03 METHANOL PRODUCTION WWW.METHANOL.ORG WWW.METHANOL.ORG - - PowerPoint PPT Presentation
03 METHANOL PRODUCTION WWW.METHANOL.ORG WWW.METHANOL.ORG Conventional Methanol Production Methanol convertor Fuel Gas Steam(H 2 O) Natural Gas(fuel) Natural Gas Reformer To Burners H 2 Purge Synthesis gas Methanol To H 2 consumers CO+H 2
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Natural Gas CO+H2 CO2+ H2 Methanol Converter Methanol/Water Distillation Methanol Fuel Gas Steam(H2O) Synthesis gas
To Burners To H2 consumers
CH3OH/H2O H2 Purge Water Reformer Natural Gas(fuel)
Reformer Distillation tower Methanol convertor 2
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Source: Johnson Matthey
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molecule that can be made from conventional fossil sources and emerging renewable feedstocks.
markets for methanol builds demand for sustainably- sourced and locally- produced methanol.
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Reformer CH4 Reactor H2 CO CO2 Distillation CH3OH
Conventional Production Option 1
Option 3
Option 4
Liquid Electricity
Option 2
CO2 Recovery & Utilization
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reformer bio-methane reactor H2 CO CO2 distillation bio-methanol
Option 1
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reformer methane reactor H2 CO CO2 distillation methanol
Option 1
flue gas CO2
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flue gas using MHI’s proprietary KS–1™ solvent and injected in synthesis loop for boosting Methanol production.
increased by 300 MTPD with addition of CO2 in synthesis gas mixture as excess H2 is available for the methanol reaction.
Self–sufficient for raw material (CO2).
Excess H2 in Reformed Gas
CO2 extraction from Flue Gas by CDR route & Injection in Methanol Plant
MeOH Production Increase
QAFAC Utilization of Recovered CO2
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gasifier Waste wood Black liquor MSW reactor H2 CO CO2 distillation crude bio-methanol
Option 3
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reactor distillation e-methanol electrolyzer H2 CO2 capture CO2 electricity
Option 4
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Source: BSE engineering
*Storage capacity BMW i3 = 21,6 kWh
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Application Current Methanol Demand (2015E, -000-Tons) Potential Market Demand (-000- Tons) Alternative Fuels
11,571 40,000-50,000
1,197 25,000-40,000
4,970 10,000-15,000
Others >1 40,000-60,000 Fuel Cells 8 3,000-8,000 Methanol-to-Olefins 16,683 30,000-40,000 Methanol-to-Gasoline 250 15,000-35,000
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In 2011, Israel Electric Corp (IEC) & Dor performed trial conversion at Caesara power plant located in valley in Eilat Previously used diesel-fuelled turbine for peak power. Limited to 300 hours of
pipeline natural gas access June 2014 commercial
fuelled Pratt & Whitney FT4C Twin Pack 50 MW gas turbine.
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methanol, with this initial project costing $5 million.
particulates emission reduction, without affecting performance.
hours per year.
hour.
world) can be adopted in many other places (mainly Islands) where due to no natural gas supply, are currently using polluting fuels.
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(wood/charcoal, dung, kerosene, paraffin, diesel, coal, LPG) can emit significant CO2 and harmful particulates, potential fire hazards.
Africa (paraffin), China (coal).
studies in Nigeria since 2005.
canister: no handling of fuel by beneficiaries; results very successful.
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applications in China since 1983
methanol needed for future cooking applications in China.
could reduce annual direct coal burning by 3,172 MW and CO2 emissions decrease of 8.25 billion tons.
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T W O T Y P E S O F F U E L C E L L S
Methanol important in fuel cells as an environmentally- friendly hydrogen carrier fuel
Direct Methanol Fuel Cells (DMFCs):
exchange fuel cells
the fuel.
energy-dense/stable
power
vapor Reformed Methanol Fuel Cells (RMFC) / Indirect Methanol Fuel Cells (IMFCs):
to hydrogen gas before being fed into fuel cell.
smaller cell stacks, better
low temps.
systems required
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Charging/Replacement of batteries
Provision of off-grid or grid-support power
towers
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Major Global Methanol Fuel Cell Producers
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MSF MAINTAINS A PRESENCE IN OVER 60 COUNTRIES MANY OF THESE COUNTRIES MI HAS TARGETED FOR METHANOL POISONING OUTREACH PROGRAMS, MSF HAS EXISTING OPERATIONS, TO INCLUDE:
CONTACTS
01 02 03 04
CEO gdolan@methanol.org
COO cchatterton@methanol.org
Director of Government Affairs dlavigne@methanol.org
Senior Manager External Affairs navin@methanol.org 05 06 07 08
Chief EU Representative edekker@methanol.org
Chief China Representative kzhao@methanol.org
Executive Manager achan@methanol.org
Executive Assistant snoshirvan@methanol.org
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SINGAPORE (HQ) WASHINGTON D.C. BRUSSELS BEIJING
10 Anson Road #32-10 International Plaza Singapore 079903 + 65 6325 6300 225 Reinekers Lane Suite 205 Alexandria, VA 22314 +1 (703) 248-3636
Square de Meeûs 38/40 B-1000 Brussels, Belgium +32 241 6151
#511, Pacific Sci- tech Development Center Peking University
Beijing 100871, China +86 10 6275 5984
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