Background on Contaminant Migration and Exposure Pathways
Presentation to the LTMS August 28, 2007
By: Brian Ross, USEPA
Background on Contaminant Migration and Exposure Pathways - - PowerPoint PPT Presentation
Background on Contaminant Migration and Exposure Pathways Presentation to the LTMS August 28, 2007 By: Brian Ross, USEPA Figure 7-1. Illustration of locales or conditions for volatile emissions from CDFs Delta Island Hydrology & Dredged
By: Brian Ross, USEPA
Figure 7-1. Illustration of locales or conditions for volatile emissions from CDFs
By: Steven Michelson Applied Water Resources Corporation Walnut Creek, CA 925 938 1600
August 28, 2007
(adapted from Jeffery Steevens, ERDC)
Management
“Use science to tell us the right level”
Regulatory Agencies
“Let’s look at the regulations”
Scientists
“It depends…”
Environmental Groups
“No level is low enough”
Politicians
“Any level is OK, if this problem will only go away”
August 28, 2007
Based on Roberts No. 1 and adjacent Deep Water Ship Channel
August 28, 2007
Stockton Deep Water Ship Channel Roberts Island Rough and Ready Island
August 28, 2007
August 28, 2007
August 28, 2007
Pump House Deep Water Ship Channel Mokelumne Aqueduct Burns Cutoff
ROUGH & READY ISLAND
Black Slough Roberts
Roberts
San Joaquin River
LOWER ROBERTS ISLAND
August 28, 2007
August 28, 2007
August 28, 2007
August 28, 2007
August 28, 2007
August 28, 2007
August 28, 2007
August 3, 2006
August 28, 2007
August 28, 2007
August 28, 2007
August 28, 2007
Specific Conductance in RN1 Peat Layer Monitor Wells Background Transect includes all field measurements since 9/05
1000 2000 3000 4000 5000 6000 7000 500 1000 1500 2000 2500 3000 Distance from River (feet) Specific Conductance (µS/cm) MW-9p MW-10p MW-11p
August 28, 2007
Specific Conductance Sand Layer Wells, Background Transect - includes all field measurements since 9/05
500 1000 1500 2000 2500 3000 3500 4000 4500 5000 500 1000 1500 2000 2500 3000 Distance from River (feet) Specific Conductance (µS/cm)
MW-9s MW-10s MW-11s
August 28, 2007
Specific Conductance in RN1 - All Peat Layer Monitor Wells
includes all field measurements since 9/05
1000 2000 3000 4000 5000 6000 7000 500 1000 1500 2000 2500 3000 Distance from River (feet) S pecific C
icrosiem ens/cm )
MW-5p MW-7p MW-8p MW-9p MW-10p MW-11p MW-13p MW-15p MW-16p MW-17p MW-18p MW-19p MW-20p
August 28, 2007
Specific Conductance in RN1 Sand Layer Monitor Wells, All Transects includes all field measurements since 9/05
500 1000 1500 2000 2500 3000 3500 4000 4500 5000 500 1000 1500 2000 2500 3000 Distance from River (feet) Specific C onductance (microsiemens/cm) MW-5s MW-6s MW-7s MW-8s MW-9s MW-10s MW-11s MW-13s MW-15s MW-16s MW-17s MW-18s MW-19s MW-20s
Edge of sediment 18s, 19s, 8s 6s, 13s, 20s, 7s 9s, 10, 11s
August 3, 2006
August 28, 2007
SW-1 SW-2 SW-3 SW-4 Main drain
August 28, 2007
5 10 15 20 25 30
Arsenic (µg/l) Lead (µg/l) Sodium (mg/l/10) Sulfate (mg/l/10) SC (µS/cm/100)
MW-6d MW-14d SW-3 Main Island Drainage Water Quality Goal
August 3, 2006
August 28, 2007
River sediment naturally eroded from foothills
Deposited throughout Central Valley and Delta Anthropogenic impacts
Mining ‐ (Hg …) Agricultural ‐ (pesticides, herbicides, nitrates, organic carbon) Industrial ‐ (you name it…) Municipal Storm Water ‐ (petroleum, metals…)
ARSENIC : in Sediment and Ground Water
10 20 30 40 50 60 70 80 90
REF (1) POS WC Docks (10) DWSC 04, 05, 05 (30) S4 Seds (5) Roberts Isl No.1 (21) MW-9P MW-10P, 11P MW-9S MW-10S, 11S DI WET DI WET DI WET DI WET GW Background Peat Background Sand RIVER PREDREDGE DREDGED ISLAND GROUND WATER Arsenic Concentration (µg/l, ppb)
WQG = 10 µg/l AG = 100 µg/l
BARIUM : in Sediment and Ground Water
100 200 300 400 500 600 700 800 900 1000 REF (1) POS WC Docks (10) DWSC 04, 05, 05 (30) S4 Seds (5) Roberts Isl No.1 (21) MW-9P MW-10P, 11P MW-9S MW-10S, 11S DI WET DI WET DI WET DI WET GW Beckground Peat Background Sand RIVER PREDREDGE DREDGED ISLAND GROUND WATER
Concentration (µg/l, ppb)
WQG = 10 µg/l AG = 100 µg/l
COPPER : in Sediment and Ground Water
10 20 30 40 50 60 70 REF (1) POS WC Docks (10) DWSC 04, 05, 05 (30) S4 Seds (5) Roberts Isl No.1 (21) MW-9P MW-10P, 11P MW-9S MW-10S, 11S DI WET DI WET DI WET DI WET GW Beckground Peat Background Sand RIVER PREDREDGE DREDGED ISLAND GROUND WATER Copper
Concentration (µg/l, ppb)
WQG = 10 µg/l AG = 100 µg/l
LEAD : in Sediment and Ground Water
2 4 6 8 10 12 14 16 18 20 REF (1) POS WC Docks (10) DWSC 04, 05, 05 (30) S4 Seds (5) Roberts Isl No.1 (21) MW-9P MW-10P, 11P MW-9S MW-10S, 11S DI WET DI WET DI WET DI WET GW Beckground Peat Background Sand RIVER PREDREDGE DREDGED ISLAND GROUND WATER Lead
Concentration (µg/l, ppb)
WQG = 10 µg/l AG = 100 µg/l
NICKEL : in Sediment and Ground Water
10 20 30 40 50 60 70 80 90 100
REF (1) POS WC Docks (10) DWSC 04, 05, 05 (30) S4 Seds (5) Roberts Isl No.1 (21) MW-9P MW-10P, 11P MW-9S MW-10S, 11S DI WET DI WET DI WET DI WET GW Beckground Peat Background Sand RIVER PREDREDGE DREDGED ISLAND GROUND WATER Nickel
Concentration (µg/l, ppb)
WQG = 10 µg/l AG = 100 µg/l
20 40 60 80 100 120 140 160 180 200
REF (1) POS WC Docks (10) DWSC 04, 05, 05 (30) S4 Seds (5) Roberts Isl No.1 (21) MW-9P MW-10P, 11P MW-9S MW-10S, 11S DI WET DI WET DI WET DI WET GW Beckground Peat Background Sand RIVER PREDREDGE DREDGED ISLAND GROUND WATER Zinc
Concentration (µg/l, ppb)
WQG = 10 µg/l AG = 100 µg/l
August 28, 2007
Delta Island Hydrology
Rivers recharge GW GW flows inland and is returned via ditches to river
Delta Island Ground Water
GW becomes more saline with distance inland GW in dredged sediments is similar to GW adjacent to river GW in dredged sediments is of better quality than inland GW
Delta Island Drainage Ditch Water
Of lower quality than GW in River and dredged sediments
Sediment characterization
DI WET tends to over‐predict potential impact to GW
August 28, 2007