Dynamic Water Management Studies by means of Perforated GDLs and - - PowerPoint PPT Presentation
Dynamic Water Management Studies by means of Perforated GDLs and - - PowerPoint PPT Presentation
Dynamic Water Management Studies by means of Perforated GDLs and In-situ ESEM Observations Robert Alink, Dietmar Gerteisen, Christian Sadeler, Christopher Hebling Fraunhofer Institute for Solar Energy Systems ISE Freiburg, Germany Diagnostic
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Overview
Test scope: Examination of the water transport
properties of laser perforated of gas diffusion layers
In-situ single cell experiments and stack experiments Ex-situ visualizing of water transport in untreated and
perforated GDLs in ESEM
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
The The Fraunhofer Society raunhofer Society
58 Institutes - 12 600 Employees – 1.2 Bio € Budget
7 Alliances
Mikroelectronics Production Technology Information and Communication Technology Materials, Devices Life Sciences Surface Technology and Photonics Defense and Security Research
Itzehoe Berlin Golm Magdeburg Hannover Braunschweig Bremen Oberhausen Dortmund Duisburg Aachen Euskirchen Schmallenberg
- St. Augustin
Ilmenau Jena Dresden Chemnitz Würzburg Erlangen Pfinztal Darmstadt Kaiserslautern
- St. Ingbert
Saarbrücken Karlsruhe Stuttgart Freiburg Freising Rostock Teltow Cottbus Halle Schkopau Paderborn Nürnberg Efringen-Kirchen München Holzkirchen Leipzig Itzehoe Berlin Golm Magdeburg Hannover Braunschweig Bremen Oberhausen Dortmund Duisburg Aachen Euskirchen Schmallenberg
- St. Augustin
Ilmenau Jena Dresden Chemnitz Würzburg Erlangen Pfinztal Darmstadt Kaiserslautern
- St. Ingbert
Saarbrücken Karlsruhe Stuttgart Freiburg Freising Rostock Teltow Cottbus Halle Schkopau Paderborn Nürnberg Efringen-Kirchen München Holzkirchen Leipzig
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Development Development
Components Products, Prototypes Systems, Processes
Fraunhofer ISE Research & Development, Services
Services Services
Consulting, Tests Monitoring Quality Assurance
Research Research
Materials Modelling Methods
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Development of fuel cell systems, stacks and autonomously controlled systems Characterizing and modelling single cells, stacks and systems Control and safety technology
Fuel Cell Systems
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
As consequence: water hinders oxygen diffusion
How can perforation of GDLs help to enhance the performance?
Water is generated in the
catalyst layer
Water flows through
small cavities
Small filled cavities
merge to larger cavities
Void space gets filled by
liquid water
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
How can perforation of GDLs help to enhance the performance?
Pressure needed for
through-plane transport
- f liquid water is higher
than that for in-plane transport
Water transport channels
(WTCs) support the through-plane transport Decrased saturation and increased oxygen diffusivity
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Investigation of single
cell with an active area of 1 cm2
Cathode GDL „under the
channel“ was perforated by laser treatment
Holes have a diameter of
80 μm and a gap distance
- f 1 mm
Investigation of single cell
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009 forward backward
* without anode polarization
different operating
conditions
sweep rate 10 mV/s
Dynamic polarisation curves @ show hysteresis effect
Enhancing liquid water transport by laser perforation of a GDL in a PEM fuel cell Journal of Power Sources, Vol 177, Issue 2, 1 March 2008, P 348-354
- D. Gerteisen, T. Heilmann, C. Ziegler
In-situ characterising of GDL water transport properties
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Potential sweep
measured with non- modified GDL
Improving the liquid water transport in the GDL
Enhancing liquid water transport by laser perforation of a GDL in a PEM fuel cell Journal of Power Sources, Vol 177, Issue 2, 1 March 2008, P 348-354
- D. Gerteisen, T. Heilmann, C. Ziegler
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Improving the liquid water transport in the GDL
Potential sweep
measured with non- modified GDL
Hysteresis knee due to
flooding effects
Enhancing liquid water transport by laser perforation of a GDL in a PEM fuel cell Journal of Power Sources, Vol 177, Issue 2, 1 March 2008, P 348-354
- D. Gerteisen, T. Heilmann, C. Ziegler
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Improving the liquid water transport in the GDL
Enhancing liquid water transport by laser perforation of a GDL in a PEM fuel cell Journal of Power Sources, Vol 177, Issue 2, 1 March 2008, P 348-354
- D. Gerteisen, T. Heilmann, C. Ziegler
Potential sweep
measured with non- modified GDL
Hysteresis knee due to
flooding effects
Perforated GDL shows
lowered pore flooding
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Improving the liquid water transport in the GDL
Enhancing liquid water transport by laser perforation of a GDL in a PEM fuel cell Journal of Power Sources, Vol 177, Issue 2, 1 March 2008, P 348-354
- D. Gerteisen, T. Heilmann, C. Ziegler
Chronoamperometriy
700 400 mV
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Performance improvement ~15%
Improving the liquid water transport in the GDL
Enhancing liquid water transport by laser perforation of a GDL in a PEM fuel cell Journal of Power Sources, Vol 177, Issue 2, 1 March 2008, P 348-354
- D. Gerteisen, T. Heilmann, C. Ziegler
Chronoamperometriy
700 400 mV
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Improving the liquid water transport in the GDL
Enhancing liquid water transport by laser perforation of a GDL in a PEM fuel cell Journal of Power Sources, Vol 177, Issue 2, 1 March 2008, P 348-354
- D. Gerteisen, T. Heilmann, C. Ziegler
Chronoamperometriy
600 300 mV
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Performance improvement ~20%
Improving the liquid water transport in the GDL
Enhancing liquid water transport by laser perforation of a GDL in a PEM fuel cell Journal of Power Sources, Vol 177, Issue 2, 1 March 2008, P 348-354
- D. Gerteisen, T. Heilmann, C. Ziegler
Chronoamperometriy
600 300 mV
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Investigation of fuel cell stack
Air cooled stack 6 cells Active area of 6 x 31 cm2
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Cell stability at 0.71 A/cm2
Stability test at 0.71
A/cm2 and 63 °C
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Cell stability at 0.71 A/cm2
Stability test at 0.71
A/cm2 and 63 °C
Voltages of outer cells
tend to collaps due to flooding
Higher overall
performance
3 times less purging steps
Increased stability and performance
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Polarisation curve
Higher Voltage at
constant current
Less variation of single
cell-voltage
Increased stability and performance
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Chronovoltametry
Increased stability and performance
Higher Voltage after
switching to higher current
Lower temperature due
to lower mass transport losses
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Examination of degradation by freezing water in ESEM
ESEM working in water
vapor athomsphere
All 3 phases of water
possible by adjusting temperature and pressure
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
before
Freeze / thaw cycling of
GDLs
Examination of degradation by freezing water in ESEM
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
before 10 x freeze / thaw after
Freeze / thaw cycling of
GDLs
Examination of degradation by freezing water in ESEM
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
before 10 x freeze / thaw 10 x freeze / thaw after
Freeze / thaw cycling of
GDLs
Freeze / thaw cycling of
MEAs
Examination of degradation by freezing water in ESEM
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
before 10 x freeze / thaw 10 x freeze / thaw 10 x wet / dry after
Freeze / thaw cycling of
GDLs
Freeze / thaw cycling of
MEAs
Wet / dry cycling of MEAs
as reference
Examination of degradation by freezing water in ESEM
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Liquid water examination in ESEM
ESEM working in water
vapor athomsphere
All 3 phases of water
possible by adjusting temperature and pressure
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Ex-situ visualization of liquid water breakthrough in ESEM
Water is „sucked“
through a porous membrane and the GDL
Visulization of water
breakthrough near the GDL surface
800 Pa absolute 800 Pa absolute 1x10 1x105 Pa absolute Pa absolute
E-beam GDL water water GDL GDL GDL GDL porous porous membrane embrane ESEM
80 800 P 0 Pa 1 °C 1 °C
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Transportation of water within an untreated GDL
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Transportation of water within an untreated GDL
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Transportation of water within an untreated GDL
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Transportation of water within an untreated GDL
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Transportation of water within an untreated GDL
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Transportation of water within an untreated GDL
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Transportation of water within an untreated GDL
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Transportation of water within an untreated GDL
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Transportation of water within an untreated GDL
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Transportation of water within an untreated GDL
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Transportation of water within a perforated GDL
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Transportation of water within a perforated GDL
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Transportation of water within a perforated GDL
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Transportation of water within a perforated GDL
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Transportation of water within a perforated GDL
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Transportation of water within a perforated GDL
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Transportation of water within a perforated GDL
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Transportation of water within a perforated GDL
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Transportation of water within a perforated GDL
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Transportation of water within a perforated GDL
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009
Summary
Single cell experiments
consistant with stack experiments
Significant increase in cell
performance and stability achieved
New method found to