Dynamic Water Management Studies by means of Perforated GDLs and - - PowerPoint PPT Presentation

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Dynamic Water Management Studies by means of Perforated GDLs and - - PowerPoint PPT Presentation

Dynamic Water Management Studies by means of Perforated GDLs and In-situ ESEM Observations Robert Alink, Dietmar Gerteisen, Christian Sadeler, Christopher Hebling Fraunhofer Institute for Solar Energy Systems ISE Freiburg, Germany Diagnostic


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Dynamic Water Management Studies by means of Perforated GDLs and In-situ ESEM Observations

Robert Alink, Dietmar Gerteisen, Christian Sadeler, Christopher Hebling Fraunhofer Institute for Solar Energy Systems ISE Freiburg, Germany Diagnostic Tools for Fuel Cell Technologies 24.06.2009, Trondheim

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Overview

Test scope: Examination of the water transport

properties of laser perforated of gas diffusion layers

In-situ single cell experiments and stack experiments Ex-situ visualizing of water transport in untreated and

perforated GDLs in ESEM

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

The The Fraunhofer Society raunhofer Society

58 Institutes - 12 600 Employees – 1.2 Bio € Budget

7 Alliances

Mikroelectronics Production Technology Information and Communication Technology Materials, Devices Life Sciences Surface Technology and Photonics Defense and Security Research

Itzehoe Berlin Golm Magdeburg Hannover Braunschweig Bremen Oberhausen Dortmund Duisburg Aachen Euskirchen Schmallenberg

  • St. Augustin

Ilmenau Jena Dresden Chemnitz Würzburg Erlangen Pfinztal Darmstadt Kaiserslautern

  • St. Ingbert

Saarbrücken Karlsruhe Stuttgart Freiburg Freising Rostock Teltow Cottbus Halle Schkopau Paderborn Nürnberg Efringen-Kirchen München Holzkirchen Leipzig Itzehoe Berlin Golm Magdeburg Hannover Braunschweig Bremen Oberhausen Dortmund Duisburg Aachen Euskirchen Schmallenberg

  • St. Augustin

Ilmenau Jena Dresden Chemnitz Würzburg Erlangen Pfinztal Darmstadt Kaiserslautern

  • St. Ingbert

Saarbrücken Karlsruhe Stuttgart Freiburg Freising Rostock Teltow Cottbus Halle Schkopau Paderborn Nürnberg Efringen-Kirchen München Holzkirchen Leipzig

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Development Development

Components Products, Prototypes Systems, Processes

Fraunhofer ISE Research & Development, Services

Services Services

Consulting, Tests Monitoring Quality Assurance

Research Research

Materials Modelling Methods

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Development of fuel cell systems, stacks and autonomously controlled systems Characterizing and modelling single cells, stacks and systems Control and safety technology

Fuel Cell Systems

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

As consequence: water hinders oxygen diffusion

How can perforation of GDLs help to enhance the performance?

Water is generated in the

catalyst layer

Water flows through

small cavities

Small filled cavities

merge to larger cavities

Void space gets filled by

liquid water

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

How can perforation of GDLs help to enhance the performance?

Pressure needed for

through-plane transport

  • f liquid water is higher

than that for in-plane transport

Water transport channels

(WTCs) support the through-plane transport Decrased saturation and increased oxygen diffusivity

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Investigation of single

cell with an active area of 1 cm2

Cathode GDL „under the

channel“ was perforated by laser treatment

Holes have a diameter of

80 μm and a gap distance

  • f 1 mm

Investigation of single cell

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009 forward backward

* without anode polarization

different operating

conditions

sweep rate 10 mV/s

Dynamic polarisation curves @ show hysteresis effect

Enhancing liquid water transport by laser perforation of a GDL in a PEM fuel cell Journal of Power Sources, Vol 177, Issue 2, 1 March 2008, P 348-354

  • D. Gerteisen, T. Heilmann, C. Ziegler

In-situ characterising of GDL water transport properties

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Potential sweep

measured with non- modified GDL

Improving the liquid water transport in the GDL

Enhancing liquid water transport by laser perforation of a GDL in a PEM fuel cell Journal of Power Sources, Vol 177, Issue 2, 1 March 2008, P 348-354

  • D. Gerteisen, T. Heilmann, C. Ziegler
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Improving the liquid water transport in the GDL

Potential sweep

measured with non- modified GDL

Hysteresis knee due to

flooding effects

Enhancing liquid water transport by laser perforation of a GDL in a PEM fuel cell Journal of Power Sources, Vol 177, Issue 2, 1 March 2008, P 348-354

  • D. Gerteisen, T. Heilmann, C. Ziegler
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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Improving the liquid water transport in the GDL

Enhancing liquid water transport by laser perforation of a GDL in a PEM fuel cell Journal of Power Sources, Vol 177, Issue 2, 1 March 2008, P 348-354

  • D. Gerteisen, T. Heilmann, C. Ziegler

Potential sweep

measured with non- modified GDL

Hysteresis knee due to

flooding effects

Perforated GDL shows

lowered pore flooding

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Improving the liquid water transport in the GDL

Enhancing liquid water transport by laser perforation of a GDL in a PEM fuel cell Journal of Power Sources, Vol 177, Issue 2, 1 March 2008, P 348-354

  • D. Gerteisen, T. Heilmann, C. Ziegler

Chronoamperometriy

700 400 mV

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Performance improvement ~15%

Improving the liquid water transport in the GDL

Enhancing liquid water transport by laser perforation of a GDL in a PEM fuel cell Journal of Power Sources, Vol 177, Issue 2, 1 March 2008, P 348-354

  • D. Gerteisen, T. Heilmann, C. Ziegler

Chronoamperometriy

700 400 mV

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Improving the liquid water transport in the GDL

Enhancing liquid water transport by laser perforation of a GDL in a PEM fuel cell Journal of Power Sources, Vol 177, Issue 2, 1 March 2008, P 348-354

  • D. Gerteisen, T. Heilmann, C. Ziegler

Chronoamperometriy

600 300 mV

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Performance improvement ~20%

Improving the liquid water transport in the GDL

Enhancing liquid water transport by laser perforation of a GDL in a PEM fuel cell Journal of Power Sources, Vol 177, Issue 2, 1 March 2008, P 348-354

  • D. Gerteisen, T. Heilmann, C. Ziegler

Chronoamperometriy

600 300 mV

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Investigation of fuel cell stack

Air cooled stack 6 cells Active area of 6 x 31 cm2

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Cell stability at 0.71 A/cm2

Stability test at 0.71

A/cm2 and 63 °C

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Cell stability at 0.71 A/cm2

Stability test at 0.71

A/cm2 and 63 °C

Voltages of outer cells

tend to collaps due to flooding

Higher overall

performance

3 times less purging steps

Increased stability and performance

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Polarisation curve

Higher Voltage at

constant current

Less variation of single

cell-voltage

Increased stability and performance

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Chronovoltametry

Increased stability and performance

Higher Voltage after

switching to higher current

Lower temperature due

to lower mass transport losses

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Examination of degradation by freezing water in ESEM

ESEM working in water

vapor athomsphere

All 3 phases of water

possible by adjusting temperature and pressure

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

before

Freeze / thaw cycling of

GDLs

Examination of degradation by freezing water in ESEM

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

before 10 x freeze / thaw after

Freeze / thaw cycling of

GDLs

Examination of degradation by freezing water in ESEM

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

before 10 x freeze / thaw 10 x freeze / thaw after

Freeze / thaw cycling of

GDLs

Freeze / thaw cycling of

MEAs

Examination of degradation by freezing water in ESEM

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

before 10 x freeze / thaw 10 x freeze / thaw 10 x wet / dry after

Freeze / thaw cycling of

GDLs

Freeze / thaw cycling of

MEAs

Wet / dry cycling of MEAs

as reference

Examination of degradation by freezing water in ESEM

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Liquid water examination in ESEM

ESEM working in water

vapor athomsphere

All 3 phases of water

possible by adjusting temperature and pressure

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Ex-situ visualization of liquid water breakthrough in ESEM

Water is „sucked“

through a porous membrane and the GDL

Visulization of water

breakthrough near the GDL surface

800 Pa absolute 800 Pa absolute 1x10 1x105 Pa absolute Pa absolute

E-beam GDL water water GDL GDL GDL GDL porous porous membrane embrane ESEM

80 800 P 0 Pa 1 °C 1 °C

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Transportation of water within an untreated GDL

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Transportation of water within an untreated GDL

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Transportation of water within an untreated GDL

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Transportation of water within an untreated GDL

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Transportation of water within an untreated GDL

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Transportation of water within an untreated GDL

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Transportation of water within an untreated GDL

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Transportation of water within an untreated GDL

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Transportation of water within an untreated GDL

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Transportation of water within an untreated GDL

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Transportation of water within a perforated GDL

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Transportation of water within a perforated GDL

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Transportation of water within a perforated GDL

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Transportation of water within a perforated GDL

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Transportation of water within a perforated GDL

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Transportation of water within a perforated GDL

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Transportation of water within a perforated GDL

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Transportation of water within a perforated GDL

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Transportation of water within a perforated GDL

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Transportation of water within a perforated GDL

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DIAGNOSTIC TOOLS FOR FUEL CELL TECHNOLOGIES 2009

Summary

Single cell experiments

consistant with stack experiments

Significant increase in cell

performance and stability achieved

New method found to

visualize water transport in GDLs in ESEM