Exogenesis Corporation Innovations in Surface Processing Applications - - PowerPoint PPT Presentation

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Exogenesis Corporation Innovations in Surface Processing Applications - - PowerPoint PPT Presentation

Exogenesis Corporation Innovations in Surface Processing Applications In Lithography Accelerated Neutral Atom Beam (ANAB) Lithography Workshop 2013 (abstract page 92) 1 Agenda Company Applications in Lithography Surface mechanism


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Exogenesis Corporation

Innovations in Surface Processing

Applications In Lithography Accelerated Neutral Atom Beam (ANAB)

Lithography Workshop 2013 (abstract page 92)

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Agenda

  • Company
  • Applications in Lithography
  • Surface mechanism
  • Technology
  • Conclusion
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Company

  • Design, manufacture, and support fully

automated HVM tool.

  • Commercialized technology, with our first unit
  • perating in the field > 1 year.
  • Privately funded company employing platform technology enabling new

generation of medical devices, optics and photolithography products.

  • Vast experience in ion beam technology.
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Agenda

  • Company
  • Applications in Lithography
  • Surface mechanism
  • Technology
  • Conclusion
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EUV Lithography mask blank substrate pit defect removal

2-15 nm

FWHM 30-50nm

Pit dimensions

(~15 total) 0.151nm Rms 0.160nm Rms

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Atomic level smoothing

EUV Lithography mask blank substrate

Ra 1.219 nm Rz 11.221 nm Ra 0.133 nm Rz 1.406 nm After Accelerated Neutral Atom Beam Exogenesis process

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7 Ra 0.11 nm Rz 1.1 nm Ra 1.4 nm Rz 13.9 nm

Atomic level smoothing

UV Optics ‐ Sapphire

After Accelerated Neutral Atom Beam Exogenesis process

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Atomic level smoothing

UV Optics ‐fused silica CMP (no slurry)

Exogenesis process Ra 0.170 nm Rz 1.867 nm Ra 0.338 nm Rz 13.146 nm

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Atomic level smoothing

UV Optics – aluminum mirror

Exogenesis process Ra 0.595 nm Rz 5.413 nm Ra 5.672 nm Rz 47.331 nm

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LBO Crystal Processed with ANAB

  • 1. Removed from

package.

  • 2. No

processing.

  • 3. Exposed to

atmosphere.

  • 1. Removed from

package.

  • 2. ANAB

processed.

  • 3. Exposed to

atmosphere.

Ra=0.313nm Rz=16.689nm Ra=0.238nm Rz=7.038nm Ra=0.230nm Rz=9.158nm

< 1 Hour ≈ 100 Hours ≈ 2 weeks

Ra=0.296nm Rz=3.357nm Ra=3.584nm Rz=35.383nm Ra=5.977nm Rz=75.273nm

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Reduce light scatter on WDM optical coating stacks

Glass

Initial After

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Ultra shallow doping

1-3nm

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Free standing Ultra‐Thin carbon films

  • Visualized with 30,000x TEM
  • Measured electron transparency

= 0.95

  • Graphene measured transparency = 0.93
  • ~1‐3nm thick
  • Uniform/high quality
  • Free standing
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Agenda

  • Company
  • Applications in lithography
  • Surface mechanism
  • Technology
  • Conclusion
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Surface mechanism of ANAB

  • Nano‐scale surface modification
  • Unique Lateral sputtering effect
  • Quartz sputter rate (~ 15‐20 Å/sec)

GCIB’s lateral sputtering has been well documented. 50nm Pit

Cluster ~ 4nm

ANAB retains these properties, but is more sensitive.

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Agenda

  • Company
  • Applications in Lithography
  • Surface mechanism
  • Technology
  • Conclusion
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ANAB Technology

Accelerated Neutral Atom Beam (ANAB):

  • Vacuum‐based particle accelerator.
  • Low energy particles (20‐40 eV).
  • Electrically neutral.
  • Highly collimated, no divergence.
  • Non‐contact dry process
  • High density flux rate (1e17

atoms/sec).

30,000kV / 1,000Atoms = 30eV per atom

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Conclusion

  • ANAB Applications in Lithography?

– Nano defect removal & Atomic level smoothing

  • EUV mask blank substrate
  • EUV optics.
  • ?

– Free standing Ultra‐Thin carbon films.

  • Pellicle
  • Enhanced TEM imaging

– Ultra shallow doping

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Thank you

Michael Walsh mwalsh@exogenesis.us