Summary of PFAS sampling for Maine public water systems Maine CDC - - PDF document

summary of pfas sampling for maine public water systems
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Summary of PFAS sampling for Maine public water systems Maine CDC - - PDF document

Summary of PFAS sampling for Maine public water systems Maine CDC Drinking Water Program October 2019 This document presents a preliminary DRAFT summary of the 2019 voluntary sampling program for per- and polyfluoroalkyl substances (PFAS) in


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Summary of PFAS sampling for Maine public water systems Maine CDC Drinking Water Program October 2019 This document presents a preliminary DRAFT summary of the 2019 voluntary sampling program for per- and polyfluoroalkyl substances (PFAS) in public water systems in Maine. The sampling program was coordinated by the Maine Center for Disease Control & Prevention (CDC) Drinking Water Program (DWP). The DWP designed this voluntary sampling program based on currently known or suspected sources of

  • PFAS. The 2019 sampling round follows two previous programs in Maine, including the Unregulated

Contaminants Monitoring Rule (UCMR) sampling of 17 system conducted by the US Environmental Protection Agency (EPA) between 2013 and 2015 and a DWP-initiated voluntary sampling program that included 17 systems in 2017. The objective of the 2019 sampling program was to further refine our understanding of potential PFAS impacts to public drinking water supplies in Maine. PFAS are not regulated under the Safe Drinking Water Act (SDWA) and therefore have no federally-established Maximum Contaminant Level (MCL) that would require action such as treatment to remove these compounds from drinking water. EPA has established a Health Advisory of 70 parts per trillion (ppt), combined, for two PFAS compounds: perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS). For the 2019 sampling program, a total of 36 public water systems were identified as having potential risk factors for impacts from PFAS. Risk factors included the following:

  • proximity to airports;
  • proximity to known use of firefighting foam;
  • nearby landfills;
  • papermill activity;
  • septic leach fields within 100 feet of a school well source; and
  • proximity to biosolids processing facilities or documented sludge spreading operations.

Sampling was conducted by an independent contractor, Sevee & Maher Engineers, Inc. (SME) of Cumberland, Maine according to currently accepted best practices for PFAS sample collection. Samples were analyzed using EPA Method 537.1 by Alpha Analytical, Inc. laboratory in Portsmouth, NH. An unanticipated outcome of the 2019 sampling program was that out of the 36 systems selected for sampling, 17 public water systems declined to participate. Although there was no cost to the systems, we can assume that these water systems were concerned about potential costs or other challenges that may have resulted from finding PFAS in their water supply. Of the 19 systems sampled for PFAS in 2019, nine (9) were found to have measurable detections of PFAS. However, there were no detections of PFOA and PFOS in exceedance of the current EPA Health Advisory

  • f 70 parts per trillion (ppt) combined. In addition, the highest levels of PFOA and PFOS measured as

individual compounds (10.2 and 5.2 ppt, respectively) are below the levels set recently as State MCLs by the State of New Hampshire (PFOA NH MCL = 12 ppt, PFOS NH MCL = 15 ppt). The remaining 10 public

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water systems tested for PFAS had no detections for any of the 18 compounds included in EPA Method 537.1. It is notable that there were no PFAS detections at systems that were selected based on proximity to sludge spreading sites. The following table summarizes detections only for the 2019 PFAS sampling program. Note that out of 18 PFAS compounds analyzed, only seven (7) were detected at any of the water systems included in this program.

Table 1 PFAS Detections in Public Water Systems for 2019 Voluntary Sampling Round Maine CDC Drinking Water Program Public Water Supply Name Potential PFAS Source Compound Perfluoro butane Sulfonate (PFBS) Perfluoroheptanoic Acid (PFHPA) Perfluorohexane Sulfonate (PFHXS) Perfluorohexanoic Acid (PFHXA) Perfluorooctanesulfonic Acid (PFOS) Perfluorooctanoic Acid (PFOA) N-Ethyl Perfluorooctane Sulfonamide, N-Ethyl Perfluorooctanesulfonamidoacetic Acid (NETFOSAA) Estes Lake Mobile Home Park Airport ND1 ND ND ND 2.222 ND ND Pine Ridge Hunton Brook Association Fire Fighting Foam Use near well ND ND ND ND ND 3.59 ND Charter Oak Mobile Home Village Landfill ND ND ND 2.38 ND 3.01 ND The Pines at Arundel Landfill ND ND ND 2.22 ND 2.65 ND Mexico Water District Aerial Deposition from Papermill ND ND ND ND ND ND 2.07 AOS 98 Georgetown Central School Septic leach field at 100' or less 12.1 ND ND ND ND 3.06 ND Fayette Central School Septic leach field at 100' or less ND ND ND ND ND 2.06 ND

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Pejepscot School- Topsham Septic leach field at 100' or less 2.07 ND 3.17 3.67 5.17 5.1 ND LISBON WATER DEPARTMENT Superfund Site 3.26 2.69 5.73 4.51 ND 10.2 ND

1ND = Non-Detect, or below the Reporting Limit Required by Method 537.1 2Values expressed as nanograms per liter or parts per trillion (ppt).

The combined sampling efforts mentioned in this document (EPA UCMR in 2013-2015, Maine DWP in 2017 and Maine DWP in 2019) have resulted in analysis of drinking water samples for PFAS concentration in a total of 53 public water systems in Maine. These system represent more than 60%

  • f the population served by Community water systems. Maine has approximately 378 regulated

Community water systems (water systems that serve people in their homes on a year-round basis); 375 non-transient non-community systems (these include schools and businesses); 1,151 transient systems (these include restaurants and campgrounds); and 54 regulated bottled water

  • sources. More than half of Maine’s residents are not served by public water systems but instead

use private residential wells as their primary drinking water source. Due to the high percentage of public water systems declining to participate in 2019, we are currently discussing whether to perform additional voluntary PFAS sampling or to consider another approach to generate a robust and meaningful dataset. The estimated cost to sample the remaining Community water systems (approximately 325) would be significant (estimated at $115,500-$231,000) and would likely need to be shared by the water systems and their ratepayers. The attached Appendix contain tables listing all laboratory analytical results generated from DWP’s 2019 voluntary sampling program. Data from previous sampling rounds can be provided upon request. Questions and comments concerning this document can be directed to: Michael Abbott, P.E., C.G. Drinking Water Program Manager 207-287-5684 michael.abbott@maine.gov

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APPENDIX A LABORATORY ANALYTICAL DATA SPREADSHEET 2019 PFAS SAMPLING ROUND

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29420-43-3 307-24-4 13252-13-6 375-85-9 355-46-4 919005-14-4 335-67-1 375-95-1 1763-23-1 335-76-2 756426-58-1 2355-31-9 2058-94-8 2991-50-6 307-55-1 763051-92-9 72629-94-8 376-06-7 Perfluorobutane Sulfonate (PFBS) PERFLUOROHEXANOI C ACID (PFHxA) Hexafluoropropylene

  • xide dimer acid

(HFPO-DA, GenX) PERFLUOROHEPTAN OIC ACID (PFHpA) Perfluorohexane Sulfonate (PFHxS) 4,8-dioxa-3H- perfluorononanoic acid (ADONA) PERFLUOROOCTANOI C ACID (PFOA) PERFLUORONONANO IC ACID (PFNA) PERFLUOROOCTANES ULFONIC ACID (PFOS) PERFLUORODECANOI C ACID (PFDA) 9- chlorohexadecafluor

  • -3-oxanone-1-

sulfonic acid (9Cl- PF3ONS) N-Methyl Perfluorooctanesulfo namidoacetic Acid (NMeFOSAA) Perfluoroundecanoic Acid (PFUnA) N-Ethyl perfluorooctane sulfonamide, N-Ethyl Perfluorooctanesulfo namidoacetic Acid (NEtFOSAA) PERFLUORODODECA NOIC ACID (PFDoDA) 11- chloroeicosafluoro-3-

  • xaundecane-1-

sulfonic acid (PF3OUdS) Perfluorotridecanoic Acid (PFTrDA) Perfluorotetradecano ic Acid (PFTA) PWSID PWS Name Potential PFAS Source ME0095575 BOUDREAU TRAILER PARK Airport Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out ME0002809 ESTES LAKE MOBILE HOME PARK Airport ND ND ND ND ND ND ND ND 0.00222 ND ND ND ND ND ND ND ND ND ME0095585 PINE RIDGE HUNTON BROOK ASSOCIATION Fire Fighting Foam Use near well ND ND ND ND ND ND 0.00359 ND ND ND ND ND ND ND ND ND ND ND ME0090020 ALFRED WATER DISTRICT Landfill ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ME0001006 CHARTER OAK MOBILE HOME VILLAGE Landfill ND 0.00238 ND ND ND ND 0.00301 ND ND ND ND ND ND ND ND ND ND ND ME0094474 MSAD 31 ENFIELD STATION ELEMENTARY Landfill Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out ME0091110 NORRIDGEWOCK WATER DISTRICT Landfill ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ME0092722 Silver Lake Estates Landfill Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out ME0095659 THE PINES AT ARUNDEL Landfill ND 0.00222 ND ND ND ND 0.00265 ND ND ND ND ND ND ND ND ND ND ND ME0090970 MEXICO WATER DISTRICT Aerial Deposition from Papermill ND ND ND ND ND ND ND ND ND ND ND ND ND 0.00207 ND ND ND ND ME0090990 MAINE WATER COMPANY MILLINOCKET DIVISION Papermill ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ME0091380 RUMFORD WATER DISTRICT Aerial Deposition from Papermill Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out ME0093813 AOS 98 GEORGETOWN CENTRAL SCHOOL Septic leach field at 100' or less 0.0121 ND ND ND ND ND 0.00306 ND ND ND ND ND ND ND ND ND ND ND ME0018680 BIG CATS CATERING- TINY TYKES DAYCARE Septic leach field at 100' or less Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out ME0000242 FAYETTE CENTRAL SCHOOL Septic leach field at 100' or less ND ND ND ND ND ND 0.00206 ND ND ND ND ND ND ND ND ND ND ND ME0004600 PEJEPSCOT SCHOOL- TOPSHAM Septic leach field at 100' or less 0.00207 0.00367 ND ND 0.00317 ND 0.0051 ND 0.00517 ND ND ND ND ND ND ND ND ND ME0092347 THE GREAT ADVENTURE DAYCARE CENTER Septic leach field at 100' or less ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 0.01 µg/L 0.01 µg/L 0.01 µg/L 0.05 µg/L 0.05 µg/L CAS # Reporting Limit Required by Method 537.1 0.01 µg/L 0.01 µg/L 0.05 µg/L 0.05 µg/L 0.05 µg/L 0.01 µg/L 0.01 µg/L 0.01 µg/L 0.01 µg/L 0.01 µg/L 0.01 µg/L 0.01 µg/L 0.01 µg/L Compound

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29420-43-3 307-24-4 13252-13-6 375-85-9 355-46-4 919005-14-4 335-67-1 375-95-1 1763-23-1 335-76-2 756426-58-1 2355-31-9 2058-94-8 2991-50-6 307-55-1 763051-92-9 72629-94-8 376-06-7 Perfluorobutane Sulfonate (PFBS) PERFLUOROHEXANOI C ACID (PFHxA) Hexafluoropropylene

  • xide dimer acid

(HFPO-DA, GenX) PERFLUOROHEPTAN OIC ACID (PFHpA) Perfluorohexane Sulfonate (PFHxS) 4,8-dioxa-3H- perfluorononanoic acid (ADONA) PERFLUOROOCTANOI C ACID (PFOA) PERFLUORONONANO IC ACID (PFNA) PERFLUOROOCTANES ULFONIC ACID (PFOS) PERFLUORODECANOI C ACID (PFDA) 9- chlorohexadecafluor

  • -3-oxanone-1-

sulfonic acid (9Cl- PF3ONS) N-Methyl Perfluorooctanesulfo namidoacetic Acid (NMeFOSAA) Perfluoroundecanoic Acid (PFUnA) N-Ethyl perfluorooctane sulfonamide, N-Ethyl Perfluorooctanesulfo namidoacetic Acid (NEtFOSAA) PERFLUORODODECA NOIC ACID (PFDoDA) 11- chloroeicosafluoro-3-

  • xaundecane-1-

sulfonic acid (PF3OUdS) Perfluorotridecanoic Acid (PFTrDA) Perfluorotetradecano ic Acid (PFTA) PWSID PWS Name Potential PFAS Source 0.01 µg/L 0.01 µg/L 0.01 µg/L 0.05 µg/L 0.05 µg/L CAS # Reporting Limit Required by Method 537.1 0.01 µg/L 0.01 µg/L 0.05 µg/L 0.05 µg/L 0.05 µg/L 0.01 µg/L 0.01 µg/L 0.01 µg/L 0.01 µg/L 0.01 µg/L 0.01 µg/L 0.01 µg/L 0.01 µg/L Compound ME0009244 BEGIN TRAILER PARK Sludge Utilization Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out ME0007363 CEDAR HAVEN MOBILE HOME PK Sludge Utilization Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out ME0002893 CRYSTAL SPRING MOBILE HOME PK Sludge Utilization ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ME0090640 GUILFORD- SANGERVILLE WATER DISTRICT Wood Ash Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out ME0090880 LIVERMORE FALLS WATER DISTRICT Sludge Utilization ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ME0090900 LUBEC WATER DISTRICT Sludge Utilization ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ME0006735 MARSHWOOD ESTATES Sludge Utilization Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out ME0194250 MCCAIN FOODS, INC - COLD STORAGE Sludge Utilization Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out ME0092397 MSAD 06 BUXTON CENTER ELEMENTARY SCHOOL Sludge Utilization Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out ME0093804 MSAD 06 FRANK JEWETT SCHOOL Sludge Utilization Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out ME0007367 PINE CONE MOBILE HOMES CT #1 Sludge Utilization ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ME0091270 PINELAND CENTER CAMPUS MSAD 15 Sludge Utilization ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ME0000637 RSU 03 TROY CENTRAL SCHOOL Sludge Utilization Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out ME0000556 RSU 19 ST ALBANS CONSOLIDATED SCHOOL Sludge Utilization Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out ME0091470 SOUTH BERWICK WATER DISTRICT Sludge Utilization ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ME0009171 WEST VILLAGE MOBILE HOME PARK# Active Industrial Site Nearby Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out ME0090870 LISBON WATER DEPARTMENT Superfund Site 0.00326 0.00451 ND 0.00269 0.00573 ND 0.0102 ND ND ND ND ND ND ND ND ND ND ND ME0092305 CORINNA WATER DISTRICT Superfund Site; associated landfill PFAS impacted Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out ME0095340 MAPLE RIDGE MOBILE HOME PARK Superfund Site; associated landfill PFAS impacted Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out Opted Out