FRONTLINE FRONTLINE DISINFECTANT WIPE 70% ALCOHOL Wipe Size : 135 - - PDF document

FRONTLINE

Wipe Size : 135 x 180 mm Wipe Weight : 45 Gsm 80 % Polyester 30 % Viscon

Individual Pack Size : 7 x 12 cm

FRONTLINE

DISINFECTANT WIPE 70% ALCOHOL

CE CERTIFICATE CERTIFICATE OF CONFORMITY

FRONTLINE

DISINFECTANT WIPE 70% ALCOHOL

FRONTLINE

BARCODE

FRONTLINE

BARCODE

FRONTLINE

DISINFECTANT WIPE 70% ALCOHOL

INSPECTION REPORT

MSDS

FRONTLINE

DISINFECTANT WIPE 70% ALCOHOL

Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830.

FRONTLINE DISPOSABLE DISINFECTANT SWAB

Date of SDS : 29.05.2020 Date of revision : - Revision no. : 0 SDS Number : GBF - 3321 www.msdshazirlama.com Page 1/9

1- IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY/UNDERTAKING

1.1- Substance/Mixture Identifier: Product Name FRONTLINE DISPOSABLE DISINFECTANT SWAB Product Code 04 1.2- Relevant identified uses of the substance advised against: Identified uses Disinfectant Used advised against No data available 1.3- Details of the supplier of the safety data sheet: Company Dinamo Kozmetik ve Tekstil Dış. Tic. A.Ş. Address Anadolu Yakası Organize Sanayi Bölgesi Mermerciler Caddesi No:10 Tuzla/İstanbul/Turkey Tel/Fax +90 216 660 12 60 E-mail nurhandogan83@gmail.com 1.4- Emergency telephone number: +90 216 660 12 60

2- HAZARDS IDENTIFICATION

2.1- Classification of the substance or mixture: Classification: Highly flammable liquid and vapour, Category 2, H225 Notes: For the full text of the H sentences mentioned in this Section, see Section 16. 2.2- Label elements (according to EC 1272/2008): GHS Pictograms GHS02 Signal word Danger Contains Ethyl alcohol Hazard statements H225 Highly flammable liquid and vapour. Precautionary statements Prevention P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking P233 Keep container tightly closed P240 Ground/bond container and receiving equipment P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge

Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830.

FRONTLINE DISPOSABLE DISINFECTANT SWAB

Date of SDS : 29.05.2020 Date of revision : - Revision no. : 0 SDS Number : GBF - 3321 www.msdshazirlama.com Page 2/9 P280 Wear protective gloves/protective clothing/eye protection/face protection. Response P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P370 + P378 In case of fire: Use … for extinction. Storage P403 + P235 Store in a well-ventilated place. Keep cool P405 Store locked up. Disposal P501 Dispose of contents/container to in accordance with local/regional/national/ international regulation (to be specified). 2.3- Other hazards This mixture does not contain substances assessed to be vPvB / PBT according to Regulation (EC) No 1907/2006, Annex XIII. 2.4- Diğer zararlar PBT ve vPvB değerlendirmesi sonuçları: Veri mevcut değildir.

3- COMPOSITION/INFORMATION ON INGREDIENTS

3.1- Substance Not applicable 3.2- Mixture Components:

Chemical Name EC No CAS No. Content, % Classification Ethyl alcohol 200-578-6 64-17-5 70

• Flam. Liq. 2, H225

Alkyldimethylbenzylamm

• nium chloride

616-786-9 8001-54-5 0,2 Acute Tox. 4, H302 Acute Tox. 4, H312 Skin Corr. 1B, H314 Aquatic Acute 1, H400 Hydroxy Ethyl Cellulose 618-387-5 9004-62-0 2 Not Classified Ethylhexylglycerine 408-080-2 70445-33-9 0,4 Eye Dam. 1, H318 Aquatic Chronic 3, H412 Phenoxyethanol 204-589-7 122-99-6 0,4 Eye Irrit. 2, H319 Acute Tox. 4, H302 Demineralized su 231-791-2 7732-18-5 27 Not Classified

Note: The full text for all H-statements is displayed in section 16.

4- FIRST AID MEASURES

4.1- Description of first aid measures General information: IF you feel unwell: Call a POISON CENTER or doctor/physician.

Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830.

FRONTLINE DISPOSABLE DISINFECTANT SWAB

Date of SDS : 29.05.2020 Date of revision : - Revision no. : 0 SDS Number : GBF - 3321 www.msdshazirlama.com Page 3/9 Skin contact: A first aid need is not expected. Avoid contact with cracked skin. In case of an irritation, consult a doctor. Eye contact: Wash eyes with plenty of water at least for 15 minutes. Remove contact lenses, if present and easy to

• do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If the complaint persists, contact a doctor immediately. Ingestion: Rinse the patient's mouth with clean water, and then drink 2-4 glasses of water or milk. Do not induce

• vomiting. Do not give anything by mouth if it is unconscious. In case of spontaneous vomiting, make

sure that vomiting can be freely drained due to the danger of suffocation. Get medical attention if negative symptoms occur. Consult a doctor. 4.2- Most important symptoms and effects, both acute and delayed Skin contact: No symptoms are expected to be observed. Eye contact: May cause eye irritation. Inhalation: No symptoms are expected to be observed. Keep calm and warm. Ingestion: It can cause adverse effects on health. May cause nausea and vomiting. Ingestion: Eye irritation may occur due to prolonged exposure. 4.3- Indication of any immediate medical attention and special treatment needed Treat symptomatically.

5- FIRE FIGHTING MEASURES

5.1- General information Highly flammable liquid. Fire may cause damage to the environment of leakage of water. Avoid spreading of water used in firefighting. 5.2- Extinguishing Media Alcohol-resistant foam, dry chemical powder, CO2, or water spray. Use high-pressure water or alcohol-resistant foam to extinguish large fires. 5.3- Special hazards arising from the substance or mixture Avoid breathing gases, vapours, fumes, and decomposition products. Unusual fire and explosion

• hazards. Vapors can be ignited. In case of fire, carbon oxides may occur.

5.4- Advice for fire-fighters In case of fire, use self-contained breathing apparatus and wear full protective clothing. Use a protective face mask, protective gloves, and safety helmet. Avoid breathing fog/vapor in the fire.

Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830.

FRONTLINE DISPOSABLE DISINFECTANT SWAB

Date of SDS : 29.05.2020 Date of revision : - Revision no. : 0 SDS Number : GBF - 3321 www.msdshazirlama.com Page 4/9 5.5- Other advices Cool endangered containers with water spray. Firefighting residues should not be allowed to reach the

• sewer. Remove personnel to safe areas.

6- ACCIDENTAL RELEASE MEASURES

6.1- Personal precautions, protective equipment, and emergency procedures Do not breathe vapours and fumes. Avoid contact with eyes, skin, and clothing. Do not allow the product to spread around. Keep unnecessary and unprotected personnel away. Use the proper personal protective equipment listed in Chapter 8, as described in Chapter 7, safely and follow the recommendations below for use. Small Spills: Put absorbing material on spill products (sand, diatomite, acid binders, sawdust, general binders) take it into appropriate waste containers. Clean the contaminated area with soap. Good ventilate the area, keep combustible materials away. Large Spills: Put absorbing material on spill products (sand, diatomite, acid binders, sawdust, general binders) take it into appropriate waste containers. Clean the contaminated area with soap. Good ventilate the area, keep combustible materials away. 6.1.1- For non-emergency personnel: Wear adequate protective clothing. Avoid substance contact. Do not breathe vapors. Provide fresh air to confined spaces. Consult an expert for emergency procedures. Avoid contact with skin and eyes. 6.1.2- For emergency responders: Use the personal protective clothing, gloves and face and eye protection equipment specified in section

• 8. Evacuate the danger area, prevent unnecessary and unprotected persons from entering the area.

Take personnel to the safe area. Do not smoke, use fire or use anything other than a fire. Avoid breathing vapors and contact with skin and eyes. Provide adequate ventilation. In case of spills, pay attention to slippery floors and surfaces. 6.2- Environmental precautions In case of leakage, pull the set. If possible, remove the leak without risk. Avoid release to the

• environment. Prohibit entry into the area until cleaning is complete. Ventilate the area. Do not mix into

surface waters and sewage. 6.3- Methods and materials for containment and cleaning up Isolate and ventilate the spill. Clean by absorbing with dry sand or similar inert material (Vermiculite, sand, diatomite, general binder or similar inert material). Dispose of the collected material according to local regulations. 6.4- References to other sections Information on safe handling is obtained from section 7. Information on personal protective equipment is given in section 8. Disposal information from section 13.

7- HANDLING AND STORAGE

7.1- Precautions for safe handling When this product is in use, the working environment must be ventilated effectively, and employees should be prevented from being affected by the respiratory tract. Do not eat, drink or smoke while you are using it. Consider the required chemical hygiene measures. Wash hands with plenty of water after work. Wash hands with plenty of water after work.

Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830.

FRONTLINE DISPOSABLE DISINFECTANT SWAB

Date of SDS : 29.05.2020 Date of revision : - Revision no. : 0 SDS Number : GBF - 3321 www.msdshazirlama.com Page 5/9 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground the container and receiving equipment. Use explosion-proof electrical/ventilation/ignition/

• material. Use only non-flammable tools. Take preventive measures against static discharge.

7.2- Condition for safe storage, including any incompatibilities Store well ventilated, dry and away from daylight. Keep containers tightly closed and upright, protecting from physical damage. Avoid eye, skin and clothing contact. Keep it in its original package. Pay attention to labelling. 7.3- Specific end use(s) Products is used for human hygiene purposes

8- EXPOSURE CONTROLS, PERSONAL PROTECTION

8.1- Control parameters Components CAS-No. Value type (Form of exposure) Control parameters/ Permissible concentration Basis Ethyl Alcohol 64-17-5 TWA 1,000 ppm CA AB OEL 1,880 mg/m3 STEL 1,000 ppm CA BC OEL TWAEV 1,000 ppm CA QC OEL 1,880 mg/m3 STEL 1,000 ppm ACGIH 8.2- Exposure controls Personal protective equipment: General protection and hygiene measures: Keep away from food items, beverages and animal feeds. Do not eat or drink any food when using this product. Eye protection: Use safety goggles or face masks that have been tested and approved in accordance with standards such as EN 166 (EU). Contact lenses should not be worn. Hand protection: No special precautions are required. Use gloves in extreme cases. Respiratory protection: Use ABEK P2 (EU EN 143) type gas mask filters for disturbing exposure. Body protection: Not recommended. 8.3- Environmental Exposure Controls The provisions of existing legislation for the protection of the environment must be fully implemented.

9- PHYSICAL AND CHEMICAL PROPERTIES

9.1- Information on basic physical and chemical properties Appearance Non-woven towel Odour Characteristic alcohol

Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830.

FRONTLINE DISPOSABLE DISINFECTANT SWAB

Date of SDS : 29.05.2020 Date of revision : - Revision no. : 0 SDS Number : GBF - 3321 www.msdshazirlama.com Page 6/9 Odour threshold No data available pH (20 °C) 7-9 Melting point/Freezing point No data available Initial boiling point and boiling range (°C) No data available Flash Point No data available Evaporation rate No data available Flammability (solid, gas) No data available Vapour pressure No data available Vapour density No data available Relative Density (gr/ml) No data available Solubility(ies) No data available Partition coefficient: n-octanol/water No data available Flammability No data available Decomposition temperature No data available Viscosity No data available Explosive properties No data available Oxidizing properties No data available 9.2- Other information No data available.

10- STABILITY AND REACTIVITY

10.1- Reactivity The product is chemically stable under standard temperature and pressure. 10.2- Chemical stability The product is stable when properly transported and stored and does not show a tendency to react. 10.3- Possibility of hazardous reactions If the product is exposed to extremely high temperatures, carbon monoxide may release carbon dioxide gases. 10.4- Conditions to avoid Open flames, hot surfaces, heat, temperature, pressure, humidity and substances to be avoided. 10.5- Incompatible materials Oxidizing substances. 10.6- Hazardous decomposition products Carbon monoxide, carbon dioxide

11- TOXICOLOGICAL INFORMATION

11.1- Information on toxicological effects Acute Toxicity Ethyl alcohol (64-17-5)

LD50 oral (rat) 10 470 mg/kg bw

Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830.

FRONTLINE DISPOSABLE DISINFECTANT SWAB

Date of SDS : 29.05.2020 Date of revision : - Revision no. : 0 SDS Number : GBF - 3321 www.msdshazirlama.com Page 7/9 Ethyl alcohol (64-17-5)

LD50 dermal (rabbit) 17 100 mg/kg bw LC50 inhalation (rat) 124,7 mg/L air 4 h

Skin Corrosion/Irritation Based on available data, the classification criteria are not met. Serious Eye Damage/Irritation Based on available data, the classification criteria are not met. Respiratory or Skin Sensitization Based on available data, the classification criteria are not met. Germ cell mutagenicity Based on available data, the classification criteria are not met. Carcinogenicity Based on available data, the classification criteria are not met. Reproductive toxicity Based on available data, the classification criteria are not met. Sensitivity Based on available data, the classification criteria are not met. Respiratory tract and skin irritation Based on available data, the classification criteria are not met. Specific Target Organ Toxicity (Single Exposure) Based on available data, the classification criteria are not met. Specific Target Organ Toxicity (Repeated Exposure) Based on available data, the classification criteria are not met. Aspiration Hazard Based on available data, the classification criteria are not met.

12- ECOLOGICAL INFORMATION

12.1- Toxicity Ethyl alcohol (64-17-5) LC50 fish (Pimephales promelas) 15,3 mg/l (96 h) LC50 Daphnia magna 5 012 mg/l (48 h) EC50 Alg (Chlorella vulgaris) 675 mg/l (4 d) 12.2- Persistence and degradability No data available. 12.3- Bioaccumulative potential No data available. 12.4- Mobility in soil No data available. 12.5- Results of PBT and vPvB assessment This product does not contain any substances classified as PBT or vPvB.

Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830.

FRONTLINE DISPOSABLE DISINFECTANT SWAB

Date of SDS : 29.05.2020 Date of revision : - Revision no. : 0 SDS Number : GBF - 3321 www.msdshazirlama.com Page 8/9 12.6- Other adverse effects No data available.

13- DISPOSAL CONSIDERATIONS

13.1- Waste treatment methods Disposal can be made with normal household waste. can be recycled and incinerated. 13.2- European waste catalogue (EWC) According to the European Waste Catalogue, waste codes are product specific, but is not specific to the application. The waste codes must be assigned by the user.

14- TRANSPORT INFORMATION

Land transport (ADR/RID) 14.1- UN number UN1993 14.2- UN proper shipping name FLAMMABLE LIQUID, N.O.S. (Ethyl alcohol) 14.3- Transport hazard class(es) 3 14.4- Packing Group II 14.5- Environmental hazard Not hazardous. 14.6- Transport in bulk according to Annex II

• f MARPOL 73/78 and the IBC Cod

Not applicable. Sea transport (IMDG Code) 14.1- UN number UN1993 14.2- UN proper shipping name FLAMMABLE LIQUID, N.O.S. (Ethyl alcohol) 14.3- Transport hazard class(es) 3 14.4- Packing Group II 14.5- Environmental hazard Not hazardous. 14.6- Transport in bulk according to Annex II

• f MARPOL 73/78 and the IBC Cod

Not applicable. Air transport (ICAO-IATA/DGR) 14.1- UN number UN1993 14.2- UN proper shipping name FLAMMABLE LIQUID, N.O.S. (Ethyl alcohol) 14.3- Transport hazard class(es) 3 14.4- Packing Group II 14.5- Environmental hazard Not hazardous. 14.6- Transport in bulk according to Annex II

• f MARPOL 73/78 and the IBC Cod

Not applicable.

15- REGULATORY INFORMATION

15.1- Safety, health and environmental regulations/legislations specific for the substance or mixture  Regulation (EC) No 1907/2006, (REACH),  Commission Regulation (EU) No 453/2010 amending Regulation (EC) No 1907/2006,  Regulation (EC) No 1272/2008 (CLP),

Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830.

FRONTLINE DISPOSABLE DISINFECTANT SWAB

Date of SDS : 29.05.2020 Date of revision : - Revision no. : 0 SDS Number : GBF - 3321 www.msdshazirlama.com Page 9/9  Commission Directive 2006/15/EC,  Commission Directive 2000/39/EC.  ADR - European Agreement Concerning the International Carriage of Dangerous Goods by Road

16- OTHER INFORMATION

16.1- Full text of any H-statements not written out in full under Sections 2 to 15 H225 Highly flammable liquid and vapour H226 Flammable liquid and vapour H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage. H319 Causes serious eye irritation. H400 Very toxic to aquatic life. H412 Harmful to aquatic life with long lasting effects. 16.2- Abbreviations: ADR European Agreement Concerning the Int. Carriage of Dangerous Goods by Road CLP Regulation of Classification, Labelling and Packaging of Chemicals IATA International Air Transport Association ICAO International Civil Aviation Organization IMDG International Maritime Code for Dangerous Goods RID International Rule for Transport of Dangerous Substances by Railway STEL Short Term Exposure Limit TWA Time Weighted Average 16.3- Other information The information contained in this Safety Data Sheet is believed to be accurate and has been compiled from sources believed to be reliable. This idea is presented for investigation and

• verification. It is the user's responsibility to comply with the rules set out in this SDS. The user

undertakes all risks of use, storage and transport in accordance with applicable laws and regulations. Dinamo Kozmetik ve Tekstil Dış. Tic. A.Ş. cannot be held responsible for the damage or loss that may arise from the transfer of the related product, processing or product.

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DISINFECTANT WIPE 70% ALCOHOL

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