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Case Study: How to Avoid Failures in the Design and Installation of Permeable Reactive Barriers SustainTech Saskatoon, SK March 21, 2019 Kevin French Presenter Kevin French, P.Eng Vice President, Vertex Environmental Inc.


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SustainTech – Saskatoon, SK March 21, 2019 Kevin French

Case Study: How to Avoid Failures in the Design and Installation of Permeable Reactive Barriers

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Presenter

Kevin French, P.Eng

  • Vice President, Vertex Environmental Inc.
  • B.A.Sc., Civil/Environmental Engineering, University of Waterloo
  • 30+ years environmental engineering; 25 in consulting and 5 as a

remedial contractor Special thanks to Milestone Environmental Contracting Inc. who were our partners for this project.

Vertex Environmental Inc.

  • Founded in 2003
  • Specialized Environmental Remediation

Contracting

  • High Resolution Site Characterization (HRSC)
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Vertex Environmental Inc.

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Presentation Overview

  • Permeable Reactive Barriers
  • Overview of Site Conditions
  • Preliminary Design & Bench-Scale Testing
  • High-Resolution Site Characterization
  • Updated Final Design
  • Full-Scale Installation
  • Quality Assurance / Quality Control
  • Performance Monitoring
  • Lessons Learned
  • Questions
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Permeable Reactive Barriers (PRBs)

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Permeable Reactive Barriers (PRBs)

  • PRBs intercept and treat

contaminated groundwater plumes (passive)

  • Allow groundwater to flow through

unimpeded

  • Different reactive media for

different contaminants

  • Original zero-valent iron (ZVI)

PRBs (“Iron Walls”) installed in mid-1990 still functional

  • Can be dug or injected
  • Sustainable (no energy use to
  • perate)
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Overview of Site Conditions

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Overview of Site Conditions

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Overview of Site Conditions

  • Contamination identified in 1998
  • Municipality purchased in 2008 and converted to parking lot
  • Main groundwater contaminants were tetrachloroethylene

(PCE) and its degradation products

  • No DNAPL suspected
  • Main pathway of concern was groundwater flow through
  • verburden
  • Remedial objective was to prevent plume of contaminated

groundwater from continuing to migrate

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Overview of Site Conditions

PCE concentrations in groundwater April 2012

1000 100 500

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Overview of Site Conditions

  • Geology:

– Sand and gravel fill with occasional cobbles – Native soil was sand, silty sand and silty clay till – Some reported “flowing” sands – Clay till served as “confining layer” over limestone / dolostone bedrock – Overburden thickness was approximately 6 to 7 mbgs

  • Hydrogeology:

– Water levels in the overburden at approx. 2.4 to 3.4 mbgs – Horizontal hydraulic gradient of approx. 0.03 to 0.06 – Hydraulic conductivity of approx. 1.2E-07 to 3.5E-04 m/s – Estimated groundwater flow velocity of 40 m/yr

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Overview of Site Conditions

Geologic Cross-Section

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Preliminary Design & Bench-Scale Testing

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Preliminary Design

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Preliminary Design

Gate Funnel Funnel

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Preliminary Design

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Bench-Scale Testing

  • The municipal client did not have

experience with ZVI PRB technology

  • Bench-scale treatability testing was
  • ffered to provide “proof-of-concept”

and assurances to client

  • Samples of contaminated

groundwater obtained from the site and mixed with ZVI and sand

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Bench-Scale Testing

  • Parameter-specific

degradation half-lives calculated based on bench-scale tests

  • Compared to literature

references as a reality check

  • >95% reduction in

total CVOCs achieved

  • ver 22 days of testing
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Preliminary Design & Bench-Scale Testing

  • Preliminary PRB design was determined using a computer model that

assessed: – CVOC concentrations in groundwater and target treatment concentrations – Physical, geological and hydrogeological conditions of the soils at the site and in the planned PRB – CVOC half-lives from the bench-scale testing (first order decay) – Groundwater temperature conditions for site – Groundwater flux balance through “funnel & gate” PRB configuration

  • In order to meet PSS levels using reported groundwater flow velocities a

PRB 1.0 m thick would need to contain 37% ZVI

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Preliminary Design & Bench-Scale Testing

  • Sensitivity analysis completed on

all input variables

  • Model (and therefore results)

most sensitive to hydraulic conductivity

  • k-values varied by over 3 orders
  • f magnitude, other parameters

by <1

  • Recommended additional site

characterization to reduce uncertainty in predicted results

Value used in model

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High-Resolution Site Characterization

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High-Resolution Site Characterization

Hydraulic Profiling Tool (HPT)

  • Direct-push
  • Assess formation permeability
  • Water injected into the ground; flow and

back-pressure measured

  • EC: Estimate of soil type
  • Identifies location of water table (no wells)
  • Result: Empirical estimate of hydraulic

conductivity on a cm scale

  • HPT deployed at the site to find preferential

flow paths in the saturated zone and to define lower “confining layer”

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High-Resolution Site Characterization

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High-Resolution Site Characterization

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High-Resolution Site Characterization

How to keep water from freezing in a 0.25” diameter line when the temperatures on-site are -10 to -20°C?

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High-Resolution Site Characterization

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High-Resolution Site Characterization

Unsaturated Zone Higher K Zone Lower K Zone Confining Layer

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Updated Final Design

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Updated Final Design

  • Data from the HPT testing activities was used to update the preliminary

design for the PRB:

  • In order to meet PSS reduction using updated site data a PRB containing

30% ZVI would now only need to be 0.9 m thick (~27% savings)

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Full-Scale Installation

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Full-Scale Installation

  • Cut and fill method PRB
  • Concrete wing walls for “Funnels”

were 12 m long and 6 m long

  • Cut / fill (using trench box) the

“Funnel” wing walls with concrete

  • Excavate PRB “Gate” section using

biopolymer slurry (guar gum) for sidewall support

  • Coarse sand for PRB “Gate”

delivered in cement mixing truck; ZVI added to truck and blended

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Full-Scale Installation

  • Backfill PRB “Gate” section with

ZVI / sand mixture and avoid gravity separation through slurry

  • Break slurry and pump back from

trench into on-site tank for off-site disposal

  • Place and compact granular trench

cap and repave

  • Completed over 6 days on-site
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Full-Scale Installation

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Full-Scale Installation

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Full-Scale Installation

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Full-Scale Installation

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Quality Assurance / Quality Control

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Quality Assurance / Quality Control

  • Samples of ZVI / sand mixture

collected from each batch and subjected to magnetic separation testing

  • Post-installation boreholes drilled

through “Gate” portion of PRB and subjected to magnetic separation testing (similar results)

  • One monitoring well drilled approx.

1.5 m downgradient of PRB for groundwater sampling and analysis Target ZVI Concentration = 30%

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Performance Monitoring

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Performance Monitoring

Groundwater Flow Direction

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Performance Monitoring

PSS for PCE PSS for TCE

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Performance Monitoring

PSS for PCE PSS for TCE

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Performance Monitoring

Generic Standards Met!

PSS for PCE PSS for TCE SCS for VC SCS for PCE, TCE & DCE

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Lessons Learned

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Lessons Learned

  • Review ESA data, develop CSM and preliminary

design (data gaps, sensitivity, etc.)

  • Bench-scale testing for site-specific response
  • Collect additional site data (HPT) to resolve

uncertainties (confining layer, k values)

  • Ensure no gravity separation of ZVI / sand admixture

as it is emplaced

  • Implement robust QA/QC programme during and post-

installation

  • Ensure field installation is as per final design
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Questions?

Thank You for Your Time

Kevin French

Vertex Environmental Inc. (519) 653-8444 x 303 (519) 404-5442 mobile kevinf@vertexenvironmental.ca www.vertexenvironmental.ca