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Assessment of Near-Source Air Pollution at a Fine Spatial Scale Utilizing a Mobile Monitoring Approach Tools of the Trade 2016 Conference Jonathan Steffens Oak Ridge National Laboratory, Oak Ridge TN, 37830 Sue Kimbrough U.S. EPA, National Risk


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Assessment of Near-Source Air Pollution at a Fine Spatial Scale Utilizing a Mobile Monitoring Approach

Office of Research and Development National Risk Management Research Laboratory, Air Pollution Prevention and Control Division

September 13, 2016

Jonathan Steffens Oak Ridge National Laboratory, Oak Ridge TN, 37830 Sue Kimbrough U.S. EPA, National Risk Management Research Laboratory, Research Triangle Park, NC 27711 Vlad Isakov U.S. EPA, National Exposure Research Laboratory, Research Triangle Park, NC 27711 Ryan Brown, Alan Powell U.S. EPA, Region 4, Atlanta, GA 30303

Tools of the Trade 2016 Conference

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SLIDE 2

Background

  • Ports play a critical role in the United States and global economies.
  • The Panama Canal is undergoing an expansion which will double its

capacity and allow for larger vessels to pass through. While this is expected to provide a positive economic impact, the environmental impact is uncertain.

  • Port facilities service traffic from ocean going vessels (OGV), on-terminal

equipment, heavy trucks, and rail, leading to significant emissions of black carbon, particulate, carbon monoxide, and other harmful pollutants.

  • Previous research on roadways and railways has shown significant

elevation of pollutant concentration above background within several hundred meters of emission sources.

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U.S. Environmental Protection Agency

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SLIDE 3

Research Objectives

  • Early efforts to investigate how ports could impact local-

scale air quality (within several hundred meters from the port facilities). –Mobile monitoring campaign conducted around the Port of Charleston in South Carolina –Measurement data supplemented with modeling results from AERMOD and RLINE and C-PORT

  • Use data to isolate the port contribution from other

source contributions (e.g. roadways) and control for confounding variables (e.g. meteorological conditions)

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U.S. Environmental Protection Agency

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SLIDE 4

Study Overview

  • Mobile monitoring campaign

– February and March, 2014 – Port of Charleston area in South Carolina – Conducted using EPA’s Geospatial Measurement

  • f Air Pollution (GMAP) vehicle
  • GMAP vehicle

– all-electric – measures real-time (1 Hz) concentrations of BC, NO2, particulate matter, CO, and CO2 – on-board GPS records geospatial coordinates – 3 to 4 hour range – Repeated laps at various times of day and week near different port terminals

  • Meteorological conditions recorded with nearby

stationary sampling

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U.S. Environmental Protection Agency

Wando Welch Terminal

Source: http://www.scspa.com/

GMAP Vehicle

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GMAP Vehicle Instrumentation

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U.S. Environmental Protection Agency

Measurement Sampling Rate Instrument Stationary/ Mobile

NO2 1s

Visible (450 nm) absorption Cavity Attenuated Phase Shift Spectroscopy (CAPS, Aerodyne Research, Inc., Billerica, MA, USA)

Mobile Carbon monoxide (CO) 1 s

Quantum cascade laser (QCL, Aerodyne Research, Inc., Billerica, MA, USA)

Mobile Carbon dioxide (CO2) 1 s

Li-COR 820 non-dispersive infrared (NDIR), (LI- COR, Lincoln, Nebraska USA)

Mobile

Particle number concentration (size range 5.6-560 nm, 32 channels)

1 s

Engine Exhaust Particle Sizer (EEPS, Model 3090, TSI, Inc., Shoreview, MN, USA)

Mobile

Particle number concentration (size range 0.5-20 µm, 52 channels)

1 s

Aerodynamic Particle Sizer (APS, Model 3321, TSI, Inc., Shoreview, MN, USA)

Mobile Black carbon 1-5 s

Single-channel Aethalometer (Magee Scientific, AE-42, Berkeley, CA, USA)

Mobile Longitude and latitude 1 s

Global positioning system (Crescent R100, Hemisphere GPS, Scottsdale, AZ, USA)

Mobile 3D wind speed and direction 1 s

Ultrasonic anemometer (RM Young, Model, Traverse City, MI, USA )

Stationary SO2 1 s

Ecotech 9850 (Ecotech, Knoxfield Victoria, 3180, Australia)

Stationary

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SLIDE 6

Port of Charleston

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U.S. Environmental Protection Agency

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SLIDE 7

Driving Routes

  • Sampling at each
  • ccurred over 3-4 hour

periods on multiple days

  • Measurement start times

were selected to cover a wide range of port

  • perational times
  • Driving routes shown in

green.

  • Port terminals outlined in

red.

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U.S. Environmental Protection Agency

Wando Welch Terminal (10 sampling days) Columbus Street Terminal (6 sampling days) Veteran’s Terminal (4 sampling days) Bennett Rail Yard (4 sampling days)

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Spatially Averaged Concentration

  • Each point represents an average of all PM2.5 concentrations (µg/m3) measured

within 20 m radius.

  • High concentrations observed along major roadways (significant non-port impact)
  • Analysis will focus on measurements within neighborhood zones (outlined in yellow)

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U.S. Environmental Protection Agency

Wando Welch Terminal Columbus Street Terminal

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Spatially Averaged Concentration

  • Spatially averaged PM2.5 concentrations (µg/m3) at Veteran’s Terminal and Bennett

Rail Yard

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U.S. Environmental Protection Agency

Bennett Rail Yard Veteran’s Terminal

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SLIDE 10

Wind Roses

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U.S. Environmental Protection Agency

Bennett Rail Yard Veteran’s Terminal Wando Welch Terminal Columbus Street Terminal

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SLIDE 11

Time of Day

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  • Distributions of concentration at

Wando Welch show high temporal variability in measurement

  • Higher concentrations observed in

the morning and afternoon – likely caused by morning and evening rush hour periods.

  • Very heavy diesel truck traffic
  • bserved moving into and out of port

in early morning.

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SLIDE 12

Wando Welch Terminal

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U.S. Environmental Protection Agency

  • Local background concentration is taken by selecting periods

where wind is from a direction away from the port (from the South at Wando for lower neighborhoods)

  • This is compared to periods where wind is blowing from over

the port

  • Comparison was confined to periods during normal port
  • perating hours (7 am to 7 pm)
  • A significant effect from the port is observed in all measured

pollutants

Port Background 200 400 600 800 1000 1200 1400 BC (g/m3) Median Mean 25%-75% 10%-90% Port Background 100 120 140 160 180 200 220 240 CO (ppb)

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Columbus Street Terminal

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U.S. Environmental Protection Agency

  • Only small (if any) port influence is observed

at the Columbus Street terminal

  • Many confounding sources in the vicinity

make it difficult to isolate port effect

Port Background 500 1000 1500 BC (g/m3) Port Background 150 200 250 300 350 400 450 CO (ppb)

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SLIDE 14

Veteran’s Terminal

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U.S. Environmental Protection Agency

  • “Background” is observed to be higher near

Veteran’s Terminal

  • Port is further away from neighborhood reducing

its impact

  • Major highway immediately on the far end of the

neighborhood causing much higher concentration when wind is blowing from that direction

Port Background 180 200 220 240 260 280 300 320 340 CO (ppb) Port Background 500 1000 1500 2000 2500 3000 BC (g/m3)

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SLIDE 15

Bennett Rail Yard

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U.S. Environmental Protection Agency

  • Little difference observed between rail

and background

  • Very strong influence from major

roadways in all directions

Rail Background 220 240 260 280 300 320 340 360 380 CO (ppb) Rail Background 500 1000 1500 2000 2500 BC (g/m3)

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Port Activity

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U.S. Environmental Protection Agency

  • Port activity data (crane counts and

ship counts) supplied at Wando Welch for most sampling periods

  • Cranes are electric, but assumed

to be representative of overall port activity including diesel trucks and

  • ther on-terminal equipment, and

hoteling OGVs.

  • Percent increase over background

concentration observed (absolute values vary strongly with regional background)

  • Weak trend observed between

crane counts and PM2.5

  • concentration. (r^2 = 0.36)

Sampling Day Ship Count Crane Count PM2.5 Concentration Percent Increase 2/21 3 8 15.5 2.25 1 1 5.6 2/27 2 2 4.9 3/2 2 4 8.2 3/5 3 7 19.3 3/7 2 4 18.7 3/13 AM 1 2 18.2 3/13 PM 3 6 20.8

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Modeling Analysis

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U.S. Environmental Protection Agency

  • Model port-related emissions of PM2.5

using AERMOD, RLINE, and C-PORT

  • AERMOD models port on-terminal

sources such as heavy equipment and docked vessels as area source using emissions inventory data

  • RLINE models roadway and railways

as line sources using AADT counts

  • Receptor grids Uniformly spaced at

270m resolution (8,100 receptors)

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Modeling Analysis

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U.S. Environmental Protection Agency

  • Differences in sampling times/days, met conditions and distance from source to

sampling locations makes it difficult to accurately compare each site to each other

  • However, comparison between measurement and model in the neighborhood regions

along the four measurement routs for PM2.5 shows good qualitative agreement at Wando, Veteran’s and the Rail Yard

  • Model results for Columbus Street terminal are much lower than measurement,

suggesting the model may be missing some major emission source near this location

Wando Columbus Veteran Rail Yard 2 4 6 8 10 12

PM2.5 (g/m3)

Wando Columbus Veteran Rail Yard 2 4 6 8 10 12

PM2.5 (g/m3)

Median Mean 25%-75% 10%-90%

  • utliers

GMAP Data Model Results

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SLIDE 19

Modeling Analysis

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U.S. Environmental Protection Agency

  • Isolating percent contribution

from the three source types shows that roadway sources dominate port and rail source everywhere except Wando Welch terminal

  • Measurement route near

Veteran’s terminal is further away than other terminal routes, explaining minor port impact

  • Port contribution only relates to
  • n-terminal activity. Part of road

and rail contribution would also be attributable to port activity

Wando Columbus Veteran Rail Yard 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Model Source Percent Contribution

Port Contribution Rail Contribution Road Contribution

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Summary and Future Work

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U.S. Environmental Protection Agency

  • Mobile monitoring campaign conducted around the Port of

Charleston, South Carolina, using GMAP vehicle.

  • Very large amount of data collected – over 55 hours of real-

time sampling of multiple pollutants and meteorological conditions.

  • Ports are shown to have a potentially significant impact on

local air quality (Wando Welch) which quickly diminishes away from the port (Veteran’s). This effect can be difficult to isolate as the impact of roadways is generally much higher.

  • This work represents an early effort in mapping near-port air
  • quality. More port-related mobile monitoring campaigns may

be conducted to facilitate a more comprehensive analysis.

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ACKNOWLEDGMENTS

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U.S. Environmental Protection Agency

This project was supported in part by an appointment to the Research Participation Program at the Office of Research and Development, U.S. Environmental Protection Agency, administered by the Oak Ridge Institute for Science and Education through an interagency agreement between the U.S. Department of Energy and EPA. The US Environmental Protection Agency through its Office of Research and Development funded and conducted the research described here through Contract EP-C-09-027 with ARCADIS, Geraghty & Miller. Mention of trade names or commercial products does not constitute endorsement or recommendations for use. Although this work was reviewed by EPA and approved for publication, it may not necessarily reflect official Agency policy.