-oil, Water and Char – Feed: Various biomass (ag waste, wood, switchgrass, landfill waste, etc.)

Projects conducted include:

– Pyrolysis demonstration with various biomass material with Cornell University – Design of 40-ton per day pyrolysis units in Australia – Development of novel variable reaction pyrolysis reactor system – Major 1000+ acre bio-char demonstration in Illinois – Design of 20-ton per day pyrolysis unit in Wisconsin – Design of 100,000 ton per year pyrolysis system in West Virginia

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MATRIC 27

Biodiesel System Development and Plant Construction

The new biodiesel process developed for BEST Energies has been designed for a facility in Cashton, Wisconsin MATRIC completed laboratory development, detailed engineering and design for the plant and provided engineering construction support and operator training for the plant Plant start-up was successfully completed in December 2007 Both esterification and transesterification of high FFA oils

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Traditional Ethanol Development

MATRIC has developed a novel process that can flexibly utilize corn, sorghum, wheat, cane and other feedstocks to produce traditional ethanol MATRIC’s small scale design reduces both the water and energy consumption through the use of advanced proprietary water separations technology, which will reduce plant operations costs by up to 50%

MATRIC 28

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MATRIC 29

Anaerobic Digestor

MATRIC has worked with West Virginia State University to develop economical systems to create methane and other biofuels from animal wastes

– Research is focused on chicken wastes

The process uses enzymes in a depleted oxygen environment to metabolize the biomass materials Design and construction of several digestors in Florida, Missouri, Virginia and Europe

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ENVIRONMENTAL TECHNOLOGY

Examples

www.matricresearch.com 30

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MATRIC 31

Carbon Capture

MATRIC has worked with the Department of Energy to develop novel technology to capture carbon dioxide in fossil fuel plants MATRIC’s adsorption technology can reduce the parasitic electrical load from 30% to 3%

Up to 70% of the cost for carbon sequestration is in the capture process at the power plant

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MATRIC 32

Natural Gas Purification

MATRIC started a company, NG-Innovations, LLC that provides natural gas treatment technology for oil and natural gas drilling

  • perations

Technology developed to allow natural gas producers to clean up their gas at the wellhead Goal is to generate a higher-quality, less corrosive gas that will provide greater value

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Natural Gas Well Desalination Unit

www.matricresearch.com 33

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Surface Mine Water Selenium Removal System

Reverse Osmosis Technology

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Surface Mine Water Selenium Removal System

Reverse Osmosis Technology

Membranes are in the white cylinders Feed pump

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Surface Mine Water Selenium Removal System

Reactive Filtration Technology

www.matricresearch.com 36

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Surface Mine Water Selenium Removal System

Reactive Filtration Technology

www.matricresearch.com 37

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Summary

MATRIC uses a disciplined work process to create innovative products and processes for the commercial marketplace The breadth of our innovations has allowed for rapid international growth Our business focuses on long-term relationships with our customers and collaborators

www.matricresearch.com 38