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Introduction Who are Phantom Plastics? Our history of new smart - PowerPoint PPT Presentation

Jan 01, 2023 •189 likes •377 views

Phantom Plastics Dr. Chris DeArmitt Phantom Plastics Introduction Who are Phantom Plastics? Our history of new smart materials Introduction to styrenic polymers What is this new polymer? What effects does it display?

  1. Phantom Plastics ™ Dr. Chris DeArmitt – Phantom Plastics ™

  2. Introduction  Who are Phantom Plastics?  Our history of new smart materials  Introduction to styrenic polymers  What is this new polymer?  What effects does it display?  How does it work?  Is it a viable material?  Production and supply  Summary Phantom Plastics ™ 2

  3. Phantom Plastics ™  Phantom Plastics ™ : • New plastic materials and formulations (fillers, antioxidants and specialty additives) • Problem solving • Training seminars, webinars, documents and video downloads • Smart materials creation  Smart materials history • Developed a new water-soluble, self-doped polyaniline with new green to red colour switching with pH change • At BASF developed and patented new Smart Salts technology to solve a long- standing and serious product quality issue with ABS, ASA and MABS (BASF had spent 30 years and several million Euros and failed to solve the problem) • Developed, patented and marketing ThermoShift ™ opacity changing thermoplastic • Working with Fortune 100 company to develop a new type of smart packaging Phantom Plastics ™ 3

  4. Commodity Styrenic Polymers Transparent + acrylonitrile General Purpose SAN Polystyrene - GPPS + butadiene + butadiene rubber rubber + acrylonitrile High Impact ABS Polystyrene (HIPS) Opaque Phantom Plastics ™ 4

  5. Specialty Styrenic Polymers Specialty Styrenics + nylon 6 ABS ABS/PA special compatibilizer + butadiene Excellent impact rubber resistance + acrylate rubber SAN ASA Excellent UV / Heat Chemical stability resistance High MABS + butadiene modulus rubber Low impact Excellent transparency + (P)MMA resistance & impact resistance Phantom Plastics ™ 5

  6. The Mechanism MABS (transparent ABS) Thermoplastic matrix Refractive Index Impact modifier 15 25 35 45 55 65 75 Temperature (˚C) Phantom Plastics ™ 6

  7. The Mechanism ThermoShift ™ Refractive Index ThermoShift ™ Matrix 15 25 35 45 55 65 75 Temperature (˚C) Phantom Plastics ™ 7

  8. Demonstration Movie Phantom Plastics ™ 8

  9. Optimised for 40°C (ASTM D1003) 40 96 Haze Transmission 35 94 30 92 Transmission [%] Haze [%] 25 90 20 88 15 86 10 84 5 82 0 10 20 30 40 50 60 70 80 90 100 Temperature [°C] Phantom Plastics ™ 9

  10. Optimised for 55°C (ASTM D1003) 40 96 Haze Transmission 35 94 30 92 Transmission [%] Haze [%] 25 90 20 88 15 86 10 84 5 82 0 10 20 30 40 50 60 70 80 90 100 Temperature [°C] Phantom Plastics ™ 10

  11. Optimised for 65°C (ASTM D1003) 40 96 Haze Transmission 35 94 30 92 Transmission [%] Haze [%] 25 90 20 88 15 86 10 84 5 82 0 10 20 30 40 50 60 70 80 90 100 Temperature [°C] Phantom Plastics ™ 11

  12. Optimised for 80°C (ASTM D1003) 40 96 Haze Transmission 35 94 30 92 Transmission [%] Haze [%] 25 90 20 88 15 86 10 84 5 82 0 10 20 30 40 50 60 70 80 90 100 Temperature [°C] Phantom Plastics ™ 12

  13. Haze Overview (ASTM D1003) 40 35 30 Haze [%] 25 20 15 10 5 0 10 20 30 40 50 60 70 80 90 100 Temperature [°C] Phantom Plastics ™ 13

  14. Transmission Overview (ASTM D1003) 96 94 92 Transmission [%] 90 88 86 84 82 0 10 20 30 40 50 60 70 80 90 100 Temperature [°C] Phantom Plastics ™ 14

  15. Indicative Mechanical Properties Not to be used as a specification Property Approximate Value Modulus (MPa) 2000 Yield Strength (MPa) 35 Elongation to Break 12 % Unnotched Charpy (kJm -2 ) 90 Notched Charpy (kJm -2 ) 10-15 Puncture test (J) 15-25 Vicat B (˚C) 91 MVR (ml/10 min) 10-15 Phantom Plastics ™ 15

  16. Applications The imagination is the limit  The initial application was for Electrolux dishwasher doors to show the machine in action but hide dirty dishes  Fridge and freezer manufacturers are interested to show whether temperature status at a glance without thermocouples  Designers are investigating the ability to use the effect for novel lighting applications, e.g. harsh to soft transitions  Car manufacturers are interested for example in sunroof use to shield against extreme sunlight  Greenhouses could be built to protect plants from extreme sun  Can be used to simulate fog / poor visibility for example firefighter training exercises  Many more applications in novelty items, etc. Phantom Plastics ™ 16

  17. Commercial Aspects Production, pricing and availability  Sample material and parts are supplied in partnership with Norner Innovation AS, Norway  Samples provided to interested parties under NDA  Production can be handled in multiple ways: • Smaller volumes from Norner Innovation • Larger volumes through Phantom Plastics tolling partners locally • Production through OEM compounders via licensing  The material is safe with no extractibles, food contact is not in place but could be obtained  Pricing depends on volume and exact material ordered, but is in the region of $ 5-10 / lb  ThermoShift can be developed based on other plastic materials Phantom Plastics ™ 17

  18. Conclusion  We present a new, unique material with a reversible thermo- opaque switching behavior  The material can be made in different grades to provide optimal transparency at temperatures anywhere from -20 ° C to +85 ° C  The material shows an excellent balance of mechanical properties e.g. modulus, yield strength and impact resistance  The material is amorphous, allowing use in any standard injection mold made for amorphous materials  The limitations are unsuitability for outdoor use or continuous use at high temperatures  Several Fortune 500 companies are working with Phantom Plastics (exclusivity available on first come, first served basis) Phantom Plastics ™ 18

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