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An MRRDC Short Course: Influent Characterization for Wastewater Modeling
Thursday, January 25, 2018 1 – 3 p.m. ET
An MRRDC Short Course: Influent Characterization for Wastewater - - PDF document
1/25/2018 An MRRDC Short Course: Influent Characterization for Wastewater Modeling Thursday, January 25, 2018 1 3 p.m. ET 1 1/25/2018 How to Participate Today Audio Modes Listen using Mic & S peakers Or, select
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Thursday, January 25, 2018 1 – 3 p.m. ET
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S peakers
Telephone” and dial the conference (please remember long distance phone charges apply).
the Questions pane.
for replay shortly after this webcast.
John B. Copp Ph.D.
Primodal Inc. Hamilton, Ontario
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Chris Tanush Alyssa Matt Bye Wadhawan Mayer Tebow
EnviroSim Dynamita Hazen&Sawyer Kimley-Horn
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Introduction – Why it is Important
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ludge production and disposal costs
S ? )
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Anaerobic Zone Influent Anoxic Zone Aerobic Zone Secondary Clarifier Process Inputs:
Wastewater Characteristics Loadings Dynamic Patterns
Process Model Variables:
Biological Reactions Physical/ Chemical
Process Operating Conditions:
Recycle Rates DO Control S etpoints
Process Configuration:
Flow Routing Unit S izes Reactor S taging Recycle S treams
WERF Methods of Wastewater Characterization for Activated Sludge Modeling (2003)
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respiration, ignores what is converted to bacterial biomass
BOD
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balance
CODEFF CODWAS CODINF CODConsumed
MASS BALANCE
Total Influent COD CODT,INF
Biodegradable COD Slowly Biodegradable SBCOD (XS) Unbiodegradable COD Soluble Unbiodegradable SUS Particulate Unbiodegradable XUP Readily Biodegradable RBCOD (SBS) Biomass Complex SBSC SCFA SBSA Colloidal XSC Particulate XSP
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1.
Biodegradable
2.
Unbiodegradable
3.
Active biomass
Total Influent COD CODT,INF
Biodegradable COD Slowly Biodegradable SBCOD (XS) Unbiodegradable COD Soluble Unbiodegradable SUS Particulate Unbiodegradable XUP Readily Biodegradable RBCOD (SBS) Biomass Complex SBSC SCFA SBSA Colloidal XSC Particulate XSP1/25/2018 11
molecules organisms rapidly take up and consume
lowly” portion consists of larger molecules requiring extracellular breakdown before uptake and use
Total Influent COD CODT,INF
Biodegradable COD Slowly Biodegradable SBCOD (XS) Unbiodegradable COD Soluble Unbiodegradable SUS Particulate Unbiodegradable XUP Readily Biodegradable RBCOD (SBS) Biomass Complex SBSC SCFA SBSA Colloidal XSC Particulate XSPTotal Influent COD CODT,INF
Biodegradable COD Slowly Biodegradable SBCOD (XS) Unbiodegradable COD Soluble Unbiodegradable SUS Particulate Unbiodegradable XUP Readily Biodegradable RBCOD (SBS) Biomass Complex SBSC SCFA SBSA Colloidal XSC Particulate XSP1/25/2018 12
discharge limit (perhaps for industrial WW)
Total Influent COD CODT,INF
Biodegradable COD Slowly Biodegradable SBCOD (XS) Unbiodegradable COD Soluble Unbiodegradable SUS Particulate Unbiodegradable XUP Readily Biodegradable RBCOD (SBS) Biomass Complex SBSC SCFA SBSA Colloidal XSC Particulate XSPdigestibility
Total Influent COD CODT,INF
Biodegradable COD Slowly Biodegradable SBCOD (XS) Unbiodegradable COD Soluble Unbiodegradable SUS Particulate Unbiodegradable XUP Readily Biodegradable RBCOD (SBS) Biomass Complex SBSC SCFA SBSA Colloidal XSC Particulate XSP1/25/2018 13
Total Influent COD CODT,INF
Biodegradable COD Slowly Biodegradable SBCOD (XS) Unbiodegradable COD Soluble Unbiodegradable SUS Particulate Unbiodegradable XUP Readily Biodegradable RBCOD (SBS) Biomass Complex SBSC SCFA SBSA Colloidal XSC Particulate XSPTotal Influent COD CODT,INF
Biodegradable COD Slowly Biodegradable SBCOD (XS) Unbiodegradable COD Soluble Unbiodegradable SUS Particulate Unbiodegradable XUP Readily Biodegradable RBCOD (SBS) Biomass Complex SBSC SCFA SBSA Colloidal XSC Particulate XSP1/25/2018 14
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Tanush Wadhawan, Ph.D.
Dynamita, Toronto, Ontario, Canada
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Tanush Wadhawan, PhD Dynamita
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multiple times and integrated together for analysis
Grab required
TN, NO3-N, NHx-N
S , VS S
Grab or Composite
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time)
ample number and S ample description
Total Influent COD TCOD Filtered COD S CCOD = S
U + S B + S VFA +CB + CU
Particulate COD XCOD S
VFA
S
B
S
U
CB CU
S = soluble C = colloidal X = part iculate VF A = volat ile fat t y acid B = biodegradable U = unbiodegradable OHO = ordinary het erot rophs E = endogenous decay product s BIO = biomass
XB XU Filtered Flocculated COD S
COD = S U + S B + S VFA
Colloidal COD CCOD = CU + CB XOHO XE=0 XBIO=0 except OHO
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Total Influent COD TCOD Filtered COD S CCOD = S
U + S B + S VFA +CB + CU
Particulate COD XCOD S
VFA
S
B
S
U
CB CU
S = soluble C = colloidal X = part iculate VF A = volat ile fat t y acid B = biodegradable U = unbiodegradable OHO = ordinary het erot rophs E = endogenous decay product s BIO = biomass
XB XU Filtered Flocculated COD S
COD = S U + S B + S VFA
Colloidal COD CCOD = CU + CB XOHO XE=0 XBIO=0 except OHO
B, S U
COD, S B, XOHO
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Glass fiber (1.2 µm) Membrane (0.45 µm) Raw sample: TCOD Filtrate 1: FCOD Filtrate 2: FFCOD
Total Influent COD TCOD Filtered COD S CCOD = S
U + S B + S VFA +CB + CU
Particulate COD XCOD S
VFA
S
B
S
U
CB CU
S = soluble C = colloidal X = part iculate VF A = volat ile fat t y acid B = biodegradable U = unbiodegradable OHO = ordinary het erot rophs E = endogenous decay product s BIO = biomass
XB XU Filtered Flocculated COD S
COD = S U + S B + S VFA
Colloidal COD CCOD = CU + CB XOHO XE=0 XBIO=0 except OHO
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XB +XU + CB + CU + SB + SU Filtration Glass fiber (1.2 µm)
Raw sample: TCOD Filtrate : FCOD
CB + CU + SB + SU
PCOD = TCOD ‐ FCOD
XB +XU
Key steps
Total Influent COD TCOD Filtered COD S CCOD = S
U + S B + S VFA +CB + CU
Particulate COD XCOD S
VFA
S
B
S
U
CB CU
S = soluble C = colloidal X = part iculate VF A = volat ile fat t y acid B = biodegradable U = unbiodegradable OHO = ordinary het erot rophs E = endogenous decay product s BIO = biomass
XB XU Filtered Flocculated COD S
COD = S U + S B + S VFA
Colloidal COD CCOD = CU + CB XOHO XE=0 XBIO=0 except OHO
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XB +XU + CB + CU + SB + SU Filtration Glass fiber (1.2 µm)
Raw sample: TCOD Filtrate : FCOD
CB + CU + SB + SU
PCOD = TCOD ‐ FCOD
XB +XU
Key steps
O4.
Flocculation
Filtrate 2: FFCOD Flocculant: ZnS O4 SB + SU Colloïdal COD = FCOD ‐ FFCOD CB + CU
0.45 µm
Total Influent COD TCOD Filtered COD S CCOD = S
U + S B + S VFA +CB + CU
Particulate COD XCOD S
VFA
S
B
S
U
CB CU
S = soluble C = colloidal X = part iculate VF A = volat ile fat t y acid B = biodegradable U = unbiodegradable OHO = ordinary het erot rophs E = endogenous decay product s BIO = biomass
XB XU Filtered Flocculated COD S
COD = S U + S B + S VFA
Colloidal COD CCOD = CU + CB XOHO XE=0 XBIO=0 except OHO
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ystems with S RT more than 3 days
5 10 15 20 25 30 35 40 45 20 40 60 80
OUR mg/L/h
Time (min)
Area = M0 mgO2/ L RBCOD = M0/ (1-Y)
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Total Influent COD TCOD Filtered COD S CCOD = S
U + S B + S VFA +CB + CU
Particulate COD XCOD S
VFA
S
B
S
U
CB CU
S = soluble C = colloidal X = part iculate VF A = volat ile fat t y acid B = biodegradable U = unbiodegradable OHO = ordinary het erot rophs E = endogenous decay product s BIO = biomass
XB XU Filtered Flocculated COD S
COD = S U + S B + S VFA
Colloidal COD CCOD = CU + CB XOHO XE=0 XBIO=0 except OHO
XB
Filtered biodegradable COD
determination
XOHO
OUR mg/ l/ d days OHO - 30 mgCOD/ L Mu – 8.5 d-1
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Key measurements Value Unit Flow 24000.0 MGD or m3/d TSS 185.0 mg/L VSS 157.0 mg/L TDM 800.0 mg/L TKN 34.4 mg N/L TP 4.3 mgP/L Total Sulfur 20.0 mgS/L Alkalinity 330.0 mg CaCO3/L pH 7.2 ‐ COD ‐ BOD Value Unit Influent COD 420.0 mg COD/L Influent filtered COD 170.0 mg COD/L Influent filtered flocculated COD 85.0 mg COD/L Effluent filtered COD (inert) 20.0 mg COD/L Influent cBOD5 200.0 mg BOD/L Other influent measurements Value Unit VFA 20.0 mg COD/L Ammonia 24.0 mg N/L Phosphate 2.5 mg P/L Nitrite+nitrate 0.0 mg N/L
Key measurements Value Unit Flow 24000.0 MGD or m3/d TSS 185.0 mg/L VSS 157.0 mg/L TDM 800.0 mg/L TKN 34.4 mg N/L TP 4.3 mgP/L Total Sulfur 20.0 mgS/L Alkalinity 330.0 mg CaCO3/L pH 7.2 ‐ COD ‐ BOD Value Unit Influent COD 420.0 mg COD/L Influent filtered COD 170.0 mg COD/L Influent filtered flocculated COD 85.0 mg COD/L Effluent filtered COD (inert) 20.0 mg COD/L Influent cBOD5 200.0 mg BOD/L Other influent measurements Value Unit VFA 20.0 mg COD/L Ammonia 24.0 mg N/L Phosphate 2.5 mg P/L Nitrite+nitrate 0.0 mg N/L Influent fractions Name Value SI unit Fraction of VSS/TSS 84.9 % Fraction of filtered COD (SCCOD, 1.5 µm, incl. colloids) in total COD (TCOD) 40.5 % Fraction of flocculated filtered (SCOD, wo colloids) COD in total COD (TCOD) 20.2 % Fraction of VFA in filtered COD (SCCOD, 1.5 µm, incl. colloids) 11.8 % Fraction of soluble unbiodegradable organics (SU) in filtered COD (SCCOD, 1.5 µm,
11.8 % Fraction of particulate unbiodegradable organics (XU) in total COD (TCOD) 14.0 % Fraction of heterotrophs (OHO) in total COD (TCOD) 5.0 % Fraction of endogenous products (XE) in total COD (TCOD) 20.0 % Fraction of colloidal unbiodegradable organics (CU) in colloidal COD (SCCOD‐SCOD) 20.0 % Fraction of NHx in total Kjeldahl nitrogen (TKN) 69.8 % Fraction of PO4 in total phosphorus (TP) 58.1 % Fraction of N in readily biodegradable substrate (SB) 4.0 % Fraction of N in particulate unbiodegradable substrate (XU) 1.0 % Fraction of P in readily biodegradable substrate (SB) 1.0 % Fraction of P in particulate unbiodegradable substrate (XU) 0.1 %
Convertor Current commercial simulators provide tools to convert usual measurements into model inputs.
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Influent fractions from data Default % Calculated from data % COD/BOD/TSS/VSS match Measured data Calculated from estimated fractions Verdict Fraction of filtered COD (SCCOD, 1.5 µm, incl. colloids) in total COD (TCOD) 40.5 40.5 Influent COD 420.0 420.0 good match Fraction of flocculated filtered (SCOD, wo colloids) COD in total COD (TCOD) 20.2 20.2 Calculated influent filtered COD 170.0 170.0 good match Fraction of VFA in filtered COD (SCCOD, 1.5 µm, incl. colloids) 11.8 11.8 Calculated Influent filtered flocculated COD 85.0 85.0 good match Fraction of soluble unbiodegradable organics (SU) in filtered COD (SCCOD, 1.5 µm,
11.8 11.8 Calculated influent BOD5 200.0 183.2 good match TSS 185.0 183.0 good match Influent fractions to estimate Default % To be estimated % VSS 157.0 155.3 good match Fraction of particulate unbiodegradable organics (XU) in total COD (TCOD) 14.00
14
Fraction of heterotrophs (OHO) in total COD (TCOD) 5.00 5 Fraction of endogenous products (XE) in total COD (TCOD) 20.00 20 Fraction of colloidal unbiodegradable organics (CU) in colloidal COD (SCCOD‐SCOD) 20.00 20 Fraction of N in readily biodegradable substrate (SB) 4.00 4 Fraction of N in particulate unbiodegradable substrate (XU) 1.00 1 Fraction of P in readily biodegradable substrate (SB) 1.00 1 Fraction of P in particulate unbiodegradable substrate (XU) 0.10 0.1 Particulate COD/VSS ratios by component Default To be estimated g COD/g VSS COD of biomass in volatile solids 1.42 1.42 COD of biodegradable substrate in volatile solids 1.80
1.80
COD of particulate unbiodegradable organics in volatile solids 1.30 1.30 COD of endogenous products in volatile solids 1.42 1.42 COD of PHA in volatile solids 1.67 1.67
Convertor
My model does not match data
ensors?
anity checks!!!
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automatic samplers and the averaging periods applied in the WWTP reports
sampling (Example BOD5)
sampling and filtration.
intervals are inconsistent.
interpolated.
S > VS S
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but still are of outside typical range
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Historical checks Assessing the validity of the data
hould not show large fluctuation
data.
by the commercial modeling software.
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Questions? Tanush@ dynamita.com
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Principal Engineer Hazen and Sawyer Cincinnati, OH
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clarifier performance lead to concern about available remaining process capacity
100,000 200,000 300,000 400,000 500,000 600,000 Load (ppd) Inf TSS Load Inf COD Load
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60 mgd plant is really only a 30 mgd plant
Individual Unit Process Capacity
44.0 33.2 56.8 42.2 29.1 31.0 10 20 30 40 50 60 70 Primary Clarifiers Bioreactors Secondary Clarifiers Blowers TWAS Centrifuges Anaerobic Digesters
Unit Process / Scenario
Capacity (mgd)
Prompted detailed study of influent characteristics, sampling locations and process performance
S concentrations, but more typical CBOD, NH3-N and Phosphorus concentrations
system
Raw Influent Data Year COD TSS CBOD NH3-N TP mg/L mg/L mg/L mg/L mg/L 2004 609 430 182 24.8 7.6 2005 1021 940 237 25.6 7.3 2006 715 575 252 25.6 7.5 2007 1170 1391 297 28.6 9.6 2008 1211 1186 277 30.6 9.4
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Measured PS load Calculated PS load (Pri Inf – Pri Eff)
Existing Influent Sample Location Influent Internal Recycle To Grit Removal
Grease buildup in influent box
Primary Influent Sample Downstream of Grit removal
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New Influent Sample Location New Primary Influent Sample Location Mixing (not installed) Influent Internal Recycle To Grit Removal
S ampling Location
ampling
Characterization using WERF methods for model calibration
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Influent Concentrations Parameter Original Design Historical Average Reconciled Data COD mg/ L 476 1,030 635 BOD5 mg/ L 200 266 284 TSS mg/ L 230 1,020 365 TKN mg/ L 40 42.5 43 NH3-N mg/ L 25 27.6 28.4 TP mg/ L 8 8.5 8 Wastewater COD Fractions Fraction Default Reconciled Readily Biodegradable S
0.16 0.19 Unbiodegradable S
0.05 0.03 Unbiodegradable Particulate 0.13 0.23 S lowly Biodegradable 0.66 0.55 Higher than typical inert particulate fraction
effluent, solids production, air demands, gas production
S still observed; measured BOD found to be most consistent and accurate representation
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temperatures, loading, and sludge settling properties
tream Processes able to maintain 60 mgd capacity
improvements and some operational changes to primary sludge withdrawal, and planning for additional digester capacity Lesson Learned: Representative Influent Sampling Key!
Total Influent COD CODT,INF
Biodegradable COD Slowly Biodegradable SBCOD (XS) Unbiodegradable COD Soluble Unbiodegradable SUS Particulate Unbiodegradable XUP Readily Biodegradable RBCOD (SBS) Biomass Complex SBSC SCFA SBSA Colloidal XSC Particulate XSP
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Plant rated for 143 mgd AA; 286 Peak
Plant 2 Plant 2 Plant 1 Plant 1
HPO HPO FS T FS T HPO HPO FS T FS T
Thickening Thickening Thickening Thickening Digest ion Digest ion Digest ion Digest ion
Capacity Evaluation Conceptual Design of Improvements Peak Flow Management S trategy Evaluation
Clarifier CFD Model
2
Low Cl Inf Medium Cl Inf High Cl Inf T 1&2-1 T 1&2-2 T 1&2-3 T 1&2-4 Secondary Eff T 3&4-1 T 3&4-2 T 3&4-3 T 3&4-4 T 5&6-1 T 5&6-2 T 5&6-3 T 5&6-4 Sludge to CDWWTP Low Cl Inf Medium Cl Inf High Cl Inf T 1&2-1 T 1&2-2 T 1&2-3 T 1&2-4 Secondary Eff T 3&4-1 T 3&4-2 T 3&4-3 T 3&4-4 T 5&6-1 T 5&6-2 T 5&6-3 T 5&6-4 Sludge to CDWWTPHydraulic Model
3
Process Model
1
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Plant 2 Plant 2 Plant 1 Plant 1
4 Options for Handling NWWTP Sludge:
1) WAS and PS to Headworks (split evenly between 2 plants) 2) WAS to Headworks (split evenly between 2 plants) + PS to Thickeners 3) PS to Headworks (split evenly between 2 plants) + WAS to Thickeners 4) WAS and PS to Thickeners NWWTP WAS and PS to Headworks
Limited record keeping of sludge transfer from NWWTP
‐ 100 200 300 400 500 600 Jul‐09 Nov‐09 Mar‐10 Jul‐10 Nov‐10 Mar‐11 Jul‐11 Nov‐11 Apr‐12 Aug‐12 Dec‐12 Apr‐13 Aug‐13 Dec‐13 Apr‐14 Aug‐14 Dec‐14 May‐15 Con Concentration (m (mg/L)
CDW CDWWTP In Infl fluent CBO CBOD and and TS TSS Con Concen entr tratio ion
Combined Inf CBOD Concentration Combined Inf TSS Concentration
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Headworks
composite at pump station in collection system (no NWWTP sludge)
ludge
eparate NWWTP S ludge input
NWWTP key for accurately capturing impact to Plant B influent and process
Low Cl Inf Medium Cl Inf High Cl Inf T 1&2-1 T 1&2-2 T 1&2-3 T 1&2-4 Outfall T 3&4-1 T 3&4-2 T 3&4-3 T 3&4-4 T 5&6-1 T 5&6-2 T 5&6-3 T 5&6-4 Sludge to CDWWTP Injection Wells Clarifiers 9-12 Clarifiers 1-4 Clarifiers 5-8NWWTP Sludge Production
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Wastewater COD Fractions Fraction Default Reconciled Readily Biodegradable S
0.16 0.25 VF A fraction of rbCOD 0.15 0.31 Unbiodegradable S
0.05 0.13 Unbiodegradable Particulate 0.13 0.14 S lowly Biodegradable 0.66 0.51
0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0 16.0 18.0
10 20 30 40 50 60
Inf OT 1 OT 3 OT 5 OT 6 Eff RAS TP and PO4, mg/L‐P
Nitrogen, mg/L‐N
NH3 NO3 NO2 TP PO4
Higher than typical rbCOD fraction and VF A
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multiple influent conditions:
Influent Conditions AADF cBOD5 Load TSS Load cBOD5 Concentration TSS Concentration (mgd) (ppd) (ppd) (mg/ L) (mg/ L) All NWWTP Sludge to Influent 143 269,100 363,500 226 305 NWWTP WAS to Influent, PS to Plant 2 Thickeners 143 225,700 285,100 189 239 NWWTP PS to Influent, ND WAS to Plant 2 Thickeners 143 222,400 269,200 186 226 All ND Sludge to Plant 2 Thickeners 143 178,900 190,800 150 160
Design Condition NWWTP Sludge AADF CBOD Load TSS Load CBOD Concentration TSS Concentration mgd ppd ppd mg/L mg/L Intermediate (2025) WAS to Inf.; PS to Thickeners 113 188,200 245,100 200 260 Future (2035) WAS and PS to Thickeners 143 178,900 190,800 150 160
NWWTP WAS to Headworks
S econdary Process Improvements Required:
tep Feed for HPO Trains
NWWTP WAS and PS to Plant 2 Thickeners
g 2035 143 mgd
NWWTP PS to Plant 2 Thickeners
g 2025 113 mgd
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Total Influent COD CODT,INF
Biodegradable COD Slowly Biodegradable SBCOD (XS) Unbiodegradable COD Soluble Unbiodegradable SUS Particulate Unbiodegradable XUP Readily Biodegradable RBCOD (SBS) Biomass Complex SBSC SCFA SBSA Colloidal XSC Particulate XSP
impact on process performance and plant design
electing representative sample locations is key and capturing the “ pure” raw sample
sampling to help identify data quality issues
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process and operate perfectly sized equipment in the most optimal way
afety factors are considered to size process basins and equipment due to the uncertainty and provide a “ cushion” against upsets and regulatory violations
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S maller S afety Factors and Potentially More Efficient Operations
Larger S afety Factors with Less Efficient Operations
mg/ L
removal facility
S (i.e. required regulatory monitoring data)
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sampling plan
pecifier to calculate the remainder of influent wastewater fractions
and facility design
gpd of existing residential wastewater being pumped to an existing WRRF
hour flow proportional composite sampling program
Characterization using WERF methods for model calibration (Table 21-1)
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Wastewater
concentration was higher than historical data proj ected
and Ammonia assumed to be a function of the unique characteristics
ampled COD/ TKN Ratio: 7.86 (low)
COD/ TKN (12-16) is better for denitrification
pecifier to calculate the influent fractions not sampled
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elected the design S afety Factors to account for TKN, Ammonia, and COD load variations
teady state simulations under several combinations of flows, S RT , temperatures, and loadings
Denitrification filters in addition to 2-stage MLE process
elected 2-stage MLE with Deep Bed Denitrification Filters
less than 12 mg/ L
and nutrient removal facility
fabricator
process to increase capacity and maintain reclaimed water quality standards
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plant operational data
S ampling
characterization results
concentration up to 8.20 mg/ L
conduct steady state simulations under several combinations of flows, S RT , temperatures considering:
afety Factors
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sludge rate and DO control setpoints
loadings based on revised design S afety Factors
changes and Local Limits, the WRRF consistently meets all reclaimed water quality requirements and fully treats the inst itutional and industrial loadings
MGD TMADF
TMADF
water and nutrient removal facility
requirements less than 12 mg/ L
combined-cycle power generation facility to discharge cooling tower blow-down water into treatment facility
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plant operational data
at treatment facility and cooling tower blow-down water
blowdown water
afety Factors to account for TKN, Ammonia, COD, and TDS load variations based on Influent Characterization
due to potential biological inhibition
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Moderator John Copp Primodal Theory Chris Bye EnviroSim Methods Tanush Wadhawan Dynamita Application Alyssa Mayer Hazen & Sawyer Application Matt Tebow Kimley-Horn