11/14/2017 1
Joseph Hun-wei Lee Hong Kong University of Science and Technology
Mixing of Chlorine Jets for Sewage Disinfection
Research & Development Forum Drainage Services Department November 14, 2017
Outline 1. Introduction 2. Overview of chlorine disinfection - - PDF document
11/14/2017 Research & Development Forum Drainage Services Department November 14, 2017 Mixing of Chlorine Jets for Sewage Disinfection Joseph Hun-wei Lee Hong Kong University of Science and Technology Outline 1. Introduction 2.
Research & Development Forum Drainage Services Department November 14, 2017
107 → 105 counts/100mL
Choi et al, Environmental Science and Technology, 2009
Screening Plants/pumping stations Stonecutters Island Sewage Treatment Work (SCISTW) 昂船洲污水處理廠 Submarine
排污口 23.6 km deep tunnels (>100m below ground level)
香港島 九龍 Stonecutters Island STW
Chamber 15 Dechlorination Dosing Effluent Box Culverts 2 x 2.5 m x 2.5m
Sedimentation Tanks Main Pumping Station
Flow distribution Chamber Chlorine Dosing
FDC No. 2 Drop Shaft Dechlorination Compound (DC) Riser Shaft Overflow Culvert Chamber 15A Extension of Chamber 15 New Effluent Tunnel
Decommissioned box culvert Flow distribution Chamber (FDC)
Hypochlorite Storage Tanks 6
CEPT Effluent Dosing of sodium hypochlorite Dosing of sodium bisulphite Dechlorinated Effluent Existing box culvert as the chlorine contact system Discharge to Outfall
Chamber 15 Flow Distribution Chamber
Cl2 conc. (ppm) x (m) 10m 1km 105 10-20
Initial mixing Chlorine decay and 2 order bacterial kill
~ 10000!
after disinfection: 107 → 105 count/100mL
Average chlorine Concentration = 12 mg/L (dry) = 18 mg/L (wet)
TRC concentration at Chambers 9 and 15.
between Chamber 9 and 15
Cl2 conc. (ppm) x (m) 10m 1km
105
10-20 ppm Few E.coli kill TRC << 1 FDC 1km culvert Chamber 15 Chamber 9 80% Chlorine consumed Expected Required Dilution ~ 10000!
Vertical section view
1.7 m opening Submerged flow Free surface flow Dense Jets Dosing Unit 2.65mPD 0.85mPD
height in the middle of FDC
injected into the sewage flow through an array of dense jets in two layers
Chlorine dosing unit Weir 2 3.5m 3.5m inlet culvert from sedimentation tanks
Plan view
12.5m
Beaker test
Cl2 = 105 mg/L Conc.
CEPT Sewage 20 m3/s
Field Dosing
Conc.
50.3% 52.9% 44.0%
0% 20% 40% 60% 80% 100% 10% (N=9) 2% (N=8) 1% (N=7) Chlorine demand Source chlorine concentration (% w/w)
Cf = 600mg/L About half of the dosed chlorine is consumed by the chlorinated sewage in 4.5 seconds Similar significant chlorine demand for dosing at 10% or 1% chlorine (same chlorine mass flux) Chlorine jet Uj = 0.3m/s CEPT Sewage Ua = 0.1m/s Δx = 0.45m, Δt = 4.5s Outflow
Chlorine dosing unit Weir 2 3.5m 3.5m inlet culvert from sedimentation tanks
Plan view of FDC
12.5m
1/16 slice of FDC
The objectives are to study:
CEPT Sewage inflow from sedimentation tank Head tank Dosing unit Discharge of sodium hypochlorite solution Test flume Outlet tank
1:2 Physical Scale Model in SCISTW for study of chlorine mixing (1/16 slice of FDC sewage flow)
Diaphragm pump Air chamber Chlorine Storage tank Safety valve To dosing unit
Discharge of sugar solution in air Jet velocity
Lower port D = 2.5mm Upper port D = 5mm
Dosing sugar solution ( = 1.168 g/mL) into cross flow in 1:2 model
Initial mixing of upper dosing jet with dyed sugar solution (tap water flow Qs = 60 L/s; Ua = 0.2 m/s; total jet discharge qd = 20 mL/s) Qiao et al. ASCE Journal of Hydraulic Engineering, 2017
Head tank FDC weir Outflow over lateral weirs
Flow distribution baffle
0.11 0.11 Measuring point y=0.0 z y Right Center Left Flume bottom z=0.0 Weir plate top (z=0.9 m) Flume side wall Free surface 0.07 0.07 0.05 0.05 0.05 Weir crest
1D motorized vertical traverse for sampling Portable TRC photometer Sampling tube
4 key runs with detailed TRC, bacteria and nutrient measurement
volume of fluid (VOF) method Dosing jet flow = 20mL/s C0 = 100,000 mg/L Δρ/ρ = 0.2
Ua = 0.36m/s Qu = 15.7mL/s Ql = 4.3mL/s
Jet mixing of the chlorine with the sewage co-flow achieves a rapid dilution in the order
achieve full mixing (i.e. a dilution of 5000-10,000). Only approximately 60-80 percent of the sewage flow over the FDC weir is chlorinated.
Flume centreline Cross-sections
0.5 1 1.5 2 2.5 3 3.5 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 Inver level z=0.0 m FDC weir Distance from jet source x(m) Level z(m) 10% chlorine dosage flow 20 mL/s Upper Jet: qu=15.3 (mL/s) and Uj=1.20 (m/s) Low jet: qd=4.7 (mL/s) and Uj=1.50 (m/s) 100 L/s CEPT sewage flow Cm= 12.2 17.7 20.0 10.0 35.0 8.0 58.0 5.8
Measured TRC concentration (mg/L) distribution at the centreline section of FDC
Measured TRC mass flux and average TRC concentration along the flume
Lee et al. ASCE Journal of Environmental Engineering, 2017
There is a direct local correlation between TRC and E. coli. Overall there is a
the chlorine injection. After immediate chlorine demand is satisfied, the residual (> 1.5 mg/L) can effectively disinfect the sewage by 2-log kill within contact time of about 5 minutes.
Correlation between local E. coli and TRC concentration above the weir
at the downstream of the weir
A top-hat profile (uniform velocity in width B) is assumed in the model Spreading hypothesis of the top-hat half width
𝑒𝐶 𝑒𝑡 = 𝛾𝑡 𝑊−𝑉𝑏 cos 𝜚 𝑊
+ 𝛾𝑜
𝑉𝑏 sin 𝜚 𝑊
+𝛾∗
𝜏 𝑉𝑏
Ua, ρa, S0 U0, C0, ρ0 U(x) W(x) ds B(x) Coflow jet region Shear entrainment Gaussian conc. distribution Advected Line Thermal (ALT) region Vortex entrainment Vortex-pair conc. distribution
𝐺0 = 𝜍0 − 𝜍𝑏 𝜍𝑏 𝑟𝑒
𝑀𝑐 = 𝐺
0/𝑉𝑏 3 z x
D V(x) C(x), S(x)
𝑟𝑒 = ¼𝜌𝐸2𝑉0
ϕ z(x) s Shear entrainment Vortex entrainment Ambient turbulence σ = RMS velocity fluctuation ≈ 0.15Ua
Spreading hypothesis (top-hat): Excess x-momentum flux:
𝛾𝑡 = 0.16 𝛾𝑜 = 0.4 𝛾∗ = 0.8
𝑒 𝑒𝑡 𝜌𝐶2𝑊 𝑉 − 𝑉𝑏 = 0 (1 + 𝑙𝑜) 𝑒 𝑒𝑡 𝜌𝐶2𝑊𝑋 = 𝐺0 𝑉𝑏 z-momentum flux: 𝑒 𝑒𝑡 ) 𝜌𝐶2𝑊(𝑇𝑏 − 𝑇 = 0 TRC mass flux:
𝑒 𝑒𝑡 𝜌𝐶2𝑊𝐷 = −𝑙𝐷𝑇(𝜌𝐶2)
Sewage “pollutant concentration”: Spreading coeff.: Added-mass coeff.:
𝑙𝑜 = 1
Trajectory: 𝑒𝑦 𝑒𝑡 = 𝑑𝑝𝑡𝜚 𝑒𝑨 𝑒𝑡 = sin 𝜚 Second order reaction
Ua, ρa, S0 U0, C0, ρ0 U(x) W(x) ds B(x) 𝐺0 = 𝜍0 − 𝜍𝑏 𝜍𝑏 𝑟𝑒 z x D V(x) C(x), S(x) 𝑟𝑒 = ¼𝜌𝐸2𝑉0 ϕ z(x) s
𝑒𝐶 𝑒𝑡 = 𝛾𝑡 𝑊−𝑉𝑏 cos 𝜚 𝑊
+ 𝛾𝑜
𝑉𝑏 sin 𝜚 𝑊
+𝛾∗
𝜏 𝑉𝑏
Solve for B, U, W, C, S and z(x)
simulate the concentration-dependent chlorine reaction with sewage.
experimental data. 𝜄𝑈−𝑈
0 = temperature dependent factor = 1.1T-20.
beaker tests.
zero at the chlorine jet nozzle (zero loss of TRC). S represents the availability of reactants in the sewage 𝑒𝐷 𝑒𝑢 = −𝑙𝐷𝑇 𝑙 𝐷, 𝑈 = 𝜄𝑈−𝑈
0 ൝0.2580 ln(𝐷) − 0.7216
0.0044 for 𝐷 > 12.8 𝑛/𝑀 𝐷 ≤ 12.8𝑛/𝑀
The relation of k against measured average TRC is obtained from field experiment and further calibrated by comparing model result with measured TRC profile. (T ≈ 29oC)
To predict and interpret the detailed TRC distribution in the FDC flume in the presence of solid boundaries. Solve 3D RANS equations (using VOF) and the advection-diffusion equation for TRC, using the decay coefficient calibrated from field data TRC distribution
0.5 0.6 0.7 0.8 0.9 1 1.1 1.2 20 40 60 80 z (m) TRC (mg/L)
S100C20 x = 0.5m
CFD
0.5 0.6 0.7 0.8 0.9 1 1.1 1.2 1.3 10 20 30 40 50 TRC (mg/L)
S100C20 x = 1.0m
CFD
0.5 0.6 0.7 0.8 0.9 1 1.1 1.2 1.3 10 20 30 40 50 TRC (mg/L)
S100C20 x = 1.5m
CFD
0.5 0.6 0.7 0.8 0.9 1 1.1 1.2 1.3 10 20 30 40 50 TRC (mg/L)
S100C20 x = 2m
CFD
0.9 0.95 1 1.05 1.1 1.15 1.2 1.25 10 20 30 40 50 z (m) TRC (mg/L)
S100C20 x = 2.5m, weir
CFD
TRC Mass flux
Flume centerline
10% chlorine solution using a two-jet dosing unit results in high chlorine demand - due to insufficient jet mixing with the ambient flow and fast chemical oxidations processes.
suggested that discharging pre-diluted chlorine solution, say ~1%, into the FDC may decrease the extent of chlorine loss.
much increased sewage contact with the injected chlorine.
mathematical models developed and then tested by experimentation in the field-scale model.
10% chlorine concentration with the same chlorine dosage of 20 mg/L
0.36m/s).
pointed to the use of 2.5% chlorine solution; focused tests were performed for this condition with an improved 4-jet (coflow) dosing unit to ensure repeatability over varying sewage conditions and temperatures.
measured in the cross-section of the outflow from the FDC, above an end weir (at x = 2.5m) in a total of 21 sampling points in the flow cross-section above the weir.
Two Jet dosing unit for 10% chlorine solution Four Jet dosing unit for 2.5% chlorine solution
chlorine mass flux (2 g/s)
0.03 0.125 0.125 0.01 solution from Upper p di z=0.9
Por di z Por di z 0.01 0.125 0.125 0.03 di
qd = 20mL/s qd = 80mL/s 9mm dia. 5mm dia. 6mm dia.
X Z
1 2 3 0.5 1 1.5
U D S10000 5000 1000 500 100 50 10
Weir Dosing Unit
X Z
1 2 3 0.5 1 1.5
U D S10000 5000 1000 500 100 50 10
Weir Dosing Unit
2-jet dosing unit (Du = 10mm, Dl = 9.4mm) 4-jet dosing unit (D = 6mm)
X Z
1 2 3 0.5 1 1.5
U D S10000 5000 1000 500 100 50 10
Weir Dosing Unit
8-jet dosing unit (D = 4mm) Flume centerline Measured TRC profile at centerline above weir (T = 26.5oC) 2 jets 4 jets
Integral model predicted chlorine jet characteristics for 2.5% chlorine solution discharge in CEPT sewage (qd = 80 mL/s).
TRC Concentration TRC Mass flux TRC Concentration
effectively reduce the chlorine demand by about 15-20%
dosing with pre-diluted 2.5% chlorine solution and a four-jet dosing unit.
Predicted (integral model) and meas. chlorine demand above the weir – coflow jets
chlorine demand by about 15-20%, demonstrated by extensive TRC flux measurement above the weir.
about 10-15% using a 4-jet dosing unit rather than a 2-jet dosing unit.
enough to justify a doubling of the flow (to 8qd), given the scarcity of freshwater resources and space constraints in SCISTW.
chlorine solution and a four-jet dosing unit.
thus chlorine demand. However, at a high chlorine condition, the reaction kinetics is mainly dictated by the chlorine level rather than by temperature fluctuations.
Utilize the intensive mixing by the weir overfall to supplement the initial jet mixing of the high concentration chlorine solution to reduce chlorine consumption by the ammonia and organics in sewage. Weir Dosing Jet above weir
x (m) z (m)
2 3 4 5 0.5 1 1.5
U D S010000 1000 100 50 20 10 5 1
Streamlines TRC (mg/L)
(d)Downstream of weir (x=6.0 m)
z=0.5 mz=0.65 m z=0.9 m
First-point dosing (x=0.0 m) Measuring section at x=6.0 m (a) Sketch of FDC model with second point dosing Measuring section at x=5.0 m Measuring section at x=4.5 m
0.6 m
x=2.5 m
(0,0) x z
CEPT sewage effluent Q0=100 L/s
1.265 m
Second-point dosing (x=2.4 or 2.25 m; z=0.95 or 1.05 m)
(c)Downstream of weir (x=5.0 m)
0.2m 0.3 m 0.4 m z=0.5 mz=~0.6 m
z=0.5 m 0.4 m 0.3 m 0.2m (b)Downstream of weir (x=4.5 m)
FDC weir
examine the chlorine demand for dosing jet discharging near the weir.
sewage flow downstream of the weir. Measurement locations
(Parameters: Sewage flow=102 L/s, sewage temp.=29.5 0C chlorine dosing flow=18.5 mL/s, chlorine dose=18 mg/L)
Chlorine jet dosing close to the weir: supplement initial jet mixing with Turbulent plunging pool mixing: 10% NaOCl solution, August 04, 2017 Higher TRC level downstream of the weir with the chlorine jet discharging close to the weir
Dosing above weir Dosing upstream
5 10 15 20 25 30 35 40 45 5 10 15 20 25 30 35 40 45
Chlorine dose Cd (mg/L) TRC of mixed outflow C3 (mg/L)
1:1
(Sewage flow=100 L/s, sewage temp.=27.5-30.5 0C, chlorine dosing flow=20-40 mL/s, 10% NaOCl solution)
Jet dosing above weir Original jet dosing location
Chlorine demand
Point 1 Point 2 Sewage flow = 100 L/s Dosing flow = 20mL/s C0 = 10%, Ca = 20mg/L
Weir
y = 0.055m
Dosing Unit 2 Q_c = 10mL/s
x (m) z (m)
1 2 3 4 0.5 1 1.5
U D S10000 1000 100 50 20 10 5 1
Two-point dosing
Dosing unit 1 Q = 10mL/s
Dosing Options
4.5m) Chlorine Demand (%, 25oC) 20oC 25oC 30oC Upstream (Existing) 5.0 3.0 1.8 85.0% One-point above weir 17.4 15.7 14.1 20.9% Two-point dosing U/S = D/S = 10 mL/s 14.9 13.6 12.2 31.9%
Weir
Centerline
Dosing Unit 1 Q_c = 20mL/s
x (m) z (m)
1 2 3 4 0.5 1 1.5
U D S10000 1000 100 50 20 10 5 1
Single point dosing (original design)
experiments using prototype sewage and chlorine dosing solution.
solution with the sewage flow in the flow distribution chamber. Only 60-70 percent of the sewage is in contact with chlorine.
from the source. The chlorine demand is due to oxidation of organic debris at the high concentrations, and not used in pathogen kill.
hypochlorite solution to 2.5% or by relocating the chlorine jet to discharge
field experiments and research into chemical kinetics modelling.
46