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Solutions: permission of the owners. NJCTL maintains its website - - PDF document

Slide 1 / 39 Slide 2 / 39 New Jersey Center for Teaching and Learning Progressive Science Initiative This material is made freely available at www.njctl.org and is intended for the non-commercial use of students and teachers. These materials


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This material is made freely available at www.njctl.org and is intended for the non-commercial use of students and teachers. These materials may not be used for any commercial purpose without the written permission of the owners. NJCTL maintains its website for the convenience of teachers who wish to make their work available to other teachers, participate in a virtual professional learning community, and/or provide access to course materials to parents, students and others.

Click to go to website: www.njctl.org New Jersey Center for Teaching and Learning Progressive Science Initiative

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www.njctl.org

Solutions: Mixtures, Solubility and Concentration

Slide 3 / 39 Solutions

The infamous saltwater crocodile cannot survive in freshwater. It needs a mixture of water and many solutes.

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Mixtures vs. Pure Substances

Mixtures contain two or more pure substances. Mixtures do not

  • bey the law of definite composition therefore the relative

amounts of each substance can vary depending on the sample. Pure water Salt water H2O contains H2O, Ca2+, Cl-, Na+..... 89% O, 11% H composition by mass varies chemical separation method physical All mixtures can be separated using physical means while most pure substances cannot with the exception of thermal decomposition of certain pure substances such as metal carbonates and metal chlorates. What are some methods for physically separating mixtures?

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Mixtures

Mixtures are classified as suspensions, colloids, or solutions based on particle size. Suspension Colloid Solution Particle Size

> 1000 nm 1000 nm <-->1 nm

< 1 nm Settling Yes No No Homogenous No Yes

Yes

Tyndall Effect (particles scatter light) Yes Yes No Given the similarity between colloids and solutions, the Tyndall effect is often key to distinguishing them apart. Click here to see a short animation of the Tyndall Effect

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Suspensions

Due to their large particle size, suspensions can often be separated by filtration. When precipitates form a mixture of aqueous solutions, a suspension is created with the solid precipitate settling out in an aqueous medium. The solid precipitate can be easily separated by proper filtration. filtration precipitate + Other examples of suspensions include sand in water and snow in air.

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SLIDE 2

Slide 7 / 39 Colloids

Due to their smaller particle size, colloids cannot be separated by filtration. In addition, the particles neither settle nor dissolve in the greater medium. Fog is a classic example of a colloid, as the water droplets neither dissolve in the surrounding gaseous medium nor do they settle out. The Tyndall Effect is easy to see when driving through fog as the light from the headlights gets scattered by the particles as visualized below by sunshine on a foggy morning.

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Solutions

Solutions contain the smallest solute particles that dissolve in a medium called the solvent. Solutions are homogeneous mixtures because regardless of sample size, the ratio of solute particles to solvent remains the same. If you took a 5mL sample or a 200mL sample of a solution you would find the exact same ratio of solute to solvent.

Uniform mixture of solute (purple) and solvent (green)

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Solutions

Solutions contain the smallest solute particles that dissolve in a medium called the solvent. Solutions are homologous mixtures because regardless of sample size, the ratio of solute particles to solven remains the same. Salt water is a classic example of a solution. The Na+ and Cl- ions are dissolved in the solvent, creating a uniform material.

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Cl- Cl- Cl- Na+ Na+

Due to their small size and interactions with the solvent, the solute particles cannot be filtered out. How could you physically separate solutes from solvents in a solution?

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1 Which of the following would be TRUE regarding mixtures? A A sample of a mixture will never be uniform in composition B They can be typically separated using only chemical methods C They vary in composition from sample to sample. D Only solutions are considered true mixtures E None of these are true

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2 A mixture cannot be separated by filtration and does not demonstrate the Tyndall Effect. Which of the following could this mixture be? A NaCl(s) B NaCl(aq) C Sand dissolved in water D Fog in the air E Pure water

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3 Which of the following physical methods is often employed to separate a suspension? A Distillation B Filtration C Evaporation D Chromatography E Lithography

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SLIDE 3

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4 Which of the following would NOT be TRUE of a solution? A There are no interactions between the solute and the solvent B Solutions cannot be separated by filtration C A sample of a solution will be uniform in composition D Solutions have smaller particles than do colloids and suspensions E Solutions do not demonstrate the Tyndall Effect

Slide 14 / 39 Solubility

The solubility of a solute is defined as the amount of solute that can dissolve in a certain quantity of solvent. The solubility of a solute depends on its state and its affinity for the solvent. Solubility is commonly expressed as g solute/100 g of solvent. Substance Solubility in water @23 C CH3OH infinite CH3Cl 0.47 g/100 g water CCl4 0.081 g/100 g water

Note: The more polar the molecule, the more affinity for water as it is also polar. CCl4 is non-polar and therefore has an extremely small solubility in water. The phrase "like dissolves like" is applicable here.

Slide 15 / 39 Solubility

The solubility of a solute in a solvent is highly temperature

  • dependent. In general, solids and liquids dissolve better at higher

temperatures while gases are more soluble at lower temperatures. Solubility of NaCl (g/100g water) at different temperatures. 0 C 10 C 50 C 80 C 100 C 35.65 35.72 36.69 37.93 38.99 Solubility of NH3 gas (mL/100 mL water) at different temperatures. 0 C 10 C 50 C 80 C 100 C 11.7 9.0 3.33 1.38 0.88

Note: The decrease in gas solubility with temperature can be explained by remembering that if the gas molecules have a high kinetic energy, they are likely to weaken any solute -solvent attraction and escape the solution.

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5 Which of the following would likely be the LEAST soluble in water? A CO2 B HCl C PH3 D CHCl3 E CH3OH

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6 Which of the following would be most likely to dissolve in hexane (C6H14)? A CH3OH B H2O C Br2 D CH2Cl2 E NaCl

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7 Which of the following is TRUE regarding solubility? A O2 gas would be more soluble at 10 C than 20 C B Polar substances are most miscible in non-polar solvents C In general, as the temperature increases, the solubility of most solids decrease D Solubility is not temperature dependent E Solubility is not dependent on the polarity of the solute or solvent

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SLIDE 4

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8 Which of the following would NOT be a miscible pair of solute and solvent? A KOH and H2O B CCl4 and C6H6 C CH3OH and H2O D CH3OH and CH3CH2OH E CH3OH and CCl4

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Solubility

Saturated solutions contain the maximum dissolved solute at that

  • temperature. Unsaturated solutions contain less and

supersaturated solutions contain more. Unsaturated Saturated Supersaturated In a saturated solution, undissolved solute and dissolved solute are in equilibrium. In an unsaturated solution any new solute will dissolve whereas in a supersaturated solution, the amount of undissolved solute is growing.

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Solubility Curves

A solubility curve shows how much solute can dissolve in a certain amount of solvent at a given temperature. The line represents the amount of solute necessary for the dissolved and undissolved amounts to be in equilibrium - a saturated solution. Below the line the solution is unsaturated and above the line the solution is supersaturated.

Temperature in Celsius

Slide 22 / 39 Solubility Curves

The solubility curve for a given salt is difficult to predict.

Solubility, grams per 100mL H

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Solubility Curves

The solubility curves for gases clearly show the inverse relationship of gas solubility and temperature. Note: Cooler streams have higher dissolved oxygen (DO) levels than warmer streams therefore supporting a different variety of life.

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Solubility Curves

The solubility of a gas also depends on the pressure. The higher the partial pressure of that gas above the liquid, the greater the

  • solubility. This is known as Henry's Law.

We can view the dissolved gas and undissolved gas above a solution as an equilibrium situation. Gas(dissolved) <--> Gas (undissolved) If the partial pressure of the undissolved gas is increased above a liquid, the equilibrium will shift left and more gas will dissolve. Gas(dissolved) <--> Gas (undissolved)

Note: This is how soft drink manufacturers carbonate your soda. They simply crank up the partial pressure of CO2 above the liquid and that causes more CO2 to dissolve. They then smack a lid on top so the pressure is maintained.

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SLIDE 5

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9 The curve to the right best represents the solubility curve for A KI B C6H12O6 C CO2 D NaCl E None of these

Solubility (g/ 100g H2O)

Temperature

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10 How many moles of NaCl would dissolve in a saturated solution containing 450 g of water @10 C. Assume the solubility of NaCl is 35.72 g/100 g water @10 C.

Temperature in Celsius

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11 Using the solubility curve below, how many grams of solute could be recrystallized if the temperature is dropped from 50 C to 20 C?

Temperature in Celsius

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12 Under which set of conditions will a gas dissolve best? A High Temp, High Pressure B Low Temp, High Pressure C Low Temp, Low Pressure D High Temp, Low Pressure

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13 Which of the following explain why a soda will become flat over time at a given temperature if left

  • pen?

A Once opened, the partial pressure has diminished above the liquid thereby lowering the solubility B The polarity of the gas changes as the pressure changes C The CO2 gas is replaced by other less bubbly gases D CO2 is polar

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14 As the temperature increases, what must be true

  • f the partial pressure of a gas above a liquid in
  • rder to maintain the same solubility of that gas

in the liquid? A It must be increased B It must be decreased C It has no influence, temperature plays the dominant role

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Solution Concentration

There are many ways to express the amount of solute dissolved in a solvent. Common Concentration Units Molarity (M) = mol solute/L solution Molality (m) = mol solute/kg solvent Mole Fraction (X) = nsolute/ntotal % by volume = Vsolute/Vsolution % by mass = gsolute/gtotal Molarity is temperature dependent unlike the others. How would increasing the temperature of a solution affect its Molarity (M)?

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15 What is the molarity of an aqueous NaCl solution @10 C assuming a solubility of 45.72 g NaCl/100 g water?Assume a density of 1g/mL of water.

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16 How many moles of OH- ion are present in a 100 mL aqueous solution of 0.5 M Mg(OH)2?

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17 How many mL of water must have evaporated from a 200 mL 0.3 M HCl solution to produce a 0.5 M solution of HCl?

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18 A solution consisting of ethanol (CH3CH2OH) and water is 25% ethanol by mass. What is the molality of this solution?

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19 An aqueous NaCl solution is heated. Assuming no evaporation of the solvent, which of the following will be TRUE? A The molarity will increase B The molarity will decrease C The molality will decrease D The molality will increase E The mole fraction of solute will decrease

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20 What is the mole fraction of an aqueous 200 mL solution that is 0.45 M CH3OH. Assume the density of the solution is 1.03 g/mL.

Slide 38 / 39 In the next section, we will examine the dissolving process and how this influences the many properties of a solution.... Slide 39 / 39