1 A N A New ew Superior Superior Mix Mixer er-Act Activa - - PowerPoint PPT Presentation

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1 A N A New ew Superior Superior Mix Mixer er-Act Activa - - PowerPoint PPT Presentation

Abstract Submission Topic : / EPIC5 / Plant intensification A NEW SUPERIOR MIXER-ACTIVATOR FOR ENHANCING CHEMICAL REACTIONS Pasi Tolvanen* 1, Henrik Grnman1, Carl-Olof Palm2, Tapio Salmi1 1Laboratory of Industrial chemistry and reaction


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Many industrial applications deal with solid-liquid interactions where an enormous amount of energy is required to obtain the desired mixing or

  • homogenization. The conventional stirring-and-waiting methods could be drastically improved if the amount of time and energy (high temperatures and

pressures) could to some extent be avoided. A new innovative mixing technology Atrex has recently obtained attention in industries around the world due to its excellent capabilities – minimal time of processing and energy is required. The main benefits of using Atrex are:

  • continuously operating industrial high shear mixing
  • suitability for grinding and crushing, as well as dispergation and disintegration
  • multiple repeated impact strikes and over- & under pressure pulses
  • strong tribomechanical and tribochemical activation for enhancing reactions

Atrex is a continuously operating industrial process equipment consisting of counter-rotating (typically1500rpm+1500rpm) pinned discs for crushing, grinding, mixing, micro-homogenization and disintegration with very strong shear forces, turbulence and huge amounts of repeated impacts and over/under pressure pulses [1] . All ingredients contribute to superior surface activation properties. Strong centrifugal forces give an easy input and output of processed materials, and the mixing time in Atrex is less than one second and every single volume unit gets a similar strong energy input. The equipment is small in size but the capacity is high. The strong activation properties of Atrex could be further improved by applying a stimulating radiation for a selective exitation of reacting atoms, molecules and ions (light, heat, pressure, microwave, electric, magnetic) to react efficiently. Typical processes such as scrubbing, flotation and precipitation, can be significantly enhanced. Several existing patents of the technology exist. The alkaline extraction of hemicellulose by conventional ways require a large input of energy and long reaction times [2]. Therefore, this reaction was selected as a model case to illustrate Atrex efficiency. A bench-scale Atrex equipment was used for extraction of valuable components from wood material. As main components in the experiments, hot water and alkali were used. With hot water extraction, hemicelluloses are obtained selectively from the wood material, whereas lignin is selectively extracted with alkaline-water solution. The results showed that the process can be considerably intensified by applying the Atrex equipment, compared to conventional hotwater and alkali extraction processes.

Abstract Submission

Topic : / EPIC5 / Plant intensification A NEW SUPERIOR MIXER-ACTIVATOR FOR ENHANCING CHEMICAL REACTIONS Pasi Tolvanen* 1, Henrik Grénman1, Carl-Olof Palm2, Tapio Salmi1 1Laboratory of Industrial chemistry and reaction engineering, Åbo Akademi, Turku, 2Megatrex, Megatrex, Lempäälä, Finland Authors of the abstract come from :: Both University and Industry

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A N A New ew Superior Superior Mix Mixer er-Act Activa ivator tor for Enhanc

  • r Enhancing Chem

ing Chemical ical and and Physical Physical Pr Processes

  • cesses

Pasi Tolvanen1,Carl-Olof Palm2 ,

Henrik Grenman1, Tapio Salmi1

1Åbo Akademi, Turku/Finland, 20500-Fi, ptolvane@abo.fi 2 Megatrex Oy, Lempäälä, Finland

EPIC-5 - 29th September 2015

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  • Many industrial processes are slow and/or,
  • r consist of several steps:
  • Disintegration & homogenization
  • Gas scrubbing
  • Precipitation
  • Solid-liquid mixing
  • Extraction processes

(stirring-and-waiting)

  • Drying steps between treatment /reaction

EPIC5 - P. Tolvanen - 29.09.2015 3

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These slow processes can be improved

  • reduce processing time
  • reduce energy consumption
  • reduce number of processing steps

Need highly efficient simultaneous mixing & grinding technology

EPIC5 - P. Tolvanen - 29.09.2015 4

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A new mixing/grinding technology

  • A continuously operating industrial

high-shear impact mixer

  • contra-rotating pinned discs
  • Strong shear forces and attrition
  • High turbulence and repeated impacts
  • Alternating over/under pressure pulses
  • Horizontal rotor position
  • Easy feed of reagents and exit of products

by strong centrifugal forces

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Strong activation by repeated collisions and virgin surfaces Enhancement of slow processes

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The impact crusher-mixer-grinder-activator

 2 discs with several concentric rows of pins  Discs rotation normally from 500 to 1500 rpm

 Contra-rotating discs normally 1500 rpm + 1500 rpm

 Mixing time less than one (1) second  Strongly activated*) virgin surfaces allow direct contact and reaction

*) Tribomechanical and –chemical activation

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Successful industrial application examples of Atrex mixer

  • Dispersion of pigments paint & paper industry
  • Disintegration of paper making rejects - up to 97% recirculated
  • Dry grinding of natural polymer
  • Gas scrubber
  • Simultaneous continuous crushing, grinding and wetting in

lime slaking process within minutes to dry product or colloidal lime milk

  • New development - Hot water extraction of

hemicellulose from wood

EPIC5 - P. Tolvanen - 29.09.2015 7

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RB

droplet

Stagnation line g Fluid stream lines

Dust, soot particles and molecules in a gas flow follow the main flow

νp RP

h0

Rc

νp

ϕT

Example: Scrubbing

A conventional scrubber process is slow with extremely low collision probability due to flow dynamics (picture)

water droplet ϕ : 10.000-1.000.000 nm dot in text : 500.000 nm smoke : 100-1000 nm SOx molecule : 1 nm

Atrex Forced collisions

  • Enhanced interactions

 faster process  smaller device  larger treated volume

. . . . . . . .

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Normal slaking of quick lime – a cumbersome chemical & physical process!

CaO (s) + H2O (l) → Ca(OH)2 (s+l) + heat

 Highly exothermic  lot of process water is needed for safety  Protective layers of hydrated lime forming on unreacted quick lime retarding the process  Agglomerated wet product must be dried and unwanted large crystals are precipitated from solution  Further grinding, separation and handling in air carbonate surfaces retarding reactivity of the product

Using Atrex slaking

 Rather big lumps (~5 cm) are simultaneously crushed, ground and wetted and the violent reaction is performed safely in a closed process directly to nanosized products  Dramatic enhancement of the slaking process

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EPIC5 - P. Tolvanen - 29.09.2015 10

Newest study: Extraction of hemicelluloses

Spruce-derived galactoglucomannan (GGM),  Potential to be utilized in a wide assortment of products, ranging from the food industry to cosmetics, fine chemicals, and biocomposites Conventional hemicellulose extraction:

  • Hot water
  • Reaction time
  • Large water quantities

Part of hemicellulose molecule

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  • 11

Atrex

P

Pump sampling

1 5 10

ሶ Q

TIC Temperature 90 ºC mixer heater

...120 min

Starting wood chips inlet

Atrex based hemicellulose pilot extraction method

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Increased extracted hemicellulose over time

Recirculation loop total 120 min One round = 2 minutes

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Extraction results

Total hemicellulose extracted to aqueous phase Breakdown of monomer products

0,2 0,4 0,6 0,8 1 1,2 1,4 1,6 1,8 50 100 150

wt.-%

time (min) Ara(Sum) Gal(Sum) GalA(Sum) Glc(Sum) GlcA(Sum) Man(Sum) Rha(Sum) Xyl(Sum) 0,00 1,00 2,00 3,00 4,00 5,00 6,00 7,00 20 40 60 80 100 120 140

yield %

time (min)

yield hemicellulose (%)

ΔcR/ Δ t

faster initial rate than conventional extraction Yield 5x higher than conventional extraction process at 90 oC

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13 Reaction time: 0 min Reaction time: 2 min Reaction time: 20 min Reaction time: 60 min

Disintegration of the fibers within minutes

Optical microscope

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  • EPIC5 - P. Tolvanen - 29.09.2015

14

mannose

15 5 2

minutes

Progress of extraction (GC analysis)

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Conclusions

 The Atrex activator mixer-grinder provided by Megatrex works efficiently in a broad area

  • f industrial process intensification

 Hemicellulose extraction gave promising results – the initial extraction rate is higher than in the conventional extraction equipment even at much lower temperature.  It was found out, that the extraction velocity using Atrex was 5 times faster than conventional extraction operated at 90ºC and 2 hours of reaction, using spruce as a source material.  Sugars from wood and other lignocellulosic material can be more easily extracted for industrial processes  Further studies - pressurize the reactor system, higher T.

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Acknowledgements

Acknowledgements:

  • Megatrex
  • Åbo Akademi University

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  • Additional ECCE info + photos can be found:

http://www.ecce2015.eu/