Ferrites-by-design for Millimeter waves and Terahertz Technologies - - PDF document

ferrites by design for millimeter waves and terahertz
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Ferrites-by-design for Millimeter waves and Terahertz Technologies - - PDF document

Ferrites-by-design for Millimeter waves and Terahertz Technologies (FeMiT) The FeMiT project explained in 5 minutes Have you ever experienced connectivity issues with your mobile? What will happen if as expected there are much more mobiles, in


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Ferrites-by-design for Millimeter waves and Terahertz Technologies (FeMiT)

The FeMiT project explained in 5 minutes Have you ever experienced connectivity issues with your mobile? What will happen if as expected there are much more mobiles, in your watches, your home appliances, your cars and in the machines that produce them in a factory? The huge data traffic would saturate the narrow spectrum of today’s networks. In fact, we are already experiencing an explosion in the data demand.1 That’s why with 5G we are shifting to higher frequencies, into the mm-waves, where plenty of bandwidth is available. A big challenge of mm-waves is that these only allow line-of sight propagation, making the transition to higher frequencies a real paradigm change, with the communications relying on myriads of closely scattered small antennas. Thus, besides working at tens to hundreds of GHz, the new communication devices will have to be cheap, low power and miniaturized. For instance, the circulators isolate emitting antennas from one another, acting as a traffic router for the waves only in one direction. This is an example of the ferrite non-reciprocal devices which will gain importance in this new context However, today, these only operate in the first portion of the mm-wave band, using external magnetic fields which makes them bulky and can only work at one frequency. The aim of FeMiT is  Making them work at higher frequencies without external magnetic fields  And making them reconfigurable to operate at different frequencies Before explaining how we plan to do this it is important to highlight that these devices exploit the phenomenon of ferromagnetic resonance: at a given frequency, the waves propagate through a ferrite or are absorbed, depending on their direction, and the resonance frequency is higher the larger is the magnetic anisotropy of the ferrite. So, for the mm-waves we need ferrites with very high magnetic anisotropy. The FeMiT Now, my idea is developing a new family of ferrites based on ε-Fe2O3 as it has two unique properties highly suitable for implementing innovative non-reciprocal devices in the mm-waves: First, a Japanese group has shown it displays ferromagnetic resonances well into the mm-waves, which can be increased or decreased by chemical doping.2-3 But the transmission losses, which are key to applications, are not characterized and the possibilities of chemical doping have not been fully explored, with relevant dopants

  • verlooked.

On the other hand we discovered that the onset of large magnetic anisotropy is accompanied by a strain of the structure, a thousand times larger than in other magnetic transition metal oxides.4 This tells us that one can expect controlling the ferromagnetic resonance through strain, obtaining much larger responses than with a standard ferrite.

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To demonstrate this hypothesis we will want to make composites of the epsilon Ferrite materials with piezoelectrics to shift the ferromagnetic resonance by applying an external

  • voltage. Based on these properties we will exploit chemical doping and strain engineering to

explore the possibilities of this new family of ferrites. The feasibility of these approaches is backed by the remarkable stability of this phase at high pressure. Selecting the best materials we aim at providing proof-of principle demonstrators of  A passive mm-wave device in the form of a faraday rotator with figures of merit matching or exceeding those of state of the art ferrites (50 degree/dB) but in this case in the mm-waves and without external fields.  An active device with voltage controlled ferromagnetic resonance We will start by preparing materials by wet chemistry methods which are fast, allow an accurate control the chemical doping and provide large amount of material for

  • characterization. Then, structural and property characterizations will give feedback for new

synthesis Two PhDs will be in charge of these tasks. An important functional characterization will be studied with a free-air transmissiometer financed by the project, with a dedicated

  • Postdoc. Selected compositions will be prepared as epitaxial films and/or composites and a

second Postdoc will join the team to develop the demonstrators. Expected project outcomes are a library of new ferrites for designing mm-wave components A reconfigurable ferromagnetic resonance device, which would constitute a technological breakthrough enabling to use the same device in zones with different standards. Finally, the frontier research of the project will certainly generate knowledge which can be relevant to related fields for instance in

  • EM absorbers and taggants
  • Magnonic transceivers
  • Spin lattice interactions in oxides

References

1. Ericsson Mobility Report, June 2018; Ericsson 2018. https://www.ericsson.com/en/mobility-report/reports/june-2018 2. Namai, A.; Sakurai, S.; Nakajima, M.; Suemoto, T.; Matsumoto, K.; Goto, M.; Sasaki, S.; Ohkoshi, S.-i., Synthesis of an Electromagnetic Wave Absorber for High-Speed Wireless

  • Communication. Journal of the American Chemical Society 2009, 131 (3), 1170-1173.
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3. Namai, A.; Yoshikiyo, M.; Yamada, K.; Sakurai, S.; Goto, T.; Yoshida, T.; Miyazaki, T.; Nakajima, M.; Suemoto, T.; Tokoro, H.; Ohkoshi, S.-i., Hard magnetic ferrite with a gigantic coercivity and high frequency millimetre wave rotation. Nature Communications 2012, 3. 4. García-Muñoz, J. L.; Romaguera, A.; Fauth, F.; Nogués, J.; Gich, M., Unveiling a New High-Temperature Ordered Magnetic Phase in ε-Fe2O3. Chemistry of Materials 2017, 29 (22), 9705-9713.

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Non-reciprocal ferrite devices

Image: http://www.millitech.com, 2018

Ferrites-by-design for Millimeter-wave & Terahertz Technologies (FeMiT)

2.5 cm ~1500 € circulator for antenna isolation

  • 100 GHz with magnetic fields
  • Passive (fixed frequency)
  • Bulky & Expensive

Limitations at mm-waves

  • Higher frequencies without magnets
  • Reconfigurable (several frequencies)
  • Cheap & Miniaturized

The FeMiT vision

increases with

Ferromagnetic resonance Non-reciprocal devices for 5G & beyond

Spectrum saturation calls for a shift into mm-waves, a new paradigm in wireless communications

ωFMR

Magnetic Anisotropy, Hc

mm-wave wireless

0.5 GHz 300 GHz Today’s 4G 3 GHz

New mm-wave devices: Small, Cheap & Low Power

Line-of-sight propagation myriads of new antennas

Ericsson Mobility Report June 2018

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Passive components Without Magnetic Field Active components Switchable operation frequency

A new family of ferrites for mm-waves based on high magnetic anisotropy ε-Fe2O3

Chemical doping

Huge spontaneous magnetostriction

Gich et al. Chem. Mater., 2017

300 350 400 450 500 550 600 650 700 0.00 0.01 0.02 0.03 0.04 5 10 15 20

Temperature (K)

425 426 427 428 429 430 431

Magnetic anisotropy, Hc (kOe) Unit cell volume (Å3)

ΔV/V ~10-3

novel dopant selection

Proof of principle demonstrators

Faraday rotator

Strain engineering

ε-Fe2O3

Voltage control of ferromagnetic resonance Mediated by strain Piezoelectric ε–MxFe2-xO3

Figure of merit: 50°/dB

Gich et al. Adv. Mater., 2014

Epitaxial films Voltage-tunable FMR mm-wave ferromagnetic resonances

Ohkoshi et al. Nature Comm., 2012

x=0

Doping level (Rh)

x=0.14

Hc (kOe)

22 24 26 28

Gich et al. Chem. Mater., 2004

High Anisotropy

5 10 15 20 25 30 35 40 350 360 370 380 390 400 410 420 430 Unit Cell Volume (Å3) Pressure (GPa)

  • M. Gich et al. Nature Comm. 2018, in press

Sustains large strains

Selected compositions

ε–MxFe2-xO3

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Methodology Expected results & impact Impact beyond FeMiT

Towards passive & active mm-wave devices without external magnetic fields

Epitaxial films Demonstrators  Library of ε-MxFe2-xO3 properties for future wireless applications

PhD1 PhD2 PDoc2

Nanoparticles by Soft chemistry Composites  Proof-of principle towards low-cost & sustainable mm-wave devices  EM absorbers and taggants (RFID)  Magnonic transcievers  Spin-lattice interactions in oxides  Proof of principle towards Reconfigurable mm-wave devices

External collaborators

  • Prof. J. O’Callaghan

(UPC, Barcelona)

  • Prof. M. Ležaić (Jülich FZ)
  • Prof. R. Mishra (U. St. Louis)
  • Prof. A. Muhkin

(Russian Ac. Sci.) FMR shift ~ 0.5 GHz/V Rotation ~ 50°/dB

Breakthrough

PDoc1

Characterization

WP1 WP3 WP2

Synthesis

1st principle calculations Free-space Transmissiometer Spectroscopic characterization