High recovery rate solar driven reverse osmosis and membrane distillation plants for brackish groundwater desalination in Egypt
A Nashed Supervisors: A.B Sproul and G Leslie
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High recovery rate solar driven reverse osmosis and membrane distillation plants for brackish groundwater desalination in Egypt A Nashed Supervisors: A.B Sproul and G Leslie Main Investigation Why decentralized high recovery rate solar
High recovery rate solar driven reverse osmosis and membrane distillation plants for brackish groundwater desalination in Egypt
A Nashed Supervisors: A.B Sproul and G Leslie
Egypt Total Oil Production and Consumption from 2000 to 2011
Source: U.S. Energy Information Administration (2013)
400 500 600 700 800 900 1000 1990 1995 2000 2005 2010
Thousand Barrels per Day
Oil Consumption Oil Production
70% 26% 2% 2% 0% Nile Water Nile Water Re-use Groundwater Extraction (Rainfall + Fossil) Treated Waste Water Seawater Desalination
10 20 30 40 50 60 Nile Water Nile Water Re-use (Inc. Waste Water) Groundwater Seawater Desaliantion Billion m³/year Available Used
Africa Flat Plate Tilted at Latitude Annual Solar Irradiance (kWh/m²/day) Source: (Solar and Wind Energy Resource Assessment (SWERA, 2005)
0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 Utility Scale Ground Mounted PV Systems (>1 MW) Small Scale PV Systems ( < 10 kW) Parabolic Trough with thermal storage (100MW) Concentrated PV Fresnel Collectors (100MW) Power Tower with thermal storage (100MW) Parabolic Trough without thermal storage (100MW) LCOE (USD/kWh)
Spiral wound RO membrane (Brennan,2001) (Water Quality Association,2008)
PV System BW Well RO Plant Permeate Tank Deep Injection Well Water Line Electricity Line Concentrate Permeate Water
20-40 g/l 2-10 g/l ≈ 0.5 g/l
BW Well PV System RO Plant Permeate Tank
50 55 60 65 70 75 80 85 90 95 100 2000 4000 6000 8000 10000 Water Recovery Rate (%) Feed Water Salinity (mg/l) Max RO RR (Design Limited) at 20-40°C Max RR pH=6 Low Scaling Potential GW Max RR pH=6 High Scaling Potential GW Max RR pH=6 Typical Composition GW
0.5 1 1.5 2 2.5 2000 4000 6000 8000 10000 15000 20000 LCOW ($/m³) Feed Water Salinity (mg/l) Diesel Genset (Subsidized Diesel) Day Only Diesel Genset (Unsubsidized Diesel) Day Only PV-RO Day Only
0.5 1 1.5 2 2.5 LCOW ($US/m³) Feed Water Salinity (mg/l) Diesel Genset (Sub. Diesel) Diesel Genset (Unsub. Diesel) PV-RO Daytime 0.5 1 1.5 2 2.5 LCOW ($US/m³) Feed Water Salinity (mg/l) Diesel Genset (Sub. Diesel) Diesel Genset (Unsub. Diesel) PV-RO 24 Hours
0.5 1 1.5 2 2.5 2000 4000 6000 8000 10000 LCOW ($/kWh) Feed Water Salinity (mg/l) Low Irrad. Zone/Unconfined Aquifer (10 m) High Irrad. Zone/ Confined Nubian Aquifer in Eastern Desert and Western Desert (20 m) High Irrad. Zone/ Unconfined Aquifer (50 m) Low Irrad. Zone/Unconfined Aquifer (50 m) High Irrad. Zone/ Confined Nubian Aquifer in the Sinai Peninsula (200 m)
1 2 3 4 5 6 7 2000 4000 6000 8000 10000 SEC (kWh/m³) GW Salinity (mg/l) Low Irrad. Zone/Unconfined Aquifer (10 m) High Irrad. Zone/ Confined Nubian Aquifer in Eastern Desert and Western Desert (20 m) High Irrad. Zone/ Unconfined Aquifer (50 m) Low Irrad. Zone/Unconfined Aquifer (50 m) High Irrad. Zone/ Confined Nubian Aquifer in the Sinai Peninsula (200 m)
1 2 3 4 5 6 7 8 Nominal IR Batt. Cost BOS Costs (inc. Inv) PV Mod. Cost BOS Costs (excl. Inv) Indirect Costs Inverter cost Percentage Variation in LCOW
PV-RO LCOW is only 2 to 5% higher than that of DG-RO
a PV-RO clearly more economical
5 10 15 20 100 150 200 Difference between PV-RO and DG-RO LCOW (%) Battery Bank Specific Cost ($US/kWh) High Irrad. Zone/ Confined Nubian Aquifer in Eastern Desert and Western Desert (20 m) High Irrad. Zone/ Unconfined Aquifer (50 m) High Irrad. Zone/ Confined Nubian Aquifer in the Sinai Peninsula (200 m) Low Irrad. Zone/Unconfined Aquifer (50 m) Low Irrad. Zone/Unconfined Aquifer (10 m)
5 10 15 20 25 30 35 40 2000 4000 6000 8000 10000 Percentage Reduction in RO Plant Power Consumption Water Salinity (mg/l) 20°C Design 30°C Design
0.5 1 1.5 2 2.5 3 3.5 4 10000 20000 RO SEC (kWh/m³) Water Salinity (mg/l) 20°C Design 30°C Design 40°C Design
Main PVT Collectors BW Well RO Plant Permeate Tank Deep Injection Well Concentrate Permeate Water
Collectors Water Line Electricity Line
1 2 3 4 5 6 7 2000 4000 6000 8000 10000 Percentage Increase in the Annual PV Yield Feed Water Salinity (mg/l) Low Irrad. Zone/Unconfined Aquifer (50 m) Low Irrad. Zone/Unconfined Aquifer (10 m) High Irrad. Zone/ Confined Nubian Aquifer in the Sinai Peninsula (200 m) High Irrad. Zone/ Unconfined Aquifer (50 m) High Irrad. Zone/ Confined Nubian Aquifer in Eastern Desert and Western Desert (20 m)
1 2 3 4 5 6 7 2000 4000 6000 8000 10000 Percentage Reduction in RO Plant Annual Energy Requirements Feed Water Salinity (mg/l) High Irrad. Zone/ Confined Nubian Aquifer in Eastern Desert and Western Desert (20 m) Low Irrad. Zone/Unconfined Aquifer (10 m) High Irrad. Zone/ Unconfined Aquifer (50 m) Low Irrad. Zone/Unconfined Aquifer (50 m) High Irrad. Zone/ Confined Nubian Aquifer in the Sinai Peninsula (200 m)
0.5 1 1.5 HSI Zone 20 m (2,000 mg/l GW) HSI Zone 200 m (2,000 mg/l GW) LSI Zone 50 m (6,000 mg/l GW) LCOW ($/m³) PV-RO PVT-RO
Largest PV Yield Annual Energy Increase Largest RO Plant Energy Increase Largest Net Energy Saving
variability of solar irradiance a percentage reduction in the RO plant annual energy consumption not exceeding 6.6% in comparison to values up to approximately 30% if the water was continuously heated to 40°C
required PV cell area while had a negligible impact on the battery bank capacity required
collectors will incur no additional costs, the decrease in the LCOW did not exceed 2%
20 30 40 50 60 70 6 8 10 12 14 16 18 20 PV Cell Temperature (°C) Hours Main PVT Collectors Auxiliary Collectors Standard PV Array
1- Hot feed water flow 2- Cold water flow mixed with distillate 3- Water vapour molecules 4- Hydrophobic membrane material 5- Vapour-Liquid Interface 6- Membrane Pore
Source: (Winter et al., 2011)
5 10 15 20 25 30 15 20 25 30 35 40 45 Permeate Flow Rate (kg/h) Cooling Channel Inlet Temperature (°C) 0 g/kg 35 g/kg 75 g/kg 105 g/kg Calc. Values
(a)
100 150 200 250 300 350 400 15 20 25 30 35 40 45 SHC (kWh/m³) Cooling Channel Inlet Temperature (°C)
(b)
0 g/kg 35 g/kg 75 g/kg 105 g/kg Calc. Values
PV System BW Well RO Plant
Permeate Tank
Water Line Electricity Line RO Concentrate RO Permeate Deep Injection Well MD Feed Tank FPC-MD Plant MD Concentrate MD Permeate
50 55 60 65 70 75 80 85 90 95 100 2000 4000 6000 8000 10000 Water Recovery Rate (%) Feed Water Salinity (mg/l) Max RO RR (Design Limited) at 20-40°C Max RR pH=6 Low Scaling Potential GW Max RR pH=6 High Scaling Potential GW Max RR pH=6 Typical Composition GW
75 80 85 90 95 100 2000 4000 6000 8000 10000 Recovery Rate (%) GW Salinity (mg/l) Max RO RR (Design Limited) at 20-40°C Expected Max. Attainable RR (Simple Pre-treatment) Actual . Attainable RR (Simple Pre-treatment) Actual Max. Attainable RR (Further Pre-treatment)
50 100 150 200 250 4 8 12 16 20 24 Water Salinity (g/kg)/Water Mass (1,000 kg) Operating Hours Stored Brine Mass (2.2% Evaporation) Brine Salinity (2.2% Evaporation Losses) Stored Brine Mass (No Evaporation Losses) Brine Salinity (No Evaporation Losses)
75 80 85 90 95 100 2 4 6 8 10 12 14 16 18 20 Recovery Rate (%) GW Salinity (g/l) PGMD MEMSYS (Brine as Coolant) MEMSYS (Additional GW as Coolant)
20 40 60 80 100 120 50 60 70 80 90 100 110 7:00 9:00 11:00 13:00 15:00 17:00 19:00 21:00 23:00 1:00 3:00 5:00 7:00
Irradiance (0.1 W/m²)/Flow Rate (kg/h) Water Temperature (°C) Time HX2 Hot Side Inlet Temperature (THX2) Tank Top Temperature Evaporator Inlet Temperature (Te,in) Tank Bottom Temperature Collector Exit Water Temperatue (Tcoll) Permeate Flow Rate Global Tilted Irradiance
Heat Storage Tank Charging Heat Storage Tank discharging
A C D E F B
2 4 6 Confined Nubian Aquifer in Eastern Desert and Western Desert (20 m) 2 g/l GW Unconfined Aquifer (50 m) 2 g/l GW Confined Nubian Aquifer in the Sinai Peninsula (200 m) 2 g/l GW Confined Nubian Aquifer in Eastern Desert and Western Desert (20 m) 10 g/l GW Unconfined Aquifer (50 m) 10 g/l GW Confined Nubian Aquifer in the Sinai Peninsula (200 m) 10 g/l GW LCOW (USD/m³) Hybrid Plant RO Plant
27% 22% 11% 9% 9% 7% 6% 6% 2% 1% 0% FPC Indirect Costs MD Modules Heat Exchangers Installation Heat Storge Tank PV System Costs Instrumentation FPC Racking Module Housing Piping & Tanks
0.00 10.00 20.00 30.00 40.00 50.00 Solar Waste Heat Available + 2x MD Module Heat Energy Reduction + 2x MD Module Flux Increase + 100 USD/m² Module Cost Solar Waste Heat Available + 4x MD Module Heat Energy Reduction + 100 USD/m² Module Cost Solar Waste Heat Available + 4x MD Module Flux Increase +100 USD/m² Module Cost Solar Waste Heat Available + 2x MD Module Heat Energy Reduction + 2x MD Module Flux Increase Solar Waste Heat Available + 4x MD Module Flux Increase 4x MD Module Heat Energy Reduction + 100 USD/m² Module Cost Solar Waste Heat Available + 100 USD/m² Module Cost Solar Waste Heat Available + 4x MD Module Heat Energy Reduction 2x MD Module Heat Energy Reduction + 2x MD Module Flux Increase + 100 USD/m² Module Cost 2x MD Module Heat Energy Reduction + 2x MD Module Flux Increase 4x MD Module Heat Energy Reduction Solar Waste Heat Available 4x MD Module Flux Increase + 100 USD/m² Module Cost 4x MD Module Flux Increase 100 USD/m² Module Cost Base Case LCOW (USD/m³) 10 g/l GW 2 g/l GW
a hybrid RO/MD plant with a corresponding significant increase in the LCOW
have a significant impact on the maximum attainable RR from a hybrid RO/MD plant even with enhanced MD process configurations
RO/MD plant, higher recovery rate MD modules with low cooling requirements are needed
feasible if a source of a waste heat is available from a CPV or a CSP plant, the SHC of the process is reduced by 4 folds and the MD module costs become similar to that of an RO module
BILBAO, J. & SPROUL, A. B. 2012, Analysis of Flat Plate Photovoltaic-Thermal (PVT) Models, World Renewable Energy Forum (WREF) Including World Renewable Energy Congress XII and Colorado Renewable Energy Society (CRES) Annual Conference, Denver, Colorado, USA. DRIOLI, E., LAGANÀ, F., CRISCUOLI, A. & BARBIERI, G. 1999 Integrated membrane operations in desalination processes, Desalination 122, 141-145. MARTINETTI, C. R., CHILDRESS, A. E. & CATH, T. Y. 2009 High recovery of concentrated RO brines using forward osmosis and membrane distillation, Journal of Membrane Science 331, 31-39 SCHWANTES, R., CIPOLLINA, A., GROSS, F., KOSCHIKOWSKI, J., PFEIFLE, D., ROLLETSCHEK, M. & SUBIELA, V. 2013 Membrane distillation: Solar and waste heat driven demonstration plants for desalination, Desalination 323, 93-106 SWERA 2005 Flat Plate Tilted at Latitude Annual, SWERA, accessed 7 September 2010, http://swera.unep.net/typo3conf/ext/metadata_tool/archive/download/africatilt_218.pdf. U.S. ENERGY INFORMATION ADMINISTRATION 2013, Egypt, EIA, accessed 16 November 2013, http://www.eia.gov/countries/country-data.cfm?fips=EG WATER QUALITY ASSOCIATION 2005 Osmosis Process, HM Digital, accessed 11 August 2010, http://www.tdsmeter.com/what-is?id=0013 WINTER, D., KOSCHIKOWSKI, J. & WIEGHAUS, M. 2011 Desalination using membrane distillation: Experimental studies on full scale spiral wound modules, Membrane Science 375, 104-112
27000 29000 31000 33000 35000 37000 39000 41000
30 35 40 45
Annual Permeate Production (1,000 kg) Collector Area to MD Modules Ratio (m²/NMD) Required MD Plant Annual Permeate Production Initially Estimated Number
20% Increase in Number
40% Increase in Number
5 10 15 20 25 30 35 40 2000 4000 6000 8000 10000 15000 20000 Percentage Increase in LCOW GW Salinity (mg/l) Confined Nubian Aquifer in the Sinai Peninusla (200 m) Confined Nubian Aquifer in Eastern Desert and Western Desert (20 m) RO Plant Only Unconfined Aquifer (50 m)
Annual Average Daily Global Irradiation in Egypt Source: NREL
20 40 60 80 100 2000 4000 6000 8000 10000 PV Energy Increase + RO Energy Reduction (MWh/year) Feed Water Salinity (mg/l) Glazed PVT Unglazed PVT